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51.
Qing Tao Yu Ping Li Zhi Ming Bi Jun Luo Xiao Dan Gao 《中国化学快报》2007,18(5):554-556
Two new saponins named mongholicoside A (1) and mongholicoside B (2) were isolated from the aerial part of Astragalus membranaceus var. mongholicus. Their structures were determined by 1D and 2D NMR, ESI-MS techniques and chemical methods. 相似文献
52.
Two novel tricyclic diterpenoids rubescensins U (1) and V (2) were isolated from the leaves of Isodon rubescens var. taihangensis. They were elucidated as a 8,15-seco-ent-kauranoid and an ent-abietanoid, respectively, by 1D and 2D NMR spectra, and single crystal X-ray analysis. Compound 1 is the first example of an 8,15-seco-ent-kaurane from the plants genus Isodon. A discussion of their biogenesis is described. 相似文献
53.
Ping Tang Dong Lin Chen Qiao Hong Chen Xi Xian Jian Feng Peng Wang Department of Chemistry of Medicinal Natural Products West China College of Pharmacy Sichuan University Chengdu China 《中国化学快报》2007,18(6):700-703
Three new lycoctonine-type C19-diterpenoid alkaloids, laxicymine 1, laxicymisine 2, and laxicyminine 3 have been isolated from the whole herb of Delphinium laxicymosum var. pilostachyum W.T. Wang. Their structures were established by spectra data. 相似文献
54.
55.
Sheng‐Xiong Huang Jing Yang Wei‐Lie Xiao Yan‐Ling Zhu Rong‐Tao Li Li‐Mei Li Jian‐Xin Pu Xian Li Sheng‐Hong Li Han‐Dong Sun 《Helvetica chimica acta》2006,89(6):1169-1175
Three new terpenoids, pubinernoids A–C ( 1 – 3 ), together with six known sesquiterpenoids, were isolated from the leaves and stems of Schisandra pubescens var. pubinervis. The structures of the new compounds were established on the basis of extensive spectroscopic analyses, including application of 2D‐NMR spectroscopic techniques. A plausible formation of the sesquiterpenoid 2 is proposed (Scheme 2), starting from guaianediol ( 4 ) as the biogenetic precursor, which was also present in the extract. 相似文献
56.
PhytochemicalinvestigationontheneedlesofTaxuschinensisvar.mairei.resultedintheisolati=?nofthreenewbicyclictaxoids1--3alongwithtaxachitrieneA4'.Compoundl,lal, 14.5(c0.001,CHCI,),wasisolatedasacolorlessgummysubstance.TheiRspectrumshowedtheacetoxyanda,0-unsaturatedcarbonylsystembandsat1730and1650cm-l.HR-FAB-MSanalysisatm/z847.3152establishedthequasi-molecularforn'ulaasC.,H,=O.,Na([M Na] ,A(B-0.1mmu).ItsIH-NMRspectrum(Tablel)showedthecharacteristicsignalsoffourtertiarymethylgroupsoftaxo… 相似文献
57.
Yun‐Heng Shen Yong‐Qing Su Jun‐Mian Tian Sheng Lin Hui‐Liang Li Jian Tang Wei‐Dong Zhang 《Helvetica chimica acta》2010,93(12):2393-2396
A novel alkaloid with a unique indolo‐[1,7]naphthyridine nucleus, incargranine B, was isolated from the whole plant of Incarvillea mairei var. grandiflora (Wehrh.) Grierson . Its structure was determined by means of spectroscopic methods. 相似文献
58.
Sebastian Busch Katrin Schmitt Christian Erhardt Thomas Speck 《Journal of Raman spectroscopy : JRS》2010,41(5):490-497
We used surface‐enhanced Raman spectroscopy (SERS) to investigate ultrastructural changes in cell‐wall composition during the self‐repair of lacerated hypocotyls of Phaseolus vulgaris var. saxa. A detailed study of self‐repair mechanisms requires localized information about cell‐wall structure and morphology in addition to the chemical cell‐wall composition. Characteristic Raman and SER spectra yielded two‐dimensional maps of cross sections of P. vulgaris var. saxa visualizing chemical compositions in the walls of different cell types and during various repair phases. SERS substrate particles were produced by the reduction of gold chloride on the plant tissue surface and characterized with absorption spectroscopy, scanning electron microscopy and energy‐dispersive X‐ray spectroscopy. The SERS results were compared with stained cross sections of the same plant using dark‐field microscopy with focus on lignin and suberin contents in repairing cells. In addition, SERS measurements revealed Au cyanide compounds on the cell surface, indicating the formation of hydrogen cyanide during the self‐repair phase. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
59.
Jinzhi Liu Jun Ling Xin Li Zhiquan Shen 《Journal of molecular catalysis. A, Chemical》2009,300(1-2):59-64
The mechanism of -caprolactone (CL) insertion into a Y–OCH3 bond was investigated using density functional theory (DFT) calculations. The optimized geometries and corresponding Gibbs-free energies of the intermediates were obtained, which confirmed a four-step coordination-insertion mechanism. The coordination of CL onto yttrium center led to a nucleophilic addition of the carbonyl group of CL, followed by an intramolecular alkoxide ligand exchange. A monomer insertion was completed by the CL ring opening via acyl–oxygen bond cleavage. The formation of the five-coordinated yttrium intermediate, 3, was found to be the rate-determining step. This study could be applicable to ring-opening polymerisation (ROP) of CL initiated by lanthanide metal complexes. 相似文献
60.
Kouken Kaniwa Tomomi Sonoda Masahiko Hayashi Masami Ishibashi 《Tetrahedron letters》2006,47(26):4351-4354
Trichiol (1) and 3-epitrichiol acetate (2), two new sterols, have been isolated from field-collected fruit bodies of the myxomycete, Trichia favoginea var. persimilis, and their structures elucidated by spectral data. Trichiol (1) and 3-epitrichiol acetate (2) possess an unprecedented 2,6-dioxabicyclo[2.2.2]octan-3-one ring system. Trichiol (1) was cytotoxic against HeLa cells, while compound 2 proved to exhibit reversal effect against TNF-related apoptosis inducing ligand (TRAIL)-resistant Jurkat cell lines. 相似文献