全文获取类型
收费全文 | 6074篇 |
免费 | 1265篇 |
国内免费 | 932篇 |
专业分类
化学 | 7609篇 |
晶体学 | 12篇 |
力学 | 82篇 |
综合类 | 11篇 |
数学 | 166篇 |
物理学 | 391篇 |
出版年
2024年 | 2篇 |
2023年 | 70篇 |
2022年 | 99篇 |
2021年 | 162篇 |
2020年 | 332篇 |
2019年 | 166篇 |
2018年 | 238篇 |
2017年 | 170篇 |
2016年 | 339篇 |
2015年 | 419篇 |
2014年 | 431篇 |
2013年 | 583篇 |
2012年 | 462篇 |
2011年 | 443篇 |
2010年 | 427篇 |
2009年 | 426篇 |
2008年 | 482篇 |
2007年 | 420篇 |
2006年 | 408篇 |
2005年 | 362篇 |
2004年 | 358篇 |
2003年 | 422篇 |
2002年 | 221篇 |
2001年 | 131篇 |
2000年 | 120篇 |
1999年 | 78篇 |
1998年 | 63篇 |
1997年 | 88篇 |
1996年 | 84篇 |
1995年 | 75篇 |
1994年 | 32篇 |
1993年 | 32篇 |
1992年 | 39篇 |
1991年 | 13篇 |
1990年 | 20篇 |
1989年 | 13篇 |
1988年 | 9篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有8271条查询结果,搜索用时 78 毫秒
21.
Yong Lee Kazuhiko Hosomi Hiroyuki Uchiyama Toshio Katsuyama Shinya Kominami Tomoyoshi Mishima 《Optical Review》2003,10(1):38-42
An InGaAsP slab-type asymmetric-coupled-waveguide-based dispersion compensator with a mode selector has been designed and fabricated. The mode selector is necessary to select either a symmetric [with a positive group-velocity dispersion (GVD)] or antisymmetric (with a negative GVD) supermode. These supermodes exist simultaneously in the dispersion-compensation region of the device. Pulse-compression experiments were used to test the dispersion compensator, evaluating the function of the mode selector. A theoretical study of the experimental results shows that the mode selector obtains a very strong selectivity (nearly 100%) for the antisymmetric supermode. 相似文献
22.
V. A. Petrosyan 《Russian Chemical Bulletin》1995,44(8):1353-1364
The results of studies on electrosynthesis involving carb- and heteroanions generated by cathodic deprotonation of acids (CDA), carried out in the laboratory headed by the author, are surveyed. These studies resulted in the elaboration of efficient electrochemical versions of the known Michaelis-Becker, Wittig-Horner, and Perkin reactions; electrochemical analogs of homolytic aromatic substitution, alkylation, heterocyclization,etc. were developed. Based on CDA, convenient and promising methods for preparing variousN-, O-, P-, S-, andC-alkylated and arylated substances have been developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1411–1422, August, 1995.The author is grateful to Professor V. A. Dorokhov, Professor V. P. Litvinov, and researchers from the laboratories of N. D. Zelinsky Institute of Organic Chemistry headed by them, who participated in joint studies.The work was carried out with financial support from the International Science Foundation (Grant No. MHYOO). 相似文献
23.
Peptidic aminopeptidase inhibitors, bestatin, phebestin and probestin have been prepared by stereo- and regiocontrolled reactions from a common α,β-epoxy ester precursor. 相似文献
24.
25.
26.
Richard P. Fischer Arne W. Fliflet 《International Journal of Infrared and Millimeter Waves》2002,23(9):1297-1313
This paper presents the design and test of asymmetric quasioptical resonators for gyrotron applications, where most of the diffraction output coupling comes from the smaller of two mirrors. A computer code based on scalar diffraction theory is used to calculate the resonator losses and the electric field near the mirrors. Resonators with mirror separations approaching confocal have reduced side lobes in the diffraction patterns, which should allow for better power transmission and focusing. Cold tests have been performed at 94 and 141 GHz to measure the quality factor of the asymmetric resonators as a function of mirror separation and mirror misalignment. Typical resonator parameters include 65 cm mirror separation, 1-3% output coupling and 85% of the losses from the small mirror. A half-symmetric resonator with one flat and one curved mirror has also been investigated. The calculated values of Q are in reasonably good agreement with the cold test measurements. 相似文献
27.
改进了张维迎对地区间竞争与国有企业民营化的分析,给出了经营者的剩余索取份额对竞争性的连续依赖关系:国有企业若要降低成本,就必须参与市场竞争,随着市场竞争的加强,国有企业经营者的剩余索取份额应该逐渐增大,而当市场竞争水平超过某一阈值,国有企业经营者拥有全部剩余索取权是最优的. 相似文献
28.
铸膜液的溶剂体系(溶剂和非溶剂)对不对称膜形态的形成有重要作用。为了探索溶剂和透气性间的关系,本文考虑到了制备BCA梯度密度不对称膜的各种溶剂的一系列物理参数,得到了一些定性结果,并指出了更全面、明确、解释两者关系的研究方向。 相似文献
29.
Dalip Kumar 《Tetrahedron letters》2004,45(14):2887-2889
Standard procedures for elaborating a quinone methide precursor for conjugation to a DNA ligand was not compatible with the presence of a vinyl group. Instead, an acrylate linker was attached by Heck coupling subsequent to o-substitution of the phenolic precursor. This transformation required protection of the phenolic group and use of ethyl acrylate rather than acrylic acid. The presence of the vinyl group also rendered the quinone methide precursor more labile to alkaline conditions than its equivalent saturated derivative and required mild conditions for coupling to the pyrrole-imidazole polyamide. 相似文献
30.
István E. MarkóJean-Christophe Vanherck Ali AtesBernard Tinant Jean-Paul Declercq 《Tetrahedron letters》2003,44(16):3333-3336
Upon treatment with tBuOK/H2O, a variety of ω-halo-β-keto-ketals undergo smooth cyclisation, affording in excellent yields mono-protected [n,m] spiro bicyclic diketones. This transformation is highly stereoselective producing, in all cases, the diastereoisomerically pure spiro derivatives. 相似文献