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101.
氢化物发生辅助雾化火焰原子吸收法测定人发中的铅 总被引:2,自引:0,他引:2
使用氢化物发生辅助雾化的火焰原子吸收法,在K3Fe(CN)6-HCl体系中,测定了头发中铅的含量。对酸度、氧化剂及浓度、NaBH4的浓度及流速对Pb测定的影响分别进行了研究。与传统雾化火焰原子吸收法相比,本方法测铅的灵敏度提高了13.4倍。方法的检出限为2.8 μg·L-1,精密度(RSD)为1.4%。用于测定人发中的Pb,回收率达96%~99%。 相似文献
102.
研究D-C chang等人引进的五个区域Hardy空间,刻划这些空间的原子分解和对偶空间,揭示了这些空间的内在联系。 相似文献
103.
激光冷却和捕陷中性原子③ 总被引:3,自引:1,他引:3
6 激光冷却和捕陷中性原子技术的应用 前面已经提到,激光冷却和捕获中性原子技术最主要的应用是在精密计量和超冷原子物理两个方面.在精密计量方面最为典型的是可用于原子频标的"原子喷泉"(atomic fountain)技术;而在超冷原子物理方面最为典型的是玻色-爱因斯坦凝聚(Bose-Einstein condensation)和原子波激射器(atom laser)的实现. 相似文献
104.
交联壳聚糖在硒的形态分析中的应用研究 总被引:20,自引:0,他引:20
本文研究了交联壳聚糖对Se(Ⅳ)和Se(Ⅵ)的吸附行为,并吸附机理进行了探讨。结果表明:在PH=4时,Se(Ⅳ)捐附率达95%,而对Se(Ⅳ)几乎无吸附;吸附Se(Ⅵ)后,用1mol/L盐酸定量解吸,建立了氢化物发生原子吸收测定环境中痕量Se(Ⅳ)/Se(Ⅵ)和有机硒的方法。本法的检出限为20ng/L,回收率为93-106%,变异系数为2.0-5.0% 相似文献
105.
Yiqi Zhang Zhenkun Wu Milivoj R. Beli Huaibin Zheng Zhiguo Wang Min Xiao Yanpeng Zhang 《Laser \u0026amp; Photonics Reviews》2015,9(3):331-338
The feasibility of realizing a photonic Floquet topological insulator (PFTI) in an atomic ensemble is demonstrated. The interference of three coupling fields will split energy levels periodically, to form a periodic refractive index structure with honeycomb profile that can be adjusted by different frequency detunings and intensities of the coupling fields. This in turn will affect the appearance of Dirac cones in momentum space. When the honeycomb lattice sites are helically ordered along the propagation direction, gaps open at Dirac points, and one obtains a PFTI in an atomic vapor. An obliquely incident beam will be able to move along the zigzag edge of the lattice without scattering energy into the PFTI, due to the confinement of edge states. The appearance of Dirac cones and the formation of a photonic Floquet topological insulator can be shut down by the third‐order nonlinear susceptibility and opened up by the fifth‐order one.
106.
107.
超短脉冲强激光与团簇的相互作用已被证明能够产生能量高达MeV量级的高能离子和中子以及非常强的X射线辐射。广阔好原子团簇在超短脉冲强激光场的作用下的加热、电离和膨胀等机制,对这种相互作用的深入研究可能会对激光核聚变和X射线激光等应用领域产生重大影响。 相似文献
108.
Y.B. Duan L. Wang W.J. Qian 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,11(1):25-29
A non-partial-wave Coulomb-Born theory is recently formulated to treat the excitation of many-electron atomic ions for impact
by an arbitrary charged particle [Y.B. Duan et al., Phys. Rev. A 56, 2431 (1997)]. The multiple expansion of the transition matrix element is decomposed into the target form factor and the
projectile form factor. These are the matrix elements of the tensor operators between quantum states so that any complicated
wave function for the target ion can be employed. In this formal theory, an infinitesimally small positive quantity is introduced artificially to guarantee the convergence of integrals. As a supplementary part of the theory, we discuss how
to choose the value of . It is found that the should be taken as functions of the momentum transfer and multipolarity . Illustrations are carried out by calculating the cross-sections for some typical transitions n
a
l
a
-n
b
l
b
of hydrogen-like ions for impact by electron, positron, and proton, respectively. The resulting cross-sections are in good
agreement with ones produced by using a method available for ion targets with Slater-type orbitals [N.C. Deb, N.C. Sil, Phys.
Rev. A 28, 2806 (1993)]. Comparisons demonstrate that the Coulomb-Born theory with non-partial wave analysis provides a powerful method
to treat the excitation of many-electron atomic ions impact by an arbitrary charged particle.
Received 6 April 1999 相似文献
109.
S.H. Patil 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,10(3):341-347
We have developed a simple model potential with a hard core and the correct large-r Coulombic behaviour, to describe the interaction of an electron with a closed shell. One has an exact, analytic ground state
wave function for this potential. This potential is used to develop two-electron perturbed and unperturbed wave functions,
with the correct asymptotic behaviour and cusp conditions. These wave functions allow us to obtain accurate values for the
two-electron energies, polarisabilities, hyperpolarisabilities, and dispersion coefficients of alkaline earth sequences. Many
of these results are the only ones available in the literature.
Received 29 July 1999 and Received in final form 16 November 1999 相似文献
110.
E. Zerrad Y. Hahn 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,10(1):81-97
The conventional Hartree and Hartree-Fock approaches for treating many-electron bound systems have been extended recently
to positive energy scattering problems, in which both the bound and continuum orbitals are determined by the requirement of
full self-consistency. Serious consequences of such a theory are that the target orbitals become energy dependent and the
asymptotic boundary conditions are satisfied only approximately, in lowest order. It is important therefore to test the theory
for its convergence under configuration mixing. This self-consistent field (SCF) theory for scattering has been tested here
for scattering from hydrogenic target as a model where the target function is determined dynamically. Penetration of the projectile
inside the bound target orbital is manifest through the SCF for the bound state. Our results show that the theory converges
to the correct amplitudes and to the exact boundary conditions as more configurations are added. The use of the amputated
functions and the weak asymptotic condition (WAC) upon which the SCF theory is based, is justified as the WAC converges to
the correct limit. It is then applied to the positron-helium and electron-helium scattering systems where the helium function
is calculated simultaneously together with the scattering function. The resulting phase shifts and the SCF target functions
are compared with those obtained with the pre-determined target functions in the conventional approaches.
Received 22 September 1999 相似文献