全文获取类型
收费全文 | 493篇 |
免费 | 14篇 |
国内免费 | 68篇 |
专业分类
化学 | 568篇 |
综合类 | 3篇 |
物理学 | 4篇 |
出版年
2023年 | 2篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 5篇 |
2019年 | 11篇 |
2018年 | 14篇 |
2017年 | 12篇 |
2016年 | 12篇 |
2015年 | 6篇 |
2014年 | 15篇 |
2013年 | 101篇 |
2012年 | 26篇 |
2011年 | 34篇 |
2010年 | 20篇 |
2009年 | 27篇 |
2008年 | 23篇 |
2007年 | 26篇 |
2006年 | 37篇 |
2005年 | 27篇 |
2004年 | 29篇 |
2003年 | 43篇 |
2002年 | 12篇 |
2001年 | 12篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 1篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有575条查询结果,搜索用时 15 毫秒
11.
12.
V. N. Listvan V. V. Listvan A. N. Shekel' 《Chemistry of Heterocyclic Compounds》2002,38(12):1480-1483
The reaction of cholesteryl triphenylphosphonioacetate chloride with heterocyclic aldehydes and hetaroyloxyarenecarbaldehydes in the presence of base gave the corresponding cholesteryl esters of substituted propenoic acids possessing liquid crystal properties. 相似文献
13.
Ruo Jun SUN Hui JIANG Zhi Zhen HUANG* Department of Chemistry Zhejiang University Hangzhou 《中国化学快报》2003,(3)
Wittigreactionisoneofthemostimportantmethodfortheformationofcarbon-carbondoublebondandhasbeenwidelyusedinthesynthesisofnaturalproducts1,2.Recentlyitwasfoundthatalcoholscanundergoinsituoxidation-Wittigreactionwithphosponiumylidestogivecorrespondingolefinationproducts,whichhasgreatpotentialutilitiesinorganicsynthesis3.Tosimplifytheprocedureofthereactionfurther,weconsideredtocombinethedeprotonationofylide,oxidationofalcoholandWittigreactionintoonetandemreaction.Weutilizedphosphoniumorarsoniumsal… 相似文献
14.
梨小食心虫性信息素的新法合成 总被引:6,自引:0,他引:6
梨小食心虫 (Grapholia molesta)是一种世界性果树害虫 ,主要危害梨、桃和苹果等果树 . 1 96 5年Geroge等 [1] 从该雌蛾腹部分离得到其性信息素 . 1 96 9年 Roelofs等 [2 ] 鉴定其结构为 8(Z/E) -十二碳烯 - 1 -醇乙酸酯 (6 ) .国内外对其生物活性进行了大面积田间试验 ,并用于 相似文献
15.
Phosphonium or arsonium salt 1 can undergo the tandem reaction of deprotonation -oxidation-Wittig reaction with alcohol 2 in the presence of sodium hydroxide and manganese dioxide,which affords a general simplified method for the stereoselective synthesis of (E)- α-β-unsaturated esters 3. 相似文献
16.
Hirofumi Kuroda Emi Hanaki Hironori Izawa Michiko Kano Hiromi Itahashi 《Tetrahedron》2004,60(8):1913-1920
α-Vinylfurans were obtained by phosphine-initiated cyclization of various enynes bearing a carbonyl group at the ene end in the presence of various aldehydes, in moderate to high yields. The reaction may consist of 1,6-addition of phosphine to the enynes, ring closure, and Wittig reaction between the ylid resulting from cyclization and an aldehyde. Thus, various aldehydes were able to be used in the reaction. The reaction was influenced greatly by the substituents at the acetylene position (R1) and the α-position of the carbonyl group (R3). 相似文献
17.
A total synthesis of d-(+)-biotin is described starting from d-(+)-glucosamine using acyliminium chemistry. 相似文献
18.
Mukund K. Gurjar Seetaram Mohapatra Usha D. Phalgune Vedavati G. Puranik Debendra K. Mohapatra 《Tetrahedron letters》2004,45(42):7899-7902
An enantioselective synthesis of the C12-C29 fragment of amphidinolide E is described. Key transformations include an intramolecular mercuriocyclization reaction, stereoselective introduction of methyl group at the C2 position, and Stille coupling for the introduction of the diene side chain. 相似文献
19.
The regio- and stereoselectivity of the reactions of carbanions, generated from alkanals, carboxylates of the type XYCHCOOEt (X = EtOOC, CN, Ac; Y = H, Br), or derivatives of 3-methyl-4-phosphono-2-butenoic acid using PTC techniques, with aldehydes of various types (alkanals, ,-enals, cross-conjugated enedials, benzaldehydes,etc.) are reviewed. The factors affecting the outcome of these reactions are discussed. The carbanion analogs, triphenylphosphorus ylides, are shown to attack selectively at one of the aldehyde groups of aromatic dialdehydes. The regularities found for the title reactions were used in the syntheses of some biologically active isoprenoids.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1867–1885, October, 1995. 相似文献
20.
Maddimsetti Venkateswara RaoKotha kapu Sridhar Reddy Batchu Venkateswara Rao 《Tetrahedron letters》2012,53(45):5993-5995
An efficient strategy has been developed for the stereo selective synthesis of N-Boc-(2S,3S)-3-hydroxy-2-phenyl piperidine and N-Boc-safingol from benzaldehyde and N-Boc-imine. 相似文献