全文获取类型
收费全文 | 183篇 |
免费 | 17篇 |
国内免费 | 18篇 |
专业分类
化学 | 128篇 |
晶体学 | 1篇 |
力学 | 10篇 |
综合类 | 4篇 |
数学 | 52篇 |
物理学 | 23篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 7篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 5篇 |
2014年 | 9篇 |
2013年 | 24篇 |
2012年 | 11篇 |
2011年 | 14篇 |
2010年 | 14篇 |
2009年 | 10篇 |
2008年 | 9篇 |
2007年 | 10篇 |
2006年 | 9篇 |
2005年 | 8篇 |
2004年 | 4篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有218条查询结果,搜索用时 0 毫秒
41.
The design and synthesis of a new family of potentially pentadentate N3Se2 or N3Te2 type donors bearing a 2,6-disubstituted pyridine dicarboxamide moiety as the central fragment [-NH-C(O)-pyridine-C(O)-NH-] functionalized with chalcogen as additional donors in the appended arms of the pyridine ring through the alkyl spacers and their potential applications and reactivity toward d8 and d10 metal ions have been demonstrated. 相似文献
42.
针对已有文献大多探讨能源价格与碳价格间的影响程度,本文从建模的角度寻找碳价格与能源价格间的联动关系。首先,使用随机微分方程刻画碳与能源的价格走势,得到碳——能源联动模型解析解。其次,在解析解的基础上,分别讨论能源价格如何通过影响碳市场价格均值、波动率路径从而影响整个碳价格。第三,分析重大能源政策产生的跳跃对碳价格的影响。结果显示,随着能源与碳市场关联程度的增加,相较于能源价格通过均值路径影响碳价格,其通过波动率路径影响碳价格的效果更为明显;且跳跃路径下的碳价格震荡小于波动率路径下能源价格传导引起的碳价格震荡。本文的结果对理清碳——能源价格联动关系具有积极意义,为投资者规避碳市场风险提供必要理论指导。 相似文献
43.
《Journal of Coordination Chemistry》2012,65(3):395-407
Abstract Crystal structures were obtained for the 3(C),2′;6′,3″(C)-linked bispyrazolylpyridines 2,6-di(2H-4,5,6,7-tetrahydroindazol-3-yl)pyridine (1), 2,6-di(l-methyl-4,5,6,7-tetrahydroindazol-3-yl)pyridine (2), 2,6-di(1 -(4-ethoxycarbonylphenyl)-4,5,6,7-tetrahydroindazol-3-yl)pyridine (3) and for the homoleptic RuII complex of 2, [Ru(2)2]Cl2, which crystallized with 7 molecules of CHCl3. Ligand 1 adopts the inter-and intramolecularly hydrogen-bonded syn,syn rotameric conformation, while 2 and 3 were in the anti,anti forms. Relative to the latter, iigand distortions were assessed in 1 (considered as a H+ complex) and [Ru(2)2]Cl2. Comparisons were drawn with other tridentate ligands containing a pyridine nucleus, specifically the 1(N),2′;6′,1″(N″) linkage isomers and 2,2′;6′,2″-terpyridine, in both free and RuII complexed forms, as well as with their bidentate analogues. Unlike with bidentate ligands, the bonds to the pyridine moiety are shortest, the outer heterocyclic rings are drawn inward and, overall, the ligands remain fairly planar. Flanking substituents remain well splayed out in the 1,2′;6′,1″-linked bispyrazolylpyridines, are more parallel in the 3,2′;6′,3″ linkage isomers and are unfavorably compressed in terpyridines. 相似文献
44.
《Acta Crystallographica. Section C, Structural Chemistry》2018,74(8):882-888
An unusual heterobimetallic bis(triphenylphosphane)(NO2)AgI–CoIII(dimethylglyoximate)(NO2) coordination compound with both bridging and terminal –NO2 (nitro) coordination modes has been isolated and characterized from the reaction of [CoCl(DMGH)2(PPh3)] (DMGH2 is dimethylglyoxime or N,N′‐dihydroxybutane‐2,3‐diimine) with excess AgNO2. In the title compound, namely bis(dimethylglyoximato‐1κ2O,O′)(μ‐nitro‐1κN:2κ2O,O′)(nitro‐1κN)bis(triphenylphosphane‐2κP)cobalt(III)silver(I), [AgCo(C4H7N2O2)2(NO2)2(C18H15P)2], one of the ambidentate –NO2 ligands, in a bridging mode, chelates the AgI atom in an isobidentate κ2O,O′‐manner and its N atom is coordinated to the CoIII atom. The other –NO2 ligand is terminally κN‐coordinated to the CoIII atom. The structure has been fully characterized by X‐ray crystallography and spectroscopic methods. Density functional theory (DFT) and time‐dependent density functional theory (TD‐DFT) have been used to study the ground‐state electronic structure and elucidate the origin of the electronic transitions, respectively. 相似文献
45.
酸敏性PEG载体的合成及其在多肽合成中的应用 总被引:1,自引:0,他引:1
本文通过聚苯乙烯固载聚乙二醇氨基树脂与羟甲基苯氧乙酸缩合制备了具有酸敏手臂结构的对羟甲基苯氧乙酰胺PEG树脂。在合成中改进了PS-PEGNH2树脂的制备方法,提高了树脂上功能基的转化率,不必进行封闭剩余活性基的操作,就得到具有单一功能基的树脂。 相似文献
46.
Vinylene-linked covalent organic frameworks(COFs) are a class of promising porous organic materials that feature fully π-conjugated structures, high crystallinity, permanent porosity, ultrahigh chemical stability, and extraordinary optoelectronic properties. Over the past 5 years, this kind of material has been witnessed rapid development either in chemical synthesis or in potential applications. In this review, we summarize the chemistry to synthesize vinylene-linked COFs, especially the synthetic strategies involving activation of aryl methyl groups for condensation reaction. We then scrutinize the state-of-the-art development in properties and functions of this kind of COFs. Our own opinions on the further development of the vinylene-linked COFs are also presented for discussion. 相似文献
47.
48.
王文举 《纯粹数学与应用数学》1999,15(1):25-31
给出了连锁类的几个不变性质,得到:在CM局部环中,广义CM性是连锁类的不变性质;强广义CM性是偶连锁类的不变性质;在正则局部环中,余维数k≤3可光滑性是连锁类的不变性质。 相似文献
49.
A dominant gene, Pml2, conferring the resistance to powdery mildew (Erysiphe graminis) has been transferred to wheat from Aegilops speltoides. Sixteen RFLP probes were used to test Line 31 and its parents, showing that Line 31 is a 6B/6S translocation lines. The linkage analysis by five probes indicates that Pm12 is located on the chromosome 6B/6S, and tightly flanked by an RFLP marker α-Amy-1 (1.1 cM), identified by RFLP and isozyme analysis. This approach is equally applicable to the identification of other transferred alien genes and the segments of alien chromosome introgressed into wheat. 相似文献
50.
N. N. Bolotnik F. L. Chernousko S. A. Kumakshev F. Pfeiffer 《Archive of Applied Mechanics (Ingenieur Archiv)》1999,69(7):429-442
Summary The static interaction of a two-member linkage with a given surface is investigated. Dry friction acts at the point of contact
of the linkage with the surface. The linkage has two drives generating torques at its joints. The optimal distribution of
the joint torques is determined to maximize the friction force at the point of contact. The dependence of this maximal force
on the lengths of the links and on the linkage configuration is investigated. The results obtained can be applied to the analysis
and optimization of various robotic systems, in particular, manipulators interacting with rough surfaces and walking machines,
especially tube-crawling robots.
Received 21 December 1998; accepted for publication 25 February 1999 相似文献