首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   29453篇
  免费   2528篇
  国内免费   5040篇
化学   25365篇
晶体学   1524篇
力学   283篇
综合类   239篇
数学   3788篇
物理学   5822篇
  2024年   30篇
  2023年   308篇
  2022年   647篇
  2021年   936篇
  2020年   827篇
  2019年   805篇
  2018年   630篇
  2017年   897篇
  2016年   932篇
  2015年   842篇
  2014年   1148篇
  2013年   2272篇
  2012年   1727篇
  2011年   1980篇
  2010年   1819篇
  2009年   2079篇
  2008年   2012篇
  2007年   2042篇
  2006年   1911篇
  2005年   1658篇
  2004年   1638篇
  2003年   1423篇
  2002年   1293篇
  2001年   937篇
  2000年   870篇
  1999年   689篇
  1998年   637篇
  1997年   523篇
  1996年   436篇
  1995年   442篇
  1994年   382篇
  1993年   352篇
  1992年   335篇
  1991年   245篇
  1990年   155篇
  1989年   169篇
  1988年   151篇
  1987年   99篇
  1986年   78篇
  1985年   87篇
  1984年   99篇
  1983年   34篇
  1982年   57篇
  1981年   76篇
  1980年   62篇
  1979年   54篇
  1978年   41篇
  1977年   31篇
  1976年   21篇
  1974年   21篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
Perfect fluid with kinematic self-similarity is studied in 2+1 dimensional spacetimes with circular symmetry, and various exact solutions to the Einstein field equations are given. These include all the solutions of dust and stiff perfect fluid with self-similarity of the first kind, and all the solutions of perfect fluid with a linear equation of state and self-similarity of the zeroth and second kinds. It is found that some of these solutions represent gravitational collapse, and the final state of the collapse can be either a black hole or a null singularity. It is also shown that one solution can have two different kinds of kinematic self-similarity.  相似文献   
102.
郝万军  李畅  魏英进  陈岗  许武 《物理学报》2003,52(4):1023-1027
研究了应用于锂二次电池正极的新型高能量密度存贮材料Li(AlxCo1-x)O2 (x=01—05)的磁性.发现Al3+的掺杂可导致Co3+中d电子自旋态发生变化,即有部分d电子进入高自旋态.伴随Co3+中电子状态的改变,材料结构演化也发生了相应变化,表现为c/a比增大明显减缓,较好地解释了材料结构对Vegard定律的正偏离.这对材料的微观结构与性能设计具有重要意义. 关键词: 锂电池材料 Li(AlxCo1-x)O2 磁性 自旋态 结构演化  相似文献   
103.
在 1,10 -邻菲罗啉显色体系中 ,引入二阶导数光谱 -峰面积积分技术 ,建立了同时测定痕量铁 ( )和钴 ( )的新方法。该法可有效消除共存离子的干扰 ,提高了准确度和灵敏度。对铁和钴的表观摩尔吸光系数分别为 εFe5 .4 5× 10 6 L·mol-1·cm-1,εCo 1.1× 10 4 L· mol-1· cm-1;铁含量在 0 .0— 8.5 μg·m L-1,钴含量在 0 .0— 7.3μg· m L-1范围内遵守比耳定律。可用于芦荟中铁和钴的同时测定 ,结果令人满意  相似文献   
104.
105.
本方法用于测定霞石中的钾、钠,主要通过在溶样时加入氢氟酸除去二氧化硅,调整溶液中钾、钠的含量,消除互相之间的干扰,加入氯化铯消除电离因素的干扰,提高了分析结果的准确性和重现性,使测定结果更接近化学分析值。回收率为99.2%-101.6%。  相似文献   
106.
The concept of a novel electrochemical reduction process for the treatment of spent nuclear fuels in Li2O-LiCl molten salt was proposed and fresh tests using U3O8 powder were carried out to elucidate the reaction mechanism and verify the feasibility of the process. Electrolysis of Li2O and reduction of U3O8 powder took place simultaneously at the cathode part of the electrolysis cell via a catalytic EC mechanism and the conversion of U3O8 to U metal was more than 99%. This revised version was published online in June 2006 with corrections to the Cover Date.  相似文献   
107.
Indoor radon measurements in dwellings of four Saudi Arabian cities   总被引:1,自引:0,他引:1  
An indoor radon survey of a total of 269 dwellings, with one dosimeter per house, distributed in four Saudi Arabian cities was carried out. The objective of this survey was to carry out indoor radon measurements of two cities in the Eastern Province, Khafji and Hafr Al-Batin and to compare this with two cities in the Western Province, Al-Madina and Taif. The survey provides additional information about indoor radon concentrations in Saudi Arabia. The results of the survey in these cities showed that the overall minimum, maximum and average radon concentration were 7,137 and 30 Bqm−3, respectively. The lowest average radon concentration (20 Bqm−3) was found in Hafr Al-Batin, while the highest average concentration was found in Khafji (40 Bqm−3).  相似文献   
108.
An NMR study of one new and several known abietane diterpenes isolated from the roots of Aegiphila lhotzkyana is described. In addition to 1D NMR, several 2D shift‐correlated NMR pulse sequences (1H–1H‐COSY, NOESY, HMQC and HMBC) were used to establish all the structures, and unambiguously perform the 1H and 13C chemical shift assignments of the new natural diterpene and three derivatives, the NMR data for which have not been reported previously. Revision of current data assignment for teuvincenone H is also suggested. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
109.
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous.  相似文献   
110.
林惠文  朱文祥 《中国化学》2003,21(8):1054-1058
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号