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991.
Shuifa Qiu Yunyang Wei Prof. Dr. Guosheng Liu Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(12):2751-2754
Taking the air! A PdII‐catalyzed intramolecular hydroamination of allenes coupled to alcohol oxidation has been developed. This reaction is performed by using a nitrogen‐based ligand under aerobic conditions, under which the molecular oxygen is used as the terminal oxidant for the reoxidation of Pd0 species to complete the catalytic cycle.
992.
Farideh Hosseinpoor 《Tetrahedron letters》2006,47(29):5195-5197
Sulfides were selectively oxidized to the corresponding sulfoxides in good yields with hydrogen peroxide using a manganese(III) Schiff-base complex as a catalyst in glacial acetic acid as solvent under mild conditions. 相似文献
993.
采用循环伏安法,稳态法,计时电位法等研究了SO2在聚钴卟啉膜电极上的电化学氧化过程,并和SO2在贵金属电极上的行为进行了比较。 相似文献
994.
用溶胶-凝胶法制备了不同组成的Mn-Al和Cu-Mn-Al复合氧化物两组催化剂,用于苯甲醇选择氧化反应.用X射线衍射(XRD)、N2物理吸附(BET)、扫描电镜(SEM)、H_2程序升温还原(H_2-TPR)、O_2程序升温脱附(O_2-TPD)和X射线光电子能谱(XPS)技术对催化剂进行了结构表征,考察了催化剂组成对催化活性的影响.结果表明:以甲苯为溶剂,O_2为氧化剂,353 K反应5 h,Mn_2Al和Cu_(0.3)Mn_(0.7)Al_2催化剂上的苯甲醇转化率分别为36.6%和40.9%,苯甲醛选择性均为100%.进一步研究表明:催化剂活性与其H2还原性和O_2吸附性有关,高活性的催化剂吸附氧多,生成的活性氧易参与反应. 相似文献
995.
This paper reports physical properties of porous silicon and oxidized porous silicon, manufactured by anodisation from heavily p-type doped silicon wafers as a function of experimental parameters. The growth rate and refractive index of the layers were studied at different applied current densities and glycerol concentrations in electrolyte. When the current density varied from 5 to 100 mA/cm2, the refractive index was between 1.2 and 2.4 which corresponded to a porosity range from 42 to 85%. After oxidation, the porosity decreased and was between 2 and 45% for a refractive index range from 1.22 to 1.46. The thermal processing also induced an increase in thickness which was dependent on the initial porosity. This increase in thickness was more important for the lowest porosities. Lastly, the roughness of the porous layer/silicon substrate interface was studied at different applied current densities and glycerol concentrations in solution. Roughness decreased when the current density or glycerol concentration increased. Moreover, roughness was also reduced by thermal oxidation. 相似文献
996.
Pt/Eu2O3-CeO2 materials with different Eu concentrations were prepared and applied to toluene destruction, and the remarkable promotion impact of EuOx on Pt/CeO2 can be observed. The characterization results reveal that the presence of EuOx significantly enhances the redox property, lattice O concentration, and Ce3+ ratio of the Pt/CeO2 material, which facilitates the dispersion and activity of Pt active sites and thus accelerates the decomposition process of toluene. Among all catalysts, a sample with an Eu content of 2.5 at.% (Pt/EC-2.5) possesses the best catalytic activity with 0.09 vol% of toluene completely destructed at 200 °C under a relatively high GHSV of 50000 h?1. The possible reaction pathway and mechanism of toluene combustion over Pt/Eu2O3-CeO2 samples are presented according to in-situ DRIFTS, which confirms that the toluene oxidation process obeys the Mars-van Krevelen mechanism with aldehydes and ketones as primary organic intermediates. 相似文献
997.
Copper‐Catalyzed Aerobic Oxidative Transformation of Ketone‐Derived N‐Tosyl Hydrazones: An Entry to Alkynes 下载免费PDF全文
Xianwei Li Xiaohang Liu Huoji Chen Dr. Wanqing Wu Dr. Chaorong Qi Prof. Dr. Huanfeng Jiang 《Angewandte Chemie (International ed. in English)》2014,53(52):14485-14489
A novel strategy involving Cu‐catalyzed oxidative transformation of ketone‐derived hydrazone moiety to various synthetic valuable internal alkynes and diynes has been developed. This method features inexpensive metal catalyst, green oxidant, good functional group tolerance, high regioselectivity and readily available starting materials. Oxidative deprotonation reactions were carried out to form internal alkynes and symmetrical diynes. Cross‐coupling reactions of hydrazones with halides and terminal alkynes were performed to afford functionalized alkynes and unsymmetrical conjugated diynes. A mechanism proceeding through a Cu‐carbene intermediate is proposed for the C? C triple bond formation. 相似文献
998.
Minxia Huang Beiyang Yao Manhua Jiang Fuzhou Sun Jinsong You Fangfang Huang Yanping Zhao Shuming Wu Xinqian He Xuezhi Song 《Journal of mass spectrometry : JMS》2022,57(4):e4821
Two unknown solution degradants were found during the dissolution testing in 0.1-M HCl for olmesartan medoxomil (OLM) tablets. The structure of the degradants was identified and characterized by liquid chromatography–ultraviolet (LC–UV), liquid chromatography with tandem mass spectrometry (LC–MS/MS), and nuclear magnetic resonance (NMR) and demonstrated to be cyclization of tetrazole and benzene in the olmesartan (OL) and OLM structures. A series of studies including stress studies, simulation studies, and mechanism-based studies were performed to reveal the potential mechanisms that lead to the formation of the unknown degradants. The study results demonstrated that the degradation was catalyzed with radicals that originated from the metal ions leached from the inner surface of high-performance liquid chromatography (HPLC) glass vials with dissolved oxygen under acidic condition. Prerinsing the glass vials with acidic solution dissolved with EDTA can effectively avoid the generation of such oxidative impurities. The present work provides new insights into the understanding of degradation pathways of OLM, which might support the development of OLM tablets. 相似文献
999.
Lacheen HS Cordeiro PJ Iglesia E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(11):3048-3057
Synthesis protocols, structures, and reactivity of Re-oxo species grafted onto H-ZSM5, and their subsequent conversion to Re-clusters through contact with H2 or CH4 were studied by using Raman, infrared, and X-ray absorption spectroscopies. Reactivity measurements by using alkane and alkanol reactants were also examined. Sublimation of Re(2)O(7) at 723 K led to a stoichiometric exchange with each ReO(x) species replacing one proton. Raman features for Re(2)O(7) disappeared during thermal treatment and Raman bands assigned to distorted-tetrahedral Si-O(f)ReO(3)-Al (O(f): zeolite-lattice oxygen atoms) species emerged; infrared bands for acidic OH groups in H-ZSM5 weakened concurrently. X-ray absorption near-edge and fine-structure spectra detected the formation of distorted-tetrahedral Re7+-oxo species during thermal treatment of Re(2)O(7)/H-ZSM5 mixtures in air, and their subsequent reduction to Re(0) in H2 or CH4 to form encapsulated Re metal clusters similar in diameter (approximately 8 A) to the channel intersections in ZSM5. Si-O(f)ReO(3)-Al species in ReO(x)-ZSM5 catalyzed the oxidative conversion of C(2)H(5)OH to acetaldehyde, acetal, and ethyl acetate with very low selectivity to CO(x) (<1 %). Unprecedented turnover rates were exhibited at temperatures much lower than previously found for ReO(x)-based catalysts, and without deactivation or sublimation processes ubiquitous in crystalline Re7+ compounds at temperatures required for catalysis. Encapsulated Re metal clusters formed by the reduction of Si-O(f)ReO(3)-Al precursors led to CH4 pyrolysis and C(3)H(8) dehydrocyclodimerization rates (per Re) that are higher than those previously reported for zeolite-based catalysts. The rate of CH4 conversion to benzene, by using Re-ZSM5, was approximately 30 % higher than that of the best reported catalysts, based on encapsulated MoC(x) clusters, whereas C(2)H(4) and C6+ arene selectivities were similar. C(3)H(8) activity and selectivity of Re-ZSM5 was significantly higher than that of Ga-ZSM5, the best reported catalyst for these reactions. Reaction rates (per Re) were independent of the Re/Al(f) (Al(f): aluminum framework) ratio for both Re and ReO(x) species. This is consistent with the uniform character of the structures formed during grafting of the ReO(x) species through sublimation and their ability to retain their homogeneity even after their reduction to encapsulated Re-clusters. 相似文献
1000.
丙烯选择氧化铋钼铁复氧化物催化剂组成,结构及性能的研究 总被引:1,自引:0,他引:1
采用XRD、Raman、XPS及催化剂性能评价等手段,考察了Bi_3(FeO_4)(MoO_4)_2和Fe_2(MoO_4)_3分别存在及两者共存时对Bi-Mo复氧化物体系催化性能的影响.结果表明,这两种含Fe物种的存在都有助于改善Bi-Mo系复氧化物催化剂对丙烯选择氧化反应的催化性能.但两者在作用机理上有所不同.Fe_2(MoO_4)_3本身无催化活性,但在反应条件下可部分还原为FeMoO_4形成Fe~(3+)/Fe~(2+)氧化还原对;且其地结构上与α-Bi_2(MoO_4)_3相匹配,这些因素都有助于促进催化体系中电子和氧物种的传递及催化剂表面活性中心的再生,从而提高催化性能.Bi_3(FeO_4)(MoO_4)_2在反应条件下也可形成Fe~(3+)/Fe~(2+)氧化还原对,但由于其Fe~(3-)所处的化学环境与Fe_2(MoO_4)_3很不相同,且Fe的含量也不及Fe_2(MoO_4)_3,因此它在促进催化体系中电子和氧物种的传递及催化剂表面活性中心的再生等方面的性能较差,但它对提高催化剂表面的活性中心(Bi-Mo对)数目有贡献. 相似文献