全文获取类型
收费全文 | 2000篇 |
免费 | 115篇 |
国内免费 | 394篇 |
专业分类
化学 | 2294篇 |
晶体学 | 51篇 |
力学 | 6篇 |
综合类 | 21篇 |
数学 | 16篇 |
物理学 | 121篇 |
出版年
2024年 | 3篇 |
2023年 | 24篇 |
2022年 | 43篇 |
2021年 | 77篇 |
2020年 | 107篇 |
2019年 | 96篇 |
2018年 | 54篇 |
2017年 | 76篇 |
2016年 | 77篇 |
2015年 | 74篇 |
2014年 | 101篇 |
2013年 | 224篇 |
2012年 | 109篇 |
2011年 | 105篇 |
2010年 | 89篇 |
2009年 | 108篇 |
2008年 | 89篇 |
2007年 | 105篇 |
2006年 | 106篇 |
2005年 | 101篇 |
2004年 | 108篇 |
2003年 | 102篇 |
2002年 | 95篇 |
2001年 | 63篇 |
2000年 | 40篇 |
1999年 | 38篇 |
1998年 | 34篇 |
1997年 | 32篇 |
1996年 | 28篇 |
1995年 | 26篇 |
1994年 | 27篇 |
1993年 | 34篇 |
1992年 | 29篇 |
1991年 | 12篇 |
1990年 | 15篇 |
1989年 | 5篇 |
1988年 | 11篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 4篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有2509条查询结果,搜索用时 812 毫秒
31.
32.
33.
34.
M. Bešter-Rogač M. Tomšič J. Barthel R. Neueder A. Apelblat 《Journal of solution chemistry》2002,31(1):1-18
Conductivity measurements of oxalic acid and neutral oxalates (disodium oxalate, dipotassium oxalate, dicesium, and diammonium oxalate) were performed on dilute aqueous solutions, c < 3 × 10–3 mol-dm–3, from 5 to 35°C. These data and those available from the literature were analyzed in terms of dissociation steps of oxalic acid, the Onsager conductivity equation for neutral oxalates, the Quint–Viallard conductivity equation for the acid, and the Debye–Hückel equation for activity coefficients, to give the limiting equivalent conductances of bioxalate anion ;(HC2O4
–) and oxalate anion (1/2C2O4
2–) and the corresponding dissociation constants K
1 and K
2. 相似文献
35.
氯化钪-氯化钠-氯化钾熔盐制备新工艺研究 总被引:3,自引:1,他引:3
研究了以Sc2O3为原料,盐酸回流溶解后与NaCl,KCl,NH4Cl溶液混合,经蒸发浓缩、结晶、真空预脱水,再在氩气保护下分段升温脱水、升华除去过量NI-hCl后制备ScCl3-NaCl-KCl熔盐的新工艺。研究表明,添加NH4Cl后加热脱水时,NH4Cl分解产生的HCl气体能抑制ScCl3水合物加热过程中的水解,溶解产生的水不溶性钪,从而有效地防止了Sc2O3等水不溶化合物的生成。制备的ScCl3-NaCl-KCl熔盐脱水完全、水不溶性钪含量很低,能满足熔盐金属热还原法制备金属钪及铝钪中间合金对熔盐原料的要求。 相似文献
37.
Ammonium acetate was found to catalyze efficiently the selective deprotection of aromatic acetates in the presence of various sensitive functionalities in aqueous methanol under neutral conditions at room temperature to yield the corresponding phenols in excellent yields. The method has been utilized for deprotection of acetates of several naturally occurring bioactive phenolic compounds and for preparation of venkatasin, a natural coumarino-lignan, from the anticancer compound cleomiscosin A. 相似文献
38.
39.
Marina S. Fonari Victor Ch. Kravtsov Yurii A. Simonov Edward V. Ganin Vladimir O. Gelmboldt Janusz Lipowski 《Journal of inclusion phenomena and macrocyclic chemistry》2001,39(1-2):85-89
The crystalline host–guest type complex [(18-crown-6NH4)2][SiF6]4H2Ohas been obtained as the result of the interaction of SiF42NH3 with 18-crown-6 (18C6) in an aqueous medium. Crystal data: monoclinic, space groupC 2 c, a=26.541(2), b=8.363(2), c=20.469(2) Å, = 122.43(1)°and Z=4. The final R-value is 0.070 for 3253 reflections with I 2(I).The crystals consist of the complex [NH418C6]+ cations, [SiF6]2-anions and water molecules. The ammonium cation is hydrogen bonded by three of its H-atoms to the crown ether oxygen atoms with N(1) O separations2.923(5)–2.940(5) Å and by the fourth H-atom to the fluorine atom of thehexafluorosilicate anion, the N(1)F(4) distance being 2.797(6) Å.The conformation of the macrocycle and the hydrogen-bond geometry in thecomplex cation closely resemble those in related adducts between 18-crown-6and ammonium salts. All crystal components are connected via a system of hydrogen bonds into a ribbon along the b axis in the unit cell. 相似文献
40.
Mohamed El Guendouzi Abderrahim Dinane Abdelfetah Mounir 《Journal of solution chemistry》2002,31(2):119-129
The mixed aqueous electrolyte system of ammonium and lithium chlorides has been studied by the hygrometric method at 25°C. The relative humidities of this system are measured at total molalities from 0.3 to 6 mol-kg– 1 for different ionic-strength fractions y of NH4Cl with y = 0.33, 0.50, and 0.67. The data obtained allow the deduction of new water activities and osmotic coefficients. The experimental results are compared with the predictions of the ECA (extended composed additivity) law proposed in our previous work. The Zdanovskii–Stokes–Robinson (ZSR), the Robinson–Stokes (RS), Reilly–Wood–Robinson (RWR), the Pitzer, and the Lietzke–Stoughton (LS II) models are also compared with our results. Predictions made using these models are, in general, consistent with our results. From these measurements, new Pitzer mixing ionic parameters are determined and used to predict the solute activity coefficients in the mixture for different ionic-strength fractions. 相似文献