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201.
Haiyan Chen Jizhi Dai Yongzhi Liu 《International Journal of Infrared and Millimeter Waves》2004,25(12):1791-1798
IR integrated photonic amplifiers at 1.55m operation will have good foreground in optical phasedarray radars for splitters and signal processing. The saturation gain characteristics of IR integrated photonic waveguide amplifiers (taken Er3+Yb3+ co-doped phosphate glass waveguide amplifiers as an example) are studied theoretically. For the homemade laser glass materials the calculated saturation intensities are 2.22kw /cm2 for signal and 10.15kw/cm2 for pump. The effects of absorption saturation of signal and pump lights on the gain of amplifiers are discussed. 相似文献
202.
A growing interest in biodegradable polymers and their biomedical and pharmaceutical applications has developed since the past decade. Ring-opening polymerization has been regarded as an efficient route for the synthesis of the biodegradable polymers, such as polyester, polycar- bonates and polyphosphates[1—6]. However, chemical methods for the ring-opening polymerization of biodegradable polymers need extremely pure monomers and anhydrous conditions as well as metallic catalysts, which must … 相似文献
203.
Nanoscopic scale studies of LiFePO4 as cathode material in lithium-ion batteries for HEV application
We present a review of the structural properties of LiFePO4. Depending on the mode of preparation, different impurities can poison this material. These impurities are identified and
a quantitative estimate of their concentrations is deduced from the combination of X-ray diffraction analysis, Fourier transform
infrared spectroscopy, Raman spectroscopy, and magnetic measurements. An optimized preparation provides samples with carbon-coated
particles free of any impurity phase, insuring structural stability and electrochemical performance that justify the use of
this material as a cathode element a new generation of lithium secondary batteries. 相似文献
204.
Synthesis and properties of amphoteric copolymer of 5‐vinyltetrazole and vinylbenzyl phosphonic acid
Hongting Pu Haochuan Luo Decheng Wan 《Journal of polymer science. Part A, Polymer chemistry》2013,51(16):3486-3493
Amphoteric polymers have been studied for various applications such as separation of low molecular weight organic molecules from inorganic salt mixtures, selective ion transport, drug delivery through membranes of biological interest, separation of ionic drugs and proteins, and separation of alcohol and water. Typical amphoteric polymers consist of weak base and weak acid groups. In present study, the copolymerization of 5‐vinyltetrazole (VT) and diisopropyl‐p‐vinylbenzyl phosphate (DIPVBP) via free radical polymerization is studied. The reactivity ratio of VT and DIPVBP, which is calculated from Kelen‐Tudos plot, is 0.251 and 0.345, respectively. The amphoteric copolymer of VT and diisopropyl‐p‐vinylbenzyl phosphonic acid (poly(VT‐co‐VBPA)) is obtained from hydrolysis of the copolymer of VT and DIPVBP (poly(VT‐co‐DIPVBP)). Poly(VT‐co‐VBPA) is thermally stable under 190 °C. The anhydrous proton conductivity of amphoteric poly(VT‐co‐VBPA) can reach 1.54 × 10‐4 S cm?1 at 170 °C with an activation energy of 114.7 kJ mol?1. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 3486–3493 相似文献
205.
Abstract An anthrylpolyamine chemosensor, whose fluorescence is partially quenced upon electrostatic complexation to ATP, can be used to monitor the action of an enzyme (apyrase) that hydrolyses ATP to AMP and inorganic phosphate. 相似文献
206.
Akiko Ohno Nana Kawasaki Kiyoshi Fukuhara Haruhiro Okuda Teruhide Yamaguchi 《Magnetic resonance in chemistry : MRC》2010,48(2):168-172
Complete NMR analysis of oxytocin (OXT) in phosphate buffer was elucidated by one‐dimensional (1D)‐ and two‐dimensional (2D)‐NMR techniques, which involve the assignment of peptide amide NH protons and carbamoyl NH2 protons. The 1H? 15N correlation of seven amide NH protons and three carbamoyl NH2 protons were also shown by HSQC NMR of OXT without 15N enrichment. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
207.
S. Hosseini M. HomaieeA.B. Mohamad M.R. MalekbalaA.A.H. Khadum 《Physica B: Condensed Matter》2011,406(9):1689-1694
Cesium dihydrogen phosphate (CDP) nanoparticles were synthesized using the surfactants cetyltrimethyl ammonium bromide (CTAB), polyoxyethylene-polyoxypropylene (F-68) and (F-68:CTAB) with molar ratio 0.06. The samples conductivity such as CDPCTAB, CDPF-68 and CDP(F-68:CTAB)0.06 was studied by impedance spectroscopy in the frequency range 0.01 Hz to 1 MHz. The Nyquist plots were drawn at different temperatures of 210, 230 and 260 °C, which are defined below transition, phase transition and above transition, respectively. The measured conductivities obey the Arrhenius relation. The influence of surfactants on conductivity are more significant at higher temperature due to grain boundary. The conductivity of CDPCTAB increased slightly with increasing temperature to 260 °C, whereas the conductivity of other samples decreased with increasing temperature over 230 °C. The results indicated that the conductivities increase in the order of CDPCTAB>CDP(F-68:CTAB)0.06>CDPF-68. These are in accordance to the ion exchange capacities of the samples that the surfactant shows a direct influence on the samples proton mobility. It is found that the conductivity of CsH2PO4 is influenced by surfactant type. 相似文献
208.
Lasers and amplifiers in a single fiber have been developed rapidly, especially for optical fiber communication and various sensors, in the recent years. However, remarkable progress and achievement have been made mainly in silica fiber doped with rare earth elements. In this paper, we report the progress on the development of the Yb3+-doped phosphate fiber laser. 相似文献
209.
《Colloids and surfaces. A, Physicochemical and engineering aspects》2000,170(2-3):107-112
The calcium phosphate which corresponds to the formula Ca3(PO)4 · nH2O (2<n<3) was isolated from solutions with Ca/P molar ratio 0.2 and pH 7. The compound was characterised by chemical and thermogravimetric analyses, Fourier-transform infrared (FTIR) spectroscopy and X-ray diffraction. The FTIR spectra were compared with spectra of β-tricalcium phosphate (β-TCP) in the atlases for analysis of urinary calculi and other literature data. 相似文献
210.
Umberto Costantino Maria Antonietta Massucci Aldo La Ginestra Anna Maria Tarola Laura Zampa 《Journal of inclusion phenomena and macrocyclic chemistry》1986,4(2):147-162
The intercalation of imidazole and some organic species containing the imidazole ring, between the layers of crystalline zirconium phosphate has been investigated. Fourteen new, well-ordered intercalation compounds are obtained with the batch procedure at r.t. and/or 60°C. A mechanism of formation of the various compounds is proposed on the basis of the interaction between the guest molecules (with their dimensions and geometries) and the free PO3OH groups available between the layers of the host. The new phases have been characterized by TG and X-ray methods. 相似文献