沉积铁钝化膜的傅立叶变换表面增强拉曼光谱

利用恒电流沉积技术、傅立叶变换表面增强拉曼散射技术现场研究了0 1mol/LNaOH溶液中铁金属电极在不同电位下的表面氧化物的组成。结果表明,在电极预钝化区,表面首先生成的Fe(OH)2可由拉曼谱图中出现的550cm-1表征,证实了以往的研究结果。进入钝化区,表面二价氧化物逐步转化为高价氧化物Fe3O4及α 、δ 和γ FeOOH。在电位回扫的过程中,各氧化产物的还原以及铁表面SERS活性的逐渐消失导致谱峰强度降低。     

Capacity Constrained Transit Assignment with Common Lines

This paper proposes the use of absorbing Markov chains to solve the capacity constrained transit network loading problem taking common lines into account. The approach handles congested transit networks, where some passengers will not be able to board because of the absence of sufficient space. The model also handles the common lines problem, where choice of route depends on frequency of arrivals. The mathematical formulation of the problem is presented together with a numerical example. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mechanism in homogeneous catalysis; NMR as a prime mover

An overview of the contribution of NMR to the development of our understanding of homogeneous catalysis is presented, with an emphasis on work from the author’s research group.     

Load-Carrying Capacity of Circular Plates Made of a Fiber-Reinforced Composite

The load-carrying capacity of circular plates made of a fiber-reinforced composite and loaded with axisymmetric transverse forces under axisymmetric boundary conditions is investigated. The plates can be freely supported or clamped along their contour. To the known yield condition used, in the plane of main bending moments, there correspond irregular hexagons, which depend on the mechanical properties of composite constituents and some characteristic geometrical parameters. It is shown that, depending on the ratio of ultimate radial and circumferential bending moments, in the plastic state, the circular plates (the central part of the clamped plates) take the form of a cone or a frustum of cone. For each of the cases, the limit load is found, which is a function of the above-mentioned mechanical parameters. The statically allowable fields of bending moments and the corresponding allowable fields of deflection rates are determined. The solutions found are exact. Special cases for the freely supported plates are analyzed, and the results obtained are presented in the form of graphs.__________Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 2, pp. 177–192, March–April, 2005.     

Chip-calorimeter for small samples

A method for measuring heat capacities of small samples using a chip-calorimeter and a heat pulse technique is described. The theoretical background to calculate the heat transport properties and the heat capacity of the sample from the pulse response function is given. Problems and potentials of the method are discussed. An example is given.     

Wavelength dependence in photochemical vapor deposition of aluminum film using dimethylaluminum hydride

In photochemical vapor deposition of aluminum film on silicon using dimethylaluminum hydride, (CH₃)₂AlH, a surface reaction dominated below a (CH₃)₂AlH pressure of 0.3 m Torr at 200°C, which was induced only with the 160 nm band emitted from a deuterium lamp. A gas-phase reaction occurred above 0.3 mTorr at 200°C, which could be induced by both 160 nm and 240 nm emission bands from the lamp. To distinguish between surface ad gas-phase reactions, a thickness profile was used. At 240°C the surface reaction could be induced even by the 240 nm band, while the deposits formed under illumination of the two bands were thinner than those obtained with only the 240 nm band, indicating occurrence of vacuum ultraviolet (VUV)-enhanced desorption. The mechanism responsible for the observed wavelength dependence in unclear. The electrical resistivity of the films deposited at 200°C was 4.5 μΩ cm, which did not change with wavelength.     

光学薄膜在现代汽车工业中的应用

本文论述应用光学薄膜技术对汽车窗口玻璃和塑料的若干性能进行改进的技术发展水平，这些性能包括塑料表面的硬化，红外区的反射，紫外区的吸收，偏振化作用，双折射，憎水性以及光学角度选择性等，评论等离子体处理和物理蒸汽淀积薄膜工艺近来应用的一些例子。对于物理蒸汽淀积薄膜所提供的异常功能连同实际使用中它们的耐久性作了特殊的强调。     

Deposition of boron nitride on graphite at 1300 K

A method for the deposition of BN onto graphite and other substrates is described. Boron trichloride (BCl₃) and ammonia (NH₃) diluted with Ar were used as reacting gases. The deposition process was carried out at 1300 K as well as lower temperatures in an open system at pressures of 1 atm. The consequences of the introduction of hydrogen to the system were considered. It was demonstrated that the replacement of argon with hydrogen increases the efficiency of the process as well as the theoretical rate of BN deposition. However, the acceleration of the deposition seems to be unprofitable, because the resulting supersaturation leads to the formation of an amorphous phase. The modification of the experimental conditions were proposed.Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthday     

回旋管输出窗热性质的研究

一、引 言 输出窗是回旋管的能量输出端口,它的特性直接影响到回旋管的性能和寿命。输出窗的设计包括电特性和热特性的研究。当输出功率增加时,热特性的研究变得非常重要以便寻求合理有效的冷却措施。 输出窗由波导和介质片(块)两部分组成。回旋管的输出波导是圆波导,介质一般做成