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951.
952.
Intense Raman scattering by acetophenone molecules adsorbed on colloidal silver particles is reported. Greater enhancement
is observed for the ring breathing and ring stretching vibrations. The orientation determination analysis shows that the adsorption
of acetophenone molecule is neither through its co-ordinating site nor through itsπ-orbital system and there is no strong chemical interaction. However significant intensity enhancement for several vibrations
suggests that the contribution is from classical electromagnetic field on the rough surface. 相似文献
953.
Modified semiempirical Interacting Bonds Method in the slab approximation with due regard for relaxation after free surface formation was used to calculate surface energies and heats of oxygen adsorption for various faces of hematite. The results obtained explained faceting of some faces after high-temperature annealing and formed bases for analysis of the structure sensitivity of CO oxidation reaction catalyzed by oxides with corundum-type structures. 相似文献
954.
We generalize previous stochastic classical trajectory-ghost atom calculations for describing palladium deposition onto the Ni(111) surface between 0.1 and 0.5 monolayers. The growth evolves through two-dimensional islands. The islands are formed following the downward funneling mechanism. Surface temperature does not affect the island growth. 相似文献
955.
956.
利用在束γ谱学方法,通过反应144Sm(28Si,1p3n)169Re研究了169Re的激发态能级结构.实验进行了X-γ符合、γ-γ符合、DCO系数和带内B(M1)/B(E2)比率测量.基于这些测量,建立了组态为π9/2-[514]的强耦合带和组态为π1/2-[541]的退耦合带.通过比较169Re的转动带与邻近奇质子核已知转动带的结构和B(M1)/B(E2)比率,指定了169Re转动带的组态.实验观测到π9/2-[514]和π1/2-[541]转动带的中子AB带交叉的转动频率分别为0.23和0.27MeV.着重讨论了169Re转动带的中子AB带交叉频率、转动角动量顺排和旋称劈列等,并讨论了奇ARe核转动带结构的系统性 相似文献
957.
958.
V. V. Shelukhin 《Journal of Applied Mechanics and Technical Physics》2005,46(4):513-522
Models for the sedimentation of particles suspended in solution are proposed that take into account mass transfer between the liquid fraction of the solution and the particles. The structure and velocity of the concentration wave describing the upward extension of the zone with a high concentration of the solid phase are studied using a kinematic model with the Froude number as a small parameter. It is established that the concentration-wave velocity becomes lower if the sorption parameter is set equal to zero, i. e., if the sorption properties of the suspended particles are ignored.__________Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 4, pp. 66–77, July–August, 2005. 相似文献
959.
通过融合蒸发反应144Nd(19F,5n)布居了双奇核158Tm的高自旋态. 扩展了原来已知的带结构, 并建立了一条新转动带. 通过与相邻核的比较, 讨论158Tm核中两条四准粒子带的内禀组态, 并分别指定为πh11/2\otimes νh9/2(α=+1/2)\otimes (νi13/2)2和πh11/2\otimes νh9/2(α=-1/2)\otimes (νi13/2)2
组态. 建立在πh11/2\otimes νi13/2组态上的转动带被观测到呈现持续旋称反转现象, 而前述的两条高自旋区的
四准粒子转动带也呈旋称反转. 对这两种类型的旋称反转现象的可能机制进行了简单而定性的讨论. 相似文献
960.
Two random-walk related problems which have been studied independently in the past, the expected maximum of a random walker
in one dimension and the flux to a spherical trap of particles undergoing discrete jumps in three dimensions, are shown to
be closely related to each other and are studied using a unified approach as a solution to a Wiener-Hopf problem. For the
flux problem, this work shows that a constant c = 0.29795219 which appeared in the context of the boundary extrapolation length, and was previously found only numerically,
can be derived analytically. The same constant enters in higher-order corrections to the expected-maximum asymptotics. As
a byproduct, we also prove a new universal result in the context of the flux problem which is an analogue of the Sparre Andersen
theorem proved in the context of the random walker's maximum. 相似文献