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101.
Luzian Porwol Daniel J. Kowalski Alon Henson De‐Liang Long Nicola L. Bell Leroy Cronin 《Angewandte Chemie (International ed. in English)》2020,59(28):11256-11261
We present a chemical discovery robot for the efficient and reliable discovery of supramolecular architectures through the exploration of a huge reaction space exceeding ten billion combinations. The system was designed to search for areas of reactivity found through autonomous selection of the reagent types, amounts, and reaction conditions aiming for combinations that are reactive. The process consists of two parts where reagents are mixed together, choosing from one type of aldehyde, one amine and one azide (from a possible family of two amines, two aldehydes and four azides) with different volumes, ratios, reaction times, and temperatures, whereby the reagents are passed through a copper coil reactor. Next, either cobalt or iron is added, again from a large number of possible quantities. The reactivity was determined by evaluating differences in pH, UV‐Vis, and mass spectra before and after the search was started. The algorithm was focused on the exploration of interesting regions, as defined by the outputs from the sensors, and this led to the discovery of a range of 1‐benzyl‐(1,2,3‐triazol‐4‐yl)‐N‐alkyl‐(2‐pyridinemethanimine) ligands and new complexes: [Fe(L1)2](ClO4)2 ( 1 ); [Fe(L2)2](ClO4)2 ( 2 ); [Co2(L3)2](ClO4)4 ( 3 ); [Fe2(L3)2](ClO4)4 ( 4 ), which were crystallised and their structure confirmed by single‐crystal X‐ray diffraction determination, as well as a range of new supramolecular clusters discovered in solution using high‐resolution mass spectrometry. 相似文献
102.
Natural selection acts on genetic variation that comes from two principal sources: mutation and recombination. Because of the inherent differences between mutation and recombination, it is often assumed that they are qualitatively different ways to explore the genotype space. In this paper a new way of constructing recombination spaces is introduced and the topological features of the resulting hypergraphs are analyzed. It is shown that types which are neighbors in the point mutation space are also neighbors in the recombination space, i.e., mutation and recombination spaces are homomorphic. This implies that the shapes of the fitness functions explored by mutation and recombination are similar. However, the potential of one- and two-point recombination operators to explore the fitness landscape may differ dramatically from uniform recombination operators or mutation operators because of the limited number of recombinant types they can produce. © 1996 John Wiley & Sons, Inc. 相似文献
103.
We introduce a Virtual Studio Technology (VST) 2 audio effect plugin that performs convolution reverb using synthetic Room Impulse Responses (RIRs) generated via a Genetic Algorithm (GA). The parameters of the plugin include some of those defined under the ISO 3382-1 standard (e.g., reverberation time, early decay time, and clarity), which are used to determine the fitness values of potential RIRs so that the user has some control over the shape of the resulting RIRs. In the GA, these RIRs are initially generated via a custom Gaussian noise method, and then evolve via truncation selection, random weighted average crossover, and mutation via Gaussian multiplication in order to produce RIRs that resemble real-world, recorded ones. Binaural Room Impulse Responses (BRIRs) can also be generated by assigning two different RIRs to the left and right stereo channels. With the proposed audio effect, new RIRs that represent virtual rooms, some of which may even be impossible to replicate in the physical world, can be generated and stored. Objective evaluation of the GA shows that contradictory combinations of parameter values will produce RIRs with low fitness. Additionally, through subjective evaluation, it was determined that RIRs generated by the GA were still perceptually distinguishable from similar real-world RIRs, but the perceptual differences were reduced when longer execution times were used for generating the RIRs or the unprocessed audio signals were comprised of only speech. 相似文献
104.
This work investigates the detection of binary neutron stars gravitational wave based on convolutional neural network(CNN).To promote the detection performance and efficiency,we proposed a scheme based on wavelet packet(WP)decomposition and CNN.The WP decomposition is a time-frequency method and can enhance the discriminant features between gravitational wave signal and noise before detection.The CNN conducts the gravitational wave detection by learning a function mapping relation from the data under being processed to the space of detection results.This function-mapping-relation style detection scheme can detection efficiency significantly.In this work,instrument effects are con-sidered,and the noise are computed from a power spectral density(PSD)equivalent to the Advanced LIGO design sensitivity.The quantitative evaluations and comparisons with the state-of-art method matched filtering show the excellent performances for BNS gravitational wave detection.On efficiency,the current experiments show that this WP-CNN-based scheme is more than 960 times faster than the matched filtering. 相似文献
105.
106.
超导量子电路已成为实现量子计算机的主流技术路线之一,其中四分之一波长超导谐振腔主要用于读取量子比特的状态信息,是实现超导量子电路的关键器件.本文设计了四分之一波长超导谐振腔,利用两种电磁仿真算法(有限元法以及矩量法),对超导谐振腔的传输特性进行建模仿真验证.制备出了设计的超导谐振腔样品,在20±5 mK的低温环境下对其传输特性进行测量.通过仿真结果与设计值和实测值进行对比研究,发现基于矩量法的sonnet软件在仿真准确性、仿真速率以及资源消耗等方面都优于基于有限元法的HFSS软件.同时研究了谐振腔之间的串扰对仿真精度的影响,当谐振腔数目不多时,其相互之间串扰的影响几乎可以忽略. 相似文献
107.
Ping Zhang 《Entropy (Basel, Switzerland)》2022,24(2)
Shinagawa and Iwata are considered quantum security for the sum of Even–Mansour (SoEM) construction and provided quantum key recovery attacks by Simon’s algorithm and Grover’s algorithm. Furthermore, quantum key recovery attacks are also presented for natural generalizations of SoEM. For some variants of SoEM, they found that their quantum attacks are not obvious and left it as an open problem to discuss the security of such constructions. This paper focuses on this open problem and presents a positive response. We provide quantum key recovery attacks against such constructions by quantum algorithms. For natural generalizations of SoEM with linear key schedules, we also present similar quantum key recovery attacks by quantum algorithms (Simon’s algorithm, Grover’s algorithm, and Grover-meet-Simon algorithm). 相似文献
108.
自20世纪70年代开始,随着计算复杂性理论的建立,近似算法逐渐成为组合优化的重要研究方向。作为第一批研究对象,装箱问题引起了组合优化领域学者的极大关注。装箱问题模型简单、拓展性强,广泛出现在各种带容量约束的资源分配问题中。除了在物流装载和材料切割等方面愈来愈重要的应用外,装箱算法的任何理论突破都关乎到整个组合优化领域的发展。直到今天,对装箱问题近似算法的研究仍如火如荼。本文主要针对一维模型,简述若干经典Fit算法的发展历程,分析基于线性规划松弛的近似方案的主要思路,总结当前的研究现状并对未来的研究提供一些参考建议。 相似文献
109.
通过对共享保护算法的深入分析,使用K条最短路和迭代思想的方法,提出了两种共享风险链路组不相关的共享保护算法,并在仿真平台上对两种算法的性能进行了仿真.KWFF算法借鉴了传统的K条最短路策略,并且在每一个波长平面上,都对新到业务进行了K条工作路由的计算,极大挖掘了网络中潜在的波长资源.而IFF算法由于引入了迭代的思想,避免了共享风险链路组问题中,所特别有“陷阱”问题的出现,并且利用两套权重计算公式,在计算工作路由和保护路由的时候,充分考虑了网络资源的实时变化情况.通过仿真数据可以看到,与以往算法相比,KWFF和IFF算法大大降低了网络阻塞率,并且提高了网络资源的使用效率. 相似文献
110.