Thin Poly(Di(Ethylene Glycol)Methyl Ether Methacrylate) Homopolymer Brushes Allow Controlled Adsorption and Desorption of PaTu 8988t Cells

Poly(di(ethylene glycol)methyl ether methacrylate) (PDEGMA) brushes, which are known to suppress protein adsorption and prevent cell attachment, are reported here to possess interesting and tunable thermoresponsive behavior, if the brush thickness is reduced or the grafting density is altered. PDEGMA brushes with a dry ellipsometric thickness of 5 ± 1 nm can be switched from cell adherent behavior at 37 °C to cell nonadherent at 25 °C. This behavior coincides with the temperature‐dependent irreversible adsorption of fibronectin from phosphate saline buffer and proteins present in the cell culture medium, as unveiled by surface plasmon resonance measurements. Unlike for tissue culture polystyrene reference surfaces, swelling of the PDEGMA chains below the lower critical solution temperature results in the absence of paxillin and actin containing cellular filaments responsible for cell attachment. These tunable properties of very thin homopolymer PDEGMA brushes render this system interesting as an alternative thermoresponsive layer for continuous cell culture or enzyme‐free cell culture systems.

     

IrIII‐based Octahedral Metalloligands Derived Primitive Cubic Frameworks for Enhanced CO2/N2 Separation

We developed a metalloligand strategy to construct porous frameworks, viz. the combined use of Ir^III‐based octahedral metalloligands and the linear unit [Ni(cyclam)] easily afforded two isostructural complexes 1 and 2 with primitive cubic frameworks. Both complexes show good CO₂/N₂ separation property.     

Subspace arrangements as generalized star configurations

In this note, we show that any projective subspace arrangement can be realized as a generalized star configuration variety. This type of interpolation result may be useful in designing linear codes with prescribed codewords of minimum weight, as well as in answering a couple of questions about the number of equations needed to define a generalized star configuration variety.     

黏弹性层合圆柱壳的蠕变分岔屈曲

采用Boltzmann积分型本构关系描述铺设单层的黏弹性力学行为,基于DMV扁壳假定和Kármán- Donnell几何非线性关系,研究了对称铺设黏弹性层合圆柱壳的前屈曲变形特征和分岔蠕变屈曲．对玻璃纤维/环氧树脂基复合材料层合圆柱壳的分析结果表明,在前屈曲阶段,挠曲变形和环向薄膜力随时间的变化趋势主要取决于圆柱壳的铺设方式,可以呈现完全相反的变化特征；层合短圆柱壳两端的边界条件对其蠕变分岔屈曲行为有决定性的影响,径厚比的增加将使分岔形式的延迟失稳现象更加明显．     

Der Einfluß des Zusatzes von Hemicellulosen auf die Fließeigenschaften von Weizenmehlteig

The water adsorption capacity of a dough consisting of wheat flour was increased linearly by the addition of water-insoluble hemicelluloses (xylane, mannane etc.) extracted from beech-wood pulp using soda lye (a by-product of viscose fiber production). The investigation of this finding by viscosity measurements revealed two reasons for the higher water uptake: 1) a higher kneading resistance of the dough, and 2) a gel-regeneration of the kneaded dough during the dough-rest.

Herrn Prof. Dr. Josef Schurz zum 60. Geburtstag gewidmet.     

铝材轧制过程中润滑添加剂吸附特性研究

依据铝材轧制过程中润滑油添加剂浓度对摩擦因数的影响，同时以Ｔｅｍｋｉｎ吸附理论为基础，设定添加剂分子在摩擦表面的覆盖率与摩擦因数的联系，提出了铝材轧制过程中润滑添加剂吸附有的求解方法，还定义了铝材轧制时润滑添加剂饱和吸附最低浓度的概念，通过二辊轧机测定了在不同添加剂浓度时纯铝材轧制过程中的摩擦因数，并且计算了相应的润滑添加剂的吸附自由能及其饱和吸附最低浓度，表明理论分析结果与实测结果具有良好的一致     

硼原子掺杂对碳纳米管吸附Ne原子影响的第一性原理计算

采用基于第一性原理的密度泛函理论(DFT)和局域密度近似(LDA)方法,优化计算得到碳纳米管(CNT),硼原子取代碳原子及其吸附氖原子前后系统的几何结构,能量,电子能带和态密度.结果显示,碳纳米管的能带结构与石墨的层状几何结构相似,能量的变化只在kz=0和kz=0.5平面之间沿着c轴方向出现.B原子取代C原子使价带和导带分别分裂为两个和三个能带.对Ne原子的吸附使价带能量沿着c轴方向升高并导致Fermi面附近的态密度下降.Ne原子的吸附在谷位H最稳定,顶位A其次.C-C间σ键的弯曲使Ne原子吸附在桥位b1比桥位b2处更为稳定.Ne原子在管外的吸附均为放热过程,而管内则为吸热过程.结构分析表明Ne原子对C原子有排斥作用,对B原子却具有吸引作用.B原子取代C原子的位置略凸出于CNT的管壁之外,使Ne原子的吸附能增加.     

MilCAN总线同步及调度配置方法

MilCAN作为一种以陆军地面武器平台应用为目标的CAN高层协议,核心是通过时序控制保证总线通信的实时性和确定性;为了增强MilCAN总线通信时序控制,提出一种新的MilCAN总线同步和调度配置方法;采用STM32微控制器对MilCAN总线主控节点进行设计,将总线同步和总线调度配置任务集成至专用的主控节点进行,同时开展了总线通信测试;测试结果表明：以该方法设计的MilCAN总线主控节点可有效完成同步和总线调度配置任务,同步精度较高,性能稳定可靠。     

Methods for describing open‐shell systems: Following the trail of Rosa Caballol's research

On the occasion of the celebration of Prof. Rosa Caballol's 65's birthday, a symposium was organized by the Quantum Chemistry Group of the Universitat Rovira i Virgili (Tarragona, Spain) under the title “Theoretical Chemistry in Spain told by women.” The symposium gave a representative illustration of the research in theoretical chemistry in Spain, which is not only very diverse, but also in many areas at the forefront of the field. In this article, we summarize the contributions made by Rosa Caballol and coworkers. Emphasis lies on the developments of wave function based methods to accurately describe electron correlation effects in systems with unpaired electrons. Besides discussing some illustrative applications, we will also explore the limits of the existing methods and outline the perspectives of how one can possibly overcome them. © 2014 Wiley Periodicals, Inc.     

一系列基于混合配体策略构筑的金属有机骨架的合成、结构及性质

通过简单高效的醛酮缩合反应,合成了碱性配体2,6-二（4-吡啶基亚甲基）环己酮（BPCH）,采用3种芳香羧酸配体：对苯二甲酸（H₂TP）、间苯二甲酸（H₂IP）和均苯三甲酸（H₃TMA）,以混合配体策略制备了7例金属有机骨架（MOFs）。用单晶X射线衍射、红外光谱、粉末X射线衍射和热重分析对其进行表征并分析其拓扑结构。MOFs1、2、3均呈现为多样的三维结构,MOFs4~7表现为同构的二维结构。荧光测试结果显示该类化合物对Fe³⁺有较好的荧光猝灭效应,同时对于染料具有一定的吸附能力。