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71.
根据反应层的概念对在任一给定形状微电极上进行的准一级和二级均相催化反应机理(EC'')的稳态电化学行为进行了研究。本方法简便易行,不需要解复杂方程的数学技巧。利用推导出的这些方程,可计算准一级和二级均相催化反应的动力学常数。 相似文献
72.
合成了9种具L-氨基酸衍生物结构的介晶化合物(I-Ⅲ,Ⅳab,Ⅴa,b,Ⅵa,b)、4种氨基酸衍生物(A1-4)和6种介晶化合物(M1-6).新化合物(Ⅰ-Ⅲ,Ⅳa,b,Ⅴa,b,Ⅵa,b,A4,M3-6)的化学结构通过IR、1HNMR和元素分析证实;并用偏光显微观察和DSC分析研究了其相变行为,结果表明有8种化合物(M3-6,Ⅵa,b,Ⅴb,Ⅵb)呈现液晶相变。测定了它们的比旋光度。通过X射线衍射研究了化合物Ⅵh120~130℃和Ⅵb170~180℃的近晶结构,Ⅵb显,Ⅵb呈。测定了化合物Ⅳb的电滞回线,证明其具铁电性。 相似文献
73.
74.
Evaporation behavior of water from aqueous dispersions of multihollow particles prepared by the stepwise alkali/acid method 总被引:1,自引:0,他引:1
In order to clarify the formation mechanism of multihollow structures inside styrene–methacrylic acid copolymer particles
prepared by the stepwise alkali/acid method, which we proposed in 1990, the evaporation behavior of water from aqueous dispersions
of the original carboxylated particles and those after the alkali treatment and the stepwise alkali/acid treatments was examined.
It is concluded that the particle after the alkali treatment had a number of small water pools inside.
Received: 22 February 2001 Accepted: 20 June 2001 相似文献
75.
In this paper,p-tricyanovinyl-N,N-dialkylanilines were synthesized as model compounds and through their spectroscopic behavior,the photo-induced electron transfer,charge separation were discussed and the aggregation in DMSO-H_2O system was investigated. 相似文献
76.
Hal Tasaki 《Journal of statistical physics》1987,49(3-4):841-847
A set of new critical exponent inequalities,d(1 –1 /)2 –, dv(1 – 1/), andd> 1, is proved for a general class of random cluster models, which includes (independent or dependent) percolations, lattice animals (with any interactions), and various stochastic cluster growth models. The inequalities imply that the critical phenomena in the models are inevitably not mean-field-like in the dimensions one, two, and three.The present work was reported at the 56th Statistical Mechanics Meeting (Rutgers, December 1986). 相似文献
77.
We study the two-dimensional first passage problem in which bonds have zero and unit passage times with probabilityp and 1–p, respectively. We prove that as the zero-time bonds approach the percolation thresholdp
c, the first passage time exhibits the same critical behavior as the correlation function of the underlying percolation problem. In particular, if the correlation length obeys(p) ¦p–p
c¦–v, then the first passage time constant satisfies(p)¦p–p
c¦v. At pc, where it has been asserted that the first passage time from 0 tox scales as ¦x¦ to a power with 0<<1, we show that the passage times grow like log ¦x¦, i.e., the fluid spreads exponentially rapidly. 相似文献
78.
尼龙66/蒙脱土复合材料结晶行为的研究 总被引:8,自引:0,他引:8
在密炼机中采用熔融共混法制备蒙脱土重量分数为 2 5 %、4 5 %的尼龙 6 6 /蒙脱土复合材料 .通过DSC法对非等温结晶行为及在 2 2 8~ 2 4 0℃范围内的等温结晶行为进行研究 ,并与纯尼龙 6 6进行比较 .从其等温和非等温结晶行为的研究表明 ,蒙脱土起成核剂的作用 ,它的填入使尼龙 6 6结晶速率提高 ,但填料与基体间的相互作用使其链段运动困难 ,结晶活化能提高 ;在研究的填料含量变化范围内 ,结晶行为变化不大 ,并且找到该复合材料在 2 2 8~ 2 34℃范围结晶对温度的不敏感区 ;对非等温结晶过程分析 ,刘结平 莫志深方程是适用的 ,而Ozawa方程则是不适用的 . 相似文献
79.
《Mendeleev Communications》2020,30(5):679-682
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80.
In this paper, elastic behaviors of non-Gaussian polymethylene (PM) chains with chain length N=100 are investigated by rotational isomeric state model. Here the tetrahedral lattice of PM chain and the non-local interaction of Sutherland potential are adopted. In the metropolis movement of PM chain, a four-bond movement model is used. The average energy and average Helmholtz free energy with various elongation ratios λ are calculated by Monte Carlo simulation method. The average energy increases with elongation ratio λ and the average Helmholtz free energy decreases with elongation ratio λ. The elastic force f and the energy contribution to elastic force fu can be obtained from f=∂〈A〉/∂r and f=∂〈U〉/∂r. We find that the elastic force f increases with elongation ratio λ and the energy contribution fu decreases with elongation ratio λ, and fu is less than zero. The ratio fu/f is close to −0.21 for λ?1.25, and −0.04 to −0.35 for λ>1.25 at T=364 K. In our calculation, the rubber elasticity may be discussed in terms of the chemical structure of polymer chains. 相似文献