热动力学问题的数值计算

 对含热传导的流体动力学方程组，用有限元方法进行数值求解。采用傅里叶热传导计算热流、用热流连续条件计算单元间接触面的温度、用三角形传热法计算体单元表面的热流，考虑各向同性弹塑性流体材料模型、三项式物态方程和导热系数与状态的相关性，给出了傅里叶热传导、接触传热、热应力应变效应、以及混合物冲击压缩特性等算例。对混合物冲击温度的数值模拟表明，小颗粒混合物在冲击压缩过程中，颗粒间的温度有差别、稍有波动，并随时间趋向于一致，以至热平衡。     

有限混合Gamma分布的拓扑稠密性证明

首先给出了有限混合Erlang分布在正实数轴上所有概率分布中稠密的理论证明,进而给出了混合Gamma分布具有稠密性的结论,说明有限混合Gamma分布具有广泛的适用性,可以用来刻画正实数轴上的任意随机变量.     

Optimized analysis of the critical behavior in polymer mixtures from Monte Carlo simulations

A complete outline is given for how to determine the critical properties of polymer mixtures with extrapolation methods similar to the Ferrenberg-Swendsen techniques recently devised for spin systems. By measuring not only averages but the whole distribution of the quantities of interest, it is possible to extrapolate the data obtained in only a few simulations nearT _c over the entire critical region, thereby saving at least 90% of the computer time normally needed to locate susceptibility peaks or cumulant intersections and still getting more precise results. A complete picture of the critical properties of polymer mixtures in the thermodynamic limit is then obtained with finite-size scaling functions. Since the amount of information extracted from a simulation in this way is drastically increased as compared to conventional methods, the investigation of mixtures with long chains or built-in asymmetries is now possible. As an example, the critical points, exponents, and amplitudes of dense, symmetric polymer mixtures with chain lengths ranging fromN=16 up toN=256 are determined within the framework of the 3D bond fluctuation model using grand canonical simulation techniques. As an example for an asymmetry, the generalization of the method to asymmetric monomer potentials is briefly discussed.     

Surface tension of talc and talc-chlorite mixtures

It is possible to estimate surface tension of high-energy solids combining the immersion microcalorimetry thermodynamics and Van Oss' model. In this study we have applied this method on talc and talc-chlorite samples in order to obtain thermodynamic values which permit to understand surface properties useful in the industrial applications of these solids. Some talcite samples are preferentially used in specific industrial applications because they are less hydrophobic or more lamellar. This method seems to be reliable to classify the solids and predict some properties.     

Large Sample Properties of Mixture Models with Covariates for Competing Risks

We study the large-sample properties of a class of parametric mixture models with covariates for competing risks. The models allow general distributions for the survival times and incorporate the idea of long-term survivors. Asymptotic results are obtained under a commonly assumed independent censoring mechanism and some modest regularity conditions on the survival distributions. The existence, consistency, and asymptotic normality of maximum likelihood estimators for the parameters of the model are rigorously derived under general sufficient conditions. Specific conditions for particular models can be derived from the general conditions for ready check. In addition, a likelihood-ratio statistic is proposed to test various hypotheses of practical interest, and its asymptotic distribution is provided.     

Synthesis of graft copolymers with “V‐shaped” and “Y‐shaped” side chains via controlled radical and anionic polymerizations

A combination of nitroxide‐mediated radical polymerization and living anionic polymerization was used to synthesize a series of well‐defined graft (co)polymers with “V‐shaped” and “Y‐shaped” branches. The polymer main chain is a copolymer of styrene and p‐chloromethylstyrene (PS‐co‐PCMS) prepared via nitroxide‐mediated radical polymerization. The V‐shaped branches were prepared through coupling reaction of polystyrene macromonomer, carrying 1,1‐diphenylethylene terminus, with polystyryllithium or polyisoprenyllithium. The Y‐shaped branches were prepared throughfurther polymerization initiated by the V‐shaped anions. The obtained branches, carrying a living anion at the middle (V‐shaped) or at the end of the third segment (Y‐shaped), were coupled in situ with pendent benzyl chloride of PS‐co‐PCMS to form the target graft (co)polymers. The purified graft (co)polymers were analyzed by size exclusion chromatography equipped with a multiangle light scattering detector and a viscometer. The result shows that the viscosities and radii of gyration of the branched polymers are remarkably smaller than those of linear polystyrene. In addition, V‐shaped product adopts a more compact conformation in dilute solution than the Y‐shaped analogy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4013–4025, 2007     

辽河冷家油田特稠油降粘剂LJVR-1及其性能评价

采用荧光法测定了辽河冷家油田冷47-556井特稠油乳化HLB值,然后以混合型表面活性剂、非离子型表面活性剂为主剂,快速渗透剂为辅剂按一定比例制备了水基降粘剂LJVR-1.实验结果表明,该降粘剂具有良好的乳化降粘性能,开采后易于破乳脱水,是一种较为理想的特稠油降粘剂.     

Alternating copolymerization of carbon dioxide and epoxide by manganese porphyrin: The first example of polycarbonate synthesis from 1-atm carbon dioxide

The first successful example of the formation of polycarbonate from 1-atm carbon dioxide and epoxide was demonstrated by the alternating copolymerization of carbon dioxide and epoxide with manganese porphyrin as a catalyst. The copolymerization of carbon dioxide and cyclohexene oxide with (porphinato)manganese acetate proceeded under the 1-atm pressure of carbon dioxide to give a copolymer with an alternating sequence. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3549–3555, 2003