纳米氧化镱对熔融石英析晶动力学机制的影响

本文研究引入纳米氧化镱对熔融石英析晶机制及动力学过程的影响.通过X射线衍射仪(XRD)测试结果分析了纳米氧化镱的引入对熔融石英陶瓷析晶率的影响,采用动力学方法分析了纳米氧化镱的引入对熔融石英陶瓷析晶机制的影响,同时探讨了其等温析晶动力学过程.研究表明,熔融石英陶瓷的晶粒向二维兼有一维及三维的方式生长,引入纳米氧化镱的熔...     

陶瓷材料疏水性能的研究进展

本文简述了疏水性表面的基本原理,分别从低表面能物质修饰和表面微细粗糙结构的构建两个方面,对疏水性陶瓷材料的制备技术和最新的成果进行了总结,介绍了其潜在的应用并对未来的研究方向作了展望.     

水合硼酸锶的制备及脱水热分解动力学

以氯化锶和硼酸氢铵为原料,采用液相沉淀法制备了片状水合硼酸锶（SrB6O10•5H2O）粉体,并用XRD、FT-IR及SEM进行了表征。利用热重分析法对片状纳米硼酸锶粉体的脱水热分解动力学进行了研究,分别采用 Coats- Redfern 方程和 Flynn-Wall-Ozawa（FWO）法对热重分析数据进行了处理和拟合,初步确定了水合硼酸锶的四步脱水过程及相应的热分解反应机理,得到各步反应的表观活化能和指前因子。     

Eine einfache Mehrprobenrotationsanordnung zur Aktivierungsanalyse am Neutronengenerator

Es wird eine Anordnung beschrieben, die es gestattet, bis zu 7 Proben unter identischen Bedingungen rotationssymmetrisch zu aktivieren. Die Proben rotieren um zwei parallele Achsen. Es wird über Erprobungsmessungen durch Aktivierung von Cu-und N-haltigen Proben berichtet.     

Fluid-Fluid Phase Separation by Molecular Dynamics

Abstract

Miscibility of several binary fluid systems, placed in an external gravitational field, has been studied by Molecular Dynamics calculation. The results show inmiscibility and phase separation to appear as a consequence of differences in the Lennard-Jones energy parameter of molecular interaction. Two situations are primarily considered: The case of a big difference in the energy parameters of pure components and the case of a weak interaction between unlike molecules.     

On the response of LR-115 plastic track detector to 10 20 Ne-ion

The track etch rates of ₁₀ ²⁰ Ne-ion in cellulose nitrate (LR-115) have been measured for different temperatures and the activation energy is determined. The experimental results show that both the track etch rate and the normalized track etch rate depend on the energy loss as well as on etching temperature. The maximum etched track length of ₁₀ ²⁰ Ne-ion agrees with the theoretically computed range. The experimental results show that there is no sharp threshold, at least in CN(LR-115).     

Rate processes on fractals: Theory,simulations, and experiments

Heterogeneous kinetics are shown to differ drastically from homogeneous kinetics. For the elementary reaction A + A products we show that the diffusion-limited reaction rate is proportional tot ^– h[A]² or to [A]^x, whereh=1- d _s/2, X=1+2/d _s =(h-2)(h-1), andd _s is the effective spectral dimension. We note that ford = d _s =1, h =1/2 andX = 3, for percolating clustersd _s = 4/3,h = 1/3 andX = 5/2, while for dust ds <1, 1 >h > 1/2 and >X > 3. Scaling arguments, supercomputer simulations and experiments give a consistent picture. The interplay of energetic and geometric heterogeneity results in fractal-like kinetics and is relevant to excitation fusion experiments in porous membranes, films, and polymeric glasses. However, in isotopic mixed crystals, the geometric fractal nature (percolation clusters) dominates.     

On the stationary measures of anharmonic systems in the presence of a small thermal noise

We consider certain small stochastic perturbations of ad-dimensional infinite system of coupled anharmonic oscillators. The evolution law is reversible in the Yaglom sense, thus Gibbs states with the given interaction and temperature are stationary measures. If d<3 then some stability properties of the interaction imply the converse statement; if d>2 then the same is proven for translation invariant measures only. The methods and results of Ref. 4, 6–8 are extended to second-order systems of stochastic differential equations.