简易混沌振荡器的混沌特性及其反馈控制电路的设计

研究了一个新的简易混沌振荡电路系统的稳定性和混沌特性,从理论上推导了该混沌振荡电路系统的稳定和混沌的条件,并对该系统进行了精确反馈线性化控制.最后,通过电路仿真实验和硬件实验验证了理论分析的准确性.     

Ab initio study of the chemical states of water on Cr2O3(0 0 0 1): From the isolated molecule to saturation coverage

The reactivity of the (0 0 0 1)-Cr–Cr₂O₃ surface towards water was studied by means of periodic DFT + U. Several water coverages were studied, from 1.2H₂O/nm² to 14.1H₂O/nm², corresponding to ¼, 1, 2 and 3 water/Cr at the (0 0 0 1)-Cr₂O₃ surface, respectively. With increasing coverage, water gradually completes the coordination sphere of the surface Cr atoms from 3 (dry surface) to 4 (1.2 and 4.7H₂O/nm²), 5 (9.4H₂O/nm²) and 6 (14.1H₂O/nm²). For all studied coverages, water replaces an O atom from the missing above plane. At coverages 1.2 and 4.7H₂O/nm², the Cr–O_s (surface oxygen) acid–base character and bond directionality govern the water adsorption. The adsorption is molecular at the lowest coverage. At 4.7H₂O/nm², molecular and dissociative states are isoenergetic. The activation energy barrier between the two states being as low as 12 kJ/mol, allowing protons exchanges between the OH groups, as evidenced by ab inito molecular dynamics at room temperature. At coverages of 9.4 and 14.1H₂O/nm², 1D- (respectively, 2D-) water networks are formed. The resulting surface terminations are –Cr(OH)₂ and –Cr(OH)₃– like, respectively. The increased stability of those terminations as compared to the previous ones are due to the stabilization of the adsorbed phase through a H-bond network and to the increase in the Cr coordination number, stabilizing the Cr (t_2g) orbitals in the valence band. An atomistic thermodynamic approach allows us to specify the temperature and water pressure domains of prevalence for each surface termination. It is found that the –Cr(OH)₃-like, –Cr(OH)₂ and anhydrous surfaces may be stabilized depending on (T, P) conditions. Calculated energies of adsorption and OH frequencies are in good agreement with published experimental data and support the full hydroxylation model, where the Cr achieves a 6-fold coordination, at saturation.     

微燃机稳压箱的计算分析

本文对自行设计的100 kW微型燃气轮机的稳压箱进行了数值模拟,并将结果与国外某75 kW微型燃气轮机的稳压箱的数值模拟结果进行了对比。然后对结果进行分析,从中发现,自行设计的微型燃气轮机的稳压箱与国外同功率级的稳压箱相比,总压恢复系数有所提高,流动损失较小,因此具有更优良的气动性能。计算表明,进口处流动方向变化较大,流动损失也较大,并且流动复杂,有漩涡产生,流场具有复杂的结构,必须在设计时引起足够的重视。     

Reorientational relaxation and rotational–translational coupling in water clusters in a d.c. external electric field

Molecular dynamics simulations have been carried out for small water clusters (N=16, 32, 64) in a d.c. electric field at T=200 K. It was shown that for relatively weak fields, there was a significant decrease of reorientational and structural relaxation times for all cluster sizes examined. Regarding the molecular reorientational motions, in the strong field regime, a decoupling of tumbling and spinning librations was observed. Reorientational relaxation times of the dipole and vector joining the two hydrogen atoms were found to follow different relaxation laws, with the former decreasing and the latter increasing with electric field increase. These trends were qualitatively explained by invoking the Debye model with field-dependent friction for dipole librations and the symmetric double-well for spinning rotations on a plane perpendicular to the field axis. Finally, the interdependence of the reorientation on the translational modes of the cluster was indicated, with the translationally slow molecules being rotationally slow as well and vice versa.     

应用级联倍频方法提高倍频系统输出稳定性研究

提出应用级联倍频方法提高倍频系统输出稳定性,并就该方法的有效性进行了理论分析和模拟计算.分析和计算结果不但证明级联倍频方法能实现倍频系统稳定输出,而且还表明可以通过仔细调节第一块倍频晶体中波矢方向 k 与光轴间夹角、两块倍频晶体间的间隔,能调节改变实现倍频系统最稳输出时所需第二块晶体的理论计算长度,使之与第二块倍频晶体的实际加工长度一致,最终实现系统稳定倍频输出.级联倍频方法在实现高输出稳定性的同时能实现高的倍频转换效率,对应用于光参量啁啾脉冲放大系统的高稳定抽运源系统的设计建造具有重要参考意义. 关键词： 级联倍频 稳定倍频输出 光参量啁啾脉冲放大     

大庆油田和南阳油田采出水的分析

采用高压消解罐法消解处理样品,对大庆油田和南阳油田几个驱块的采出水样品进行了全离子分析.用ICP-AES测定了其中Na、K、Ca、Mg、Al、Ba、Sr、Mn、Si元素的含量.方法回收率在95.00%-106.00%,相对标准偏差小于2.15%.采用离子色谱测定了各驱采出水中Cl<'->、SO<,4><'2->含量,方...     

分数阶系统有限时间稳定性理论及分数阶超混沌Lorenz系统有限时间同步

研究了分数阶系统有限时间稳定性理论及分数阶混沌系统的同步问题.根据分数阶微分性质及分数阶系统稳定性理论,建立了分数阶系统有限时间稳定性理论并进行了证明.根据该理论设计控制器实现了分数阶超混沌Lorenz系统有限时间同步并运用数值仿真进行了验证. 关键词： 分数阶 超混沌Lorenz系统 稳定 有限时间同步     

H2O line strengths revisited: ν2 and 2ν2-ν2 at 6 μm

The necessity to revisit water spectroscopy at 6 μm was prompted by recent work indicating that some prior measurements of H₂¹⁶O line strengths (ranging through seven orders of magnitude) had larger than expected systematic errors for the stronger transitions. To investigate this, linestrengths of stronger transitions were re-measured (with 14 new H₂O spectra recorded with a Bruker 125 HR Fourier transform spectrometer at the Jet Propulsion Laboratory) and combined with re-analyzed prior results (obtained at higher optical densities from 32 spectra recorded with the FTS at Kitt Peak). Systematic differences for some of the older data sets were identified and corrected. In this paper, an internally-consistent sampling of 1243 selected line strengths are reported for (0 1 0)-(0 0 0) and (0 2 0)-(0 1 0) transitions between 783 and 2378 cm⁻¹. To confirm experimental precisions, observed and calculated line strengths are compared.     

MNI—1U中性注入器高压长脉冲稳定电源研制

本文介绍一种为MNI-1U中性注入器研制的大功率长脉冲高压稳定电源。电路的技术指标为:输出脉冲电压50kV,脉冲电流30A,脉冲宽度50ms,上升下降时间小于25μs,平顶稳定度优于0.5％,调整响应时间30μs。当作直流高压稳压和稳流电源使用时,输出电压1-80kV,电流0.5—5A,电压或电流的稳定度可优于0.1％     

Potential-dependent structure of the interfacial water on the gold electrode

Doubly tunable sum frequency generation (SFG) spectra demonstrate that the water molecules at gold/electrolyte interface change their orientation with applied potential. At negative potentials, water molecules in the double layer align with their oxygen atom pointing to the solution. As potential became positive to be close to the potential of zero charge (PZC), the SFG signal decreased, suggesting the OH groups of the water molecule are either in random orientation or parallel to the electrode. As potential became more positive than the PZC, the SFG signal increased again with the oxygen-up orientation as same as in the negative potential region, indicating that water molecules interact with the adsorbed sulfate anions. The peak position of the SFG spectra indicates a relatively disordered state of water molecules at the gold electrode surface, in contrast to the previously observed ice-like structure of water at electrolyte/oxide interfaces.