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91.
E. Yu. Yagudaeva M. R. Muidinov D. V. Kapustin V. P. Zubov 《Russian Chemical Bulletin》2007,56(6):1166-1173
Polyaniline coatings of the cation-exchange resin Dowex and a synthetic composite material based on silica gel surface-modified
by a sulfated styrene-divinylbenzene copolymer were prepared by precipitative polymerization of aniline on the surface of
the supports. The optimal conditions for the preparation of the polyaniline-containing material providing the formation of
a thin polymeric coating on the support surface were determined. Aniline is predominantly consumed to the formation of a uniform
polymeric coating about 3 nm thick with an increase in the concentration of sulfo groups on the support surface. The efficiency
of using the polyaniline-containing sorbents for the preparative isolation of DNA from plant tissue lysates was demonstrated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1123–1130, June, 2007. 相似文献
92.
Phosphinophosphiniden-Phosphorane tBu2P?P = P(R)tBu2 aus Li(THF)2[η2-(tBu2P)2P] und Alkylhalogeniden
The Phosphinophosphinidene-phosphoranes tBu2P? P = P(R)tBu2 from Li(THF)2[η2-(tBu2P)2P] and Alkyl Halides We report the formation of tBu2P? P = P(R)tBu2 a and (tBu2)2PR b (with R = Me, Et, nPr, iPr, nBu, PhCH2, H2C = CH? CH2 and CF3) reactions of Li(THF)2[η2-(tBu2P)2P] 2 with MeCl, MeI, EtCl, EtBr, nPrCl, nPrBr, iPrCl, nBuBr, PhCH2Cl, H2C = CH? CH2Cl or CF3Br. In THF solutions the ylidic compounds a predominate, whereas in pentane the corresponding triphosphanes b are preferrably formed. With ClCH2? CH = CH2 only b is produced; CF3Br however yields both tBu2P? P = P(Br)tBu2 and tBu2P? P = P(CF3)tBu2, but no b . The ratio of a:b is influenced by the reaction temperature, too. The compounds tBu2P? P = P(Et)tBu2 4a and (tBu2P)2PEt 4 b , e. g., are produced in a ratio of 4:3 at ?70°C in THF, and 1:1 at 20°C; whereas 1:1 is obtained at ?70°C in pentane, and 1:2 at 20°C. Neither tBuCl nor H2C = CHCl react with 2 . The compounds a decompose thermally or under UV irradiation forming tBu2PR and the cyclophosphanes (tBu2P)nPn. 相似文献
93.
Nenajdenko V. G. Korotchenko V. N. Shastin A. V. Balenkova E. S. 《Russian Chemical Bulletin》2004,53(5):1034-1064
The review is devoted to a new catalytic olefination reaction (COR) discovered by the authors. This is the reaction between N-unsubstituted hydrazones of carbonyl compounds with dihalides CHal2XY in the presence of copper(i) chloride to give substituted alkenes. Catalytic olefination is versatile. Variation of the carbonyl and olefinating components opens up the way for the synthesis of various classes of unsaturated compounds including those containing functional groups. The reaction mechanism is discussed and a catalytic cycle describing the process is proposed. A model for estimating and predicting the reactivity of halogen-containing compounds in the COR is developed. The relationship between the structure of the carbonyl substrates and their behavior in the title reaction is elucidated. 相似文献
94.
S. Ravi Kanth D. Maitraie P. Shanthan Rao B. Sridhar 《Journal of fluorine chemistry》2006,127(9):1211-1221
Three-component Grieco condensation reaction of 3-aminopyrazolo[3,4-b]pyridine, formaldehyde/benzaldehyde and electron rich alkenes in presence of iron(III) chloride gave tetrahydropyrido[2′,3′:3,4]pyrazolo[1,5-a]pyrimidines/quinazolines in single pot. The sequence of reactions is formation of di-azadiene in situ and the subsequent regioselective addition of alkenes in aza-Diels Alder type reaction. The structure and stereochemistry of the products were confirmed by spectral data and single crystal X-ray crystallography. 相似文献
95.
A. Lévai 《Monatshefte für Chemie / Chemical Monthly》1995,126(11):1245-1251
Summary 3-Aroyl-4-aryl-2-pyrazolines (21–40) have been synthesized by the reaction of ,-unsaturated ketones (1–20) with diazomethane. These 2-pyrazolines gave -methyl-,-unsaturated ketones (41–46) on thermal denitrogenation.Dedicated to Prof. Dr.F. Sauter on the occasion of his 65th birthday 相似文献
96.
The interfacial tension of aqueous dodecyltrimethylammonium chloride (DTAC) solution/hexane interface has been measured as a function of pressure at concentrations around the critical micelle concentration (CMC). The derivative of the interfacial tension with respect to pressure has been observed to change abruptly at the CMC as in the case of aqueous dodecylammonium chloride (DAC) solution-hexane system studied already. The volume changes associated with the adsorption of DTAC from its monomeric and micellar states have been calculated. The results have indicated that the micelle formation of surfactant is treated like the appearance of a new macroscopic phase in the system. It has also been concluded that the micelle solubilizing hexane bears resemblance to the adsorbed film in terms of the volume. The difference in the pressure dependence of the volume of micelle formation
MW between DTAC and DAC has been attributed to a larger polar group of DTAC. The fact that the value of
MW is larger than that estimated from the conductivity data has been explained by the solubilization of hexane into the micelle. 相似文献
97.
Determination of Aldehydes and Ketones in Fuel Ethanol by High-Performance Liquid Chromatography with Electrochemical Detection 总被引:1,自引:0,他引:1
A. A. Saczk L. L. Okumura M. F. de Oliveira M. V. B. Zanoni N. R. Stradiotto 《Chromatographia》2006,63(1-2):45-51
A new methodology was developed for analysis of aldehydes and ketones in fuel ethanol by high-performance liquid chromatography
(HPLC) coupled to electrochemical detection. The electrochemical oxidation of 5-hydroxymethylfurfural, 2-furfuraldehyde, butyraldehyde,
acetone and methyl ethyl ketone derivatized with 2,4-dinitrophenylhydrazine (DNPH) at glassy carbon electrode present a well
defined wave at +0.94 V; +0.99 V; +1.29 V; +1.15 V and +1.18 V, respectively which are the basis for its determination on
electrochemical detector. The carbonyl compounds derivatized were separated by a reverse-phase column under isocratic conditions
with a mobile phase containing a binary mixture of methanol / LiClO4(aq) at a concentration of 1.0 × 10−3 mol L−1 (80:20 v/v) and a flow-rate of 1.1mL min−1 . The optimum potential for the electrochemical detection of aldehydes-DNPH and ketones-DNPH was +1.0 V vs. Ag/AgCl. The
analytical curve of aldehydes-DNPH and ketones-DNPH presented linearity over the range 5.0 to 400.0 ng mL−1, with detection limits of 1.7 to 2.0 ng mL−1 and quantification limits from 5.0 to 6.2 ng mL−1, using injection volume of 20 μL. The proposed methodology was simple, low time-consuming (15 min/analysis) and presented
analytical recovery higher than 95%. 相似文献
98.
Natural dolomite powders obtained from caves which give unusual high resistance building materials, have been decomposed in a Knudsen cell at high CO2 pressures in the temperature range of 913-973 K. XRD traces for the final solid products, after the first half thermal decomposition, have shown, that beside the XRD patterns for the calcite and MgO, the existence of a new structure with major peaks at 2θ equal to 38.5 and 65°. This finding has been ascribed to a solid solution of MgO in calcite. The kinetic analysis of the TG curves yield a total apparent enthalpy (ΔH∗) for the decomposition equal to 440±10 kJ mol−1 for a range of fraction decomposed (α) varying between 0.2 and 0.7. This value is much closer to the theoretical expected at 950 K value ΔH=486 kJ mol−1 for the dolomite decomposition in CO2 environment, where CaO, MgO and oxides of solid solution can be the solid reaction products. The rate determining step is the transport of CO2 across the reacting interface through an high activated thermal process due to solid state diffusion of CO32− in the bulk and/or the grain boundaries phases of CaCO3 and/or of the solid solution. The microstructure evolution of the solid products follows a shear-transformation mechanism. At temperatures below 943 K, porous product particles are characterized by a monomodal narrow pore size distribution around 0.05 μm. At higher temperatures, a critical level of tensions inside the particles is reached and a bimodal pore size distribution around 1 and 0.05 μm is formed. 相似文献
99.
Khaja Basheeruddin Vicki Rothman Simeon Margolis 《Applied biochemistry and biotechnology》1985,11(2):133-140
We have immobilized E.coli alkaline phosphatase (EC 3.1.3.1) by linking it covalently to sepharose 4B. This preparation has several advantages over
the soluble enzyme. The immobilized enzyme is easily separable from other constituents in incubation mixtures. The immobilized
enzyme can be reused repeatedly and is more stable than the soluble enzyme to heat treatment in the presence of 10 mM Mg2+. The insoluble and soluble phosphatases removed 75 and77%, respectively, of the inorganic phosphorus from casein. The immobilized enzyme inactivated two enzymes believed to be active
in the phosphorylated state, acyl-CoA : cholesterol acyltransferase (ACAT) by 39% and NADPH-cytochrome P-450 reductase by
89%. The utility of immobilized alkaline phosphatase for studying the phosphorylation and dephosphorylation of soluble or
membrane-bound enzymes and proteins is discussed. 相似文献
100.
Polyfluoroalkyl-containing aziridinyl ketones, unlike their nonfluorinated analogs, react with hydrogen halides to give only -halo- -anvnoketones or their hydrogen halide salts. Thermal decomposition of the latter in the case where Hal = CI affords -chlorovinyl ketones.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 684–686, March, 1996. 相似文献