首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8000篇
  免费   988篇
  国内免费   1007篇
化学   3615篇
晶体学   129篇
力学   1001篇
综合类   184篇
数学   2383篇
物理学   2683篇
  2024年   17篇
  2023年   70篇
  2022年   176篇
  2021年   223篇
  2020年   256篇
  2019年   206篇
  2018年   193篇
  2017年   287篇
  2016年   313篇
  2015年   265篇
  2014年   446篇
  2013年   676篇
  2012年   457篇
  2011年   502篇
  2010年   414篇
  2009年   532篇
  2008年   533篇
  2007年   496篇
  2006年   494篇
  2005年   426篇
  2004年   343篇
  2003年   359篇
  2002年   284篇
  2001年   250篇
  2000年   247篇
  1999年   216篇
  1998年   173篇
  1997年   162篇
  1996年   153篇
  1995年   153篇
  1994年   100篇
  1993年   95篇
  1992年   70篇
  1991年   57篇
  1990年   62篇
  1989年   51篇
  1988年   53篇
  1987年   32篇
  1986年   26篇
  1985年   26篇
  1984年   29篇
  1983年   5篇
  1982年   19篇
  1981年   14篇
  1980年   3篇
  1979年   10篇
  1978年   3篇
  1977年   3篇
  1976年   3篇
  1975年   4篇
排序方式: 共有9995条查询结果,搜索用时 281 毫秒
951.
A non-autonomous SIR model with periodic transmission rate and a constant removal rate is formulated. By using the continuation theorem of coincidence degree theory, sufficient conditions for the existence of at least two positive periodic solutions are obtained. The stability of the periodic solution for small seasonality is investigated. Numerical simulations are done to show our theoretical results.  相似文献   
952.
Most decision making research in real options focuses on revenue uncertainty assuming discount rates remain constant. However, for many decisions revenue or cost streams are relatively static and investment is driven by interest rate uncertainty, for example the decision to invest in durable machinery and equipment. Using interest rate models from Cox et al. (1985b), we generalize the work of Ingersoll and Ross (1992) in two ways. Firstly, we include real options on perpetuities (in addition to zero coupon cash flows). Secondly, we incorporate abandonment or disinvestment as well as investment options, and thus model interest rate hysteresis (parallel to revenue uncertainty in Dixit (1989a)). Under stochastic interest rates, economic hysteresis is found to be significant, even for small sunk costs.  相似文献   
953.
This study is motivated by the paper of Skouri et al. [Skouri, Konstantaras, Papachristos, Ganas, European Journal of Operational Research 192 (1) (2009) 79–92]. We extend their inventory model from ramp type demand rate and Weibull deterioration rate to arbitrary demand rate and arbitrary deterioration rate in the consideration of partial backorder. We demonstrate that the optimal solution is actually independent of demand. That is, for a finite time horizon, any attempt at tackling targeted inventory models under ramp type or any other types of the demand becomes redundant. Our analytical approach dramatically simplifies the solution procedure.  相似文献   
954.
研究系数在边界点有奇性的一类Hamilt on- Jacobi- Bellman (HJB)方程的粘性解的存在唯一性问题及解的渐近估计,这类问题包括波动系数振荡或爆破的情况.奇异HJB方程在随机最优控制和金融数学等许多领域都有重要的应用,包括金融数学中的随机利率模型.应用粘性上下解理论建立了一类奇异HJB方程的比较原理,给出了粘性解存在唯一性的条件.  相似文献   
955.
城市社区共享资源维护的个体异质性效应研究   总被引:1,自引:0,他引:1  
城市社区共享资源经历日晒雨淋或人为频繁使用而逐渐耗损,为了"保值增值",必然出现对其维护捐赠的可持续性问题.在多人跨期均衡模型和数学赋值的随机模拟基础上,对个体偏好异质性等参数影响捐赠投入的机理进行了探讨,认为:差异程度与城市社区共享资源维护的捐赠投入正相关;且初始存量较大或耗损速率较慢时,异质性的作用更加显著.  相似文献   
956.
Under the elution of methanol‐based mobile phase, the isocratic resolution of 12 biogenic amines, including 1 aromatic, 2 heterocyclic and 9 aliphatic amines, as the dansylated derivatives has been accomplished in less than 25 minutes on a 15 cm C8‐bonded column. The resolution can not be reproduced on other examined alkyl‐bonded phases (e.g., C4 and C18) under the same chromatographic conditions, or in the reversed‐phase mode. The retention, mainly as a result of hydrophobic interaction between analyte and stationary phase, can be adjusted by varying the percentage of methanol in the mobile phase. Also, incorporating acetic acid as additive to the mobile phase to protonate the analyte and silanol groups that are little shielding on the surface of silica gel reduces the dipole‐dipole interaction, and thus the retention scale, which in turn deteriorates the resolution. Furthermore, the elution reversal is plausible for some of analytes as a greater percent of acetic acid is used in the elution. Values of correlation coefficients (R2) range between 0.9995 and 0.9996, indicating good linearity.  相似文献   
957.
Polymer nanoparticles within the range of 2–5 nm with a solid content of more than 13 wt.% and a narrow molecular weight polydispersity (Mw/Mn ∼ 1.1) were for the first time prepared using a micellar nucleation differential microemulsion polymerization system emulsified by sodium dodecyl sulfate (SDS), with SDS/monomer (methyl methacrylate) and SDS/H2O weight ratios of up to 1:16 and 1:100, respectively. It was found that for benzoyl peroxide (BPO), micellar nucleation is more favorable for the synthesis of smaller polymer nanoparticles than ammonium persulfate (APS) which gives rise to homogeneous nucleation and 2,2′-azobisisobutyronitrile (AIBN) which involves partially heterogeneous nucleation. In the polymerization process, there exists a critical stability concentration (CSC) of SDS, above which the size of the nanoparticles is to be minimized and stabilized. With an increase in the monomer addition rate, the polymerization system changes from a microemulsion system to an emulsion system. A mechanism was proposed to describe the micellar nucleation process of differential microemulsion polymerization. This study may contribute to the development of fine polymer nanoparticles for drug delivery systems.  相似文献   
958.
Liquid phase microextraction applications in food analysis   总被引:2,自引:0,他引:2  
Over the last years, liquid-phase microextraction (LPME) in its different application modes (single drop microextraction, dispersive liquid-liquid microextraction and hollow fiber-LPME) has been increasingly applied for the extraction of both inorganic and organic analytes from different matrices. Its advantages over conventional extraction procedures (simplicity, effectiveness, rapidity and low consumption of organic solvents) has also attracted its application in the complex food analysis field, in which it has clearly provided good and challenging results. A comprehensive review dealing with those articles published since its introduction till the end of March 2011 is presented, offering also a critical vision of the analytical potential of LPME for the analysis of foods.  相似文献   
959.
A general rate model was employed in concert with a preferential interaction quadratic adsorption isotherm for the characterization of HIC resins and the prediction of solute behavior in these separation systems. The results indicate that both pore and surface diffusion play an important role in protein transport in HIC resins. The simulated and experimental solute profiles were compared for two model proteins, lysozyme and lectin, for both displacement and gradient modes of chromatography. Our results indicate that a modeling approach using the generate rate model and preferential interaction isotherm can accurately predict the shock layer response in both gradient and displacement chromatography in HIC systems. While pore and surface diffusion played a major role and were limiting steps for proteins, surface diffusion was seen to play less of a role for the displacer. The results demonstrate that this modeling approach can be employed to describe the behavior of these non-linear HIC systems, which may have implications for the development of more efficient preparative HIC separations.  相似文献   
960.
This paper explores the response of a novel fiber optics sensor allowing real-time determination of the migration rate of vapor zones in capillary gas chromatography. The sensitivity is related to the gradient of the vapor zone distribution in the capillary and it is highest when vapor zones show steep variations in concentration. The expected linearity between the height of the velocity peaks and the response of a thermal conductivity detector is demonstrated experimentally. The sensor can be used to infer an approximate value of the analyte diffusion coefficient from the time response. Finally, the time evolution of the envelope of the optical signal is explained with experimental evidences.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号