Electrical resistivity studies of benzidine-TCNQ and its inclusion compound under high pressure

Electrical resistivity studies of the charge transfer complex benzidine—TCNQ and its inclusion compound, have been carried out up to pressures 8 GPa. Two types of behaviour were observed in these complexes under high pressure and this difference is interpreted and discussed.     

钙钛矿CaTiO3的超高压结构研究

利用同步辐射x射线衍射和 DAC 高压技术在室温下测量了钙钛矿CaTiO₃在压力0—44.53 GPa下的结构变化.结果表明，随着压力的增加CaTiO₃的三个晶轴都受到不同程度的压缩，a,b的压缩率相近且相对比较大，c的压缩率最小，但没有证据表明有相变的发生.在压力范围内CaTiO₃的P-V关系用Murnaghan状态方程表示，设定K′0=4，得到V0=0.2245(6)nm3和K0=222(9) GPa.应用赝立方角γpc与压力的关系，初 关键词： 3')" href="#">CaTiO₃ 结构 超高压 状态方程     

A numerical model for the flooding and drying of irregular domains

A numerical technique for the modelling of shallow water flow in one and two dimensions is presented in this work along with the results obtained in different applications involving unsteady flows in complex geometries. A cell‐centred finite volume method based on Roe's approximate Riemann solver across the edges of both structured and unstructured cells is presented. The discretization of the bed slope source terms is done following an upwind approach. In some applications a problem arises when the flow propagates over adverse dry bed slopes, so a special procedure has been introduced to model the advancing front. It is shown that this modification reproduces exactly steady state of still water in configurations with strong variations in bed slope and contour. The applications presented are mainly related with unsteady flow problems. The scheme is capable of handling complex flow domains as will be shown in the simulations corresponding to the test cases that are going to be presented. Comparisons of experimental and numerical results are shown for some of the tests. Copyright © 2002 John Wiley & Sons, Ltd.     

Unusual pressure-induced phase behavior in crystalline poly-4-methyl-pentene-1

We report some highly unusual phase behavior, of general implication for condensed matter, on the polymer poly(4-methyl-pentene-1) (P4MP1) induced by changes in pressure and temperature, as observed in situ by x-ray diffraction. Upon increasing pressure beyond a threhold, the polymer, crystalline under ambient conditions, loses its crystalline order isothermally, passing through a continuously varying sequence of mesomorphic states, the process being reversible. This behavior is observed in two widely separated temperature regions, suggesting, for the first time in a single component system, the possibility of reentrant liquid-crystal and amorphous phases. At the upper temperature region (ca. 250°C) there is a consecutive increase and decrease of melting point with pressure. In the lower temperature region (room temperature) the pressure converts the crystal into an amorphous-like glass obviating the need for going through the melt first, and this in a reversible manner. The latter pressure-induced disordered phase converts into crystal on raising the temperature, and reverts to the glassy, disordered phase on lowering the temperature. Some aspects of this behavior have been found quite recently in water-ice and silica but the process of “melting on cooling” has no precedent in any known system. Other unexpected findings include a new pressure-induced modification of P4MP1 with a one-way only entry with temperature, but full reversibility with pressure leading to a triple point in the PT phase diagram. The above highly uncommon results are putting several prevailing preconceptions to test which are being scrutinized. In the course of it some early expectations on general phase behavior, allowing among others for reentrant phases in one component systems, are being invoked as potentially appropriate for certain polymeric systems, if not for condensed matter in general. © 1993 John Wiley & Sons, Inc.     

Highly efficient and well‐controlled ambient temperature RAFT polymerization of glycidyl methacrylate under visible light radiation

A range of well‐defined poly(glycidyl methacrylate) (PGMA) polymers and their corresponding block copolymers were synthesized via 2‐cyanoprop‐2‐yl(4‐fluoro) dithiobenzoate or CPFDB‐mediated ambient temperature reversible addition fragmentation chain transfer radical polymerization or RAFT polymerization under environmentally friendly visible light radiation (λ = 405–577 nm), using a (2,4,6‐trimethylbenzoyl) diphenylphosphine oxide photoinitiator. As comparison, CPFDB‐mediated ambient temperature RAFT polymerizations of glycidyl methacrylate (GMA) under both full‐wave radiation (λ = 254–577 nm) and long‐wave radiation (λ = 365–577 nm) were also studied in this article. The results indicated that CPFDB moieties were significantly photolyzed under either full‐wave radiation or long‐wave radiation, thus undermining the controlled behavior of these RAFT processes. Whereas this photolysis was significantly suppressed under visible light radiation, thus CPFDB functionalities exerted well control over RAFT process, leading to a remarkably living behavior up to 90% GMA monomer conversions. This strategy facilitates the facile synthesis of well‐defined PGMA polymers. More importantly, under visible light radiation, a relatively high initial molar ratio of GMA to CPFDB and TPO led to shortening initialization period of RAFT process and accelerating overall polymerization rate. These effects are remarkably in favor of the facile synthesis of well‐defined PGMA polymers and PGMA‐based copolymers with high molecular weights. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5091–5102, 2007     

光子晶体压力传感器的基本原理

通过研究一维光子晶体受压力后其光带隙性能的变化，提出了光子晶体压力传感器的原理.计算表明，压力的大小与禁带起始波长、截止波长和禁带宽之间呈简单的线性对应关系.这就提供了通过测量光带隙性能而感知外载荷或者通过施加载荷而调制光带隙性能的可能.由于光子晶体的结构周期和光波波长为一个数量级，也就有可能制造出一系列精巧的压力、温度传感器或者其他精密仪器. 关键词： 压力传感器 光子晶体 光带隙性能     

The influence of tube bundle geometry on cross-flow boiling heat transfer and pressure drop

An experimental investigation was performed to compare the boiling heat transfer coefficients and two-phase pressure drops from a square inline and a staggered tube bundle having the same tube pitch-to-diameter ratio (P/D = 1.30) and from two square inline tube bundles having different pitch-to-diameter ratios (P/D = 1.30 and 1.70). Except at the highest heat fluxes the heat transfer coefficients generally were higher in the staggered tube bundle than in the inline tube bundle and higher in the larger P/D tube bundle than in the smaller. As the heat flux increased, the differences decreased. The differences were attributed to the tradeoff between nucleation and convection. The staggered tube bundle had higher pressure drops than the inline bundle except at low mass velocities; the larger pressure drop in the staggered bundle was attributed to the combination of a larger void fraction and a larger friction multiplier, with the frictional component dominating at higher mass velocities. Comparing the inline tube bundle pressure drops, it was concluded that the larger P/D bundle had a larger void fraction than the smaller P/D tube bundle; no conclusions could be drawn regarding the relative magnitude of the two-phase fraction multiplier.     

双稀土氧化物LnEuO3的Mossbauer效应研究

 本文首次利用高温高压方法合成了双稀土氧化物LaEuO₃、PrEuO₃、NdEuO₃和SmEuO₃。此外，还合成了CeEuO_3.5。X射线衍射分析表明LaEuO₃属A型（六方）结构，PrEuO₃、NdEuO₃和SmEuO₃属B型（单斜）结构，CeEuO_3.5属F型（萤石）结构。室温下用¹⁵¹Eu的21.6 eV γ射线测量了它们的Mossbauer谱，观察到了¹⁵¹Eu同质异能移位和四极劈裂强烈地依赖于Eu离子配位体体积而呈线性关系。超精细相互作用的这种体积效应，主要原因是由于Eu离子5s壳层的重叠畸变所引起。     

冷气喷射对直叶栅型面压力及气动损失分布影响的实验研究

提高燃气涡轮比功率，降低比油耗要通过升高涡轮入口温度和压气机压比实现，但必须对涡轮叶片实施诸如气膜冷却等保护措施。Ito和Goldstein[1]，Yamamoto[2]等分别研究了冷气喷射对在叶栅气动性能的影响。本文通过实验研究了冷气喷射对叶型型面压力和叶栅流道内气动损失的影响，并得出了一些有意义的结论。1实验装置实验在哈尔滨工业大学发动机气体动力研究中心低速风洞实验台[3]上进行。图1及表1给出了实验用叶片型线（取自一典型涡轮导向器叶型），冷气喷射孔位置及静压孔分布。叶片表面前缘、吸力面后部和压力面后部开了三列孔，每列孔…