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近年来,具有分子内共扼的电荷转移化合物用作荧光探针来研究微环境的特性得到较大的发展,由Lout坛Law等提出的p-N,N一二烷基氨基爷叉丙二睛类化合物,其吸收光谱,特别是荧光光谱具有强烈的溶剂极性依赖性,即荧光光谱的峰值波长依赖于所处环境的极性,并有良好的线性关系。 相似文献
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本文综述了图案化TiO2薄膜的制备技术,按图案的生成方式可分为图案的直接生成,掩膜复制法,硬质模板复制法三大类。可以通过针尖写蚀法、电子书写蚀法、激光写蚀法、自组装法、光电化学法直接制备图案。掩膜复制法包括光刻胶法、自组装膜法、光敏凝胶膜法等。硬质模板法也称软刻蚀技术,分为复制微模塑、转移微模塑、毛细管微模塑、微接触印刷法、光-盖印印刷等技术。对每类方法的优缺点作了适当评述,对今后图案化TiO2薄膜制备的研究方向提出了一些建议。 相似文献
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Yiting Xu Jianjie Xie Lingnan Chen Hui Gao Conghui Yuan Cong Li Weiang Luo Birong Zeng Lizong Dai 《先进技术聚合物》2014,25(6):613-623
Organic/inorganic hybrid amphiphilic block copolymer poly(methacrylate isobutyl POSS)‐b‐poly(N‐isopropylacrylamide‐co‐oligo(ethylene glycol) methyl ether methacrylate) (PMAPOSS‐b‐P(NIPAM‐co‐OEGMA)) was synthesized via reversible addition–fragmentation chain transfer polymerization. The self‐assembly behavior of this block copolymer in aqueous solution was investigated by dynamic light scattering (DLS) and transmission electron microscopy. The results indicate that the novel block copolymer can self‐assemble into spherical micelles with PMAPOSS segment as the hydrophobic part and P(NIPAM‐co‐OEGMA) segment as the hydrophilic part. The temperature‐responsive characteristics of the assemblies were tested by UV–Vis spectra and DLS. Some factors such as the concentration, molecular weight, and copolymer generation that may affect the cloud point were studied systematically. The results reveal that this copolymer exhibits a sharp and intensive lower critical solution temperature (LCST). The essentially predetermined LCST can be conveniently achieved by adjusting the content of NIPAM or OEGMA domain. In addition, these novel hybrid micelles can undergo an association/disassociation cycle with the heating and cooling of solution and the degree of reversibility displaying a tremendous concentration dependence, as a novel organic/inorganic hybrid material with distinctive virtues can be potentially used in biological and medical fields, especially in drug nanocarriers for targeted therapy. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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本文继续文献[1~2]的研究,首先引进了生态系统的系综概念,在此基础上比较详细地讨论了生态协同学的微观方法和宏观方法.将这二者结合起来,利用生态系统输出(或可以测得)的宏观数据,建立广义金兹堡-朗道方程(GGLE),把握广义相变(群落演替)前后的信息变化,找出其微观对客观结果的作用机制,这也许是对复杂生态系统作用机制研究的一条新途径. 相似文献
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Recently, protein-based nanoparticles as drug delivery systems have attracted great interests due to the excellent behavior of high biocompatibility and biodegradability, and low toxicity. However, the synthesis techniques are generally costly, chemical reagents introduced, and especially present difficulties in producing homogeneous monodispersed nanoparticles. Here, we introduce a novel physical method to synthesize protein nanoparticles which can be accomplished under physiological condition only through ultraviolet (UV) illumination. By accurately adjusting the intensity and illumination time of UV light, disulfide bonds in proteins can be selectively reduced and the subsequent self-assembly process can be well controlled. Importantly, the co-assembly can also be dominated when the proteins mixed with either anti-cancer drugs, siRNA, or active targeting molecules. Both in vitro and in vivo experiments indicate that our synthesized protein–drug nanoparticles (drug-loading content and encapsulation efficiency being ca. 8.2% and 70%, respectively) not only possess the capability of traditional drug delivery systems (DDS), but also have a greater drug delivery efficiency to the tumor sites and a better inhibition of tumor growth (only 35% of volume comparing to the natural growing state), indicating it being a novel drug delivery system in tumor therapy. 相似文献
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通过静电组装技术在碳圆盘电极(PGE)表面制备{聚二烯丙基二甲基氯化铵(PDDA)/多壁碳纳米管(MWCNT)}n/PDDA多膜,并采用循环伏安法在多膜表面电化学修饰一磷钼酸(PMo12)膜,构筑PGE/{PDDA/MWNTs}5/PDDA/PMo12复合膜修饰电极,研究该复合膜修饰电极电化学及其对溴酸盐(BrO3-)电催化还原性质.在此基础上建立毛细管电泳-PGE/{PDDA/MWNTs}5/PDDA/PMo12修饰电极电化学检法定饮用水中溴酸盐分析新方法.在优化实验条件下,电泳峰面积与溴酸根浓度在5.0×10-8~5.0×10-5mol/L范围内呈良好性关系(r=0.9954),检出为2.0×10-8mol/L(S/N=3). 相似文献
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采用LB技术组装了一种三维有序的由十八胺修饰的纳米金颗粒多层结构.这是一种新的组装纳米颗粒三维有序聚集体的方法.为了扩大这种方法的适用范围,在组装过程中,将有机小分子1-苯基-5-巯基四氮唑引进结构,形成了新的纳米金颗粒多层聚集体.这两种多层膜经透射电子显微镜和小角X射线衍射测量证明构成多层膜的单层膜上的纳米金颗粒是有序的,并且颗粒在层与层之间的排列也是有序的. 相似文献
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This paper is a continuous study of references[1-2].At first,we introduce theconcept of assembles of ecosystems,and then discuss macro-and micro-synergeticalmethods for ecology study.Combining the two methods,by use of the macroscopic data(observable)outputted from the ecosystems,we can construct their GGLE,master theirinformation changes between,before and after the generalized phase changes(e.g.community successions),and find out the action mechanisms of microscopic factors onmacroscopic results.This may be a new approach to the study of action mechanisms ofcomplex ecosystems. 相似文献
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胆固醇(Cholesterol)嵌入卵磷脂(PC)有序体后对其中CaCO3晶型结构的影响 总被引:1,自引:0,他引:1
在PC和Chol/PC有序体中进行CaCO3沉淀反应,用X射线衍射和扫描电镜方法表征了反应物结构,研究了作为有机模板剂的不同分子有序体对CaCO3的晶型和形态的指导作用.在反胶束合成中出纳米级CaCO3颗粒.胆固醇对有序体有显著影响,进而影响此体系中形成的CaCO3晶型,可诱导生成3种CaCO3异构体:胶体CaCO3、球霰石和方解石.方解石含量随胆固醇含量增加减少. 相似文献