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101.
102.
Viorica Lopez-Avila Richard Young Werner F. Beckert 《Journal of separation science》1997,20(9):487-492
This paper describes the extraction of 49 organophosphorus pesti-cides (OPPs) from water samples using solid-phase microextraction (SPME). Three fibers, including a 15-μm XAD-coated fiber, a 85-μm polyacrylate-coated fiber, and a 30-μm polydimethylsilox-ane-coated fiber (PDMS), were evaluated here. The effects of stirring and the addition of NaCl to the sample were examined for the polyacrylate-coated fiber. The precision of the technique was examined for all three fibers and the extraction kinetics were investigated using the XAD- and polyacrylate-coated fibers. With some exceptions, the XAD- and polyacrylate-coated fibers performed better than the PDMS-coated fiber. The superiority of the XAD-nd polyacrylate-coated fiber. The superiority of the XAD- and polyacrylate-coated fibers over the PDMS-coated fibers can be attribuibuted to the aromatic functionalities of the XAD and the polar functionalities in the polyacrylate. The relatively high percent RSDs indicate that the SPME technique needs to be further refined before it can be used for anything other than screening. A more effective form of agitation than mechanical stirring may be neccessary to reduce variability and achieve a faster equilibrium between the sample and the SPME fiber. 相似文献
103.
Hanns‐Dieter Amberger Lixin Zhang Hauke Reddmann Christos Apostolidis Olaf Walter 《无机化学与普通化学杂志》2006,632(15):2467-2470
Electronic Structures of Organometallic Compounds of f Elements. 64 Does the Zwitterionic Nature of the Triphenylphosphine Oxide Ligand Manifest itself in its Spectrochemical Properties? The triphenylphosphine oxide mono adducts of the moiety tris(η5‐cyclopentadienyl)lanthanide(III) (Ln(Cp)3; Ln = Pr ( 1 ), La ( 2 )) were synthesized and structurally characterized. The Ln–O distances of these compounds are noticeably shorter than those of the corresponding THF adducts. A crystal field (CF) analysis of the optical spectra of 1 leads to a low absolute value of the quadratic CF parameter which is comparable with those of [Pr(Cp)3(L)]? adducts with anionic bases but not with [Pr(Cp)3(MeTHF)]. Reasons for the latter finding are presented. 相似文献
104.
Bagiyan G. A. Koroleva I. K. Soroka N. V. Ufimtsev A. V. 《Russian Chemical Bulletin》2003,52(5):1135-1141
Side self-oxidation of thiols was studied. It was found that these reactions in neutral and alkaline solutions are induced by impurities of variable-valence metals. The ability of transition metals to catalyze oxidation of thiols changes in the order Cu > Mn > Fe > Ni Co. The plot of the self-oxidation rate vs. pH passes through a maximum whose position on the pH scale depends on both the nature of metal and the structure of the thiol oxidized. For thiols having different structures, the kinetic orders in reactions catalyzed by copper ions differently vary with pH, which is apparently associated with the formation of complexes possessing different catalytic activity. 相似文献
105.
M~++BrCN─→MCN~++Br气相反应的从头算研究朱荣顺,戴树珊(云南大学化学系,昆明,650091)关键词气相反应,过渡金属阳离子,溴化氰,从头算,相对论赝势对过渡金属离子与一些小分子的气相反应已有大量的实验和理论研究[1~5],MichelS... 相似文献
106.
La2O3,Y2O3-Mo次级发射材料研究 总被引:2,自引:1,他引:2
采用粉末冶金方法制备了La2O3,Y2O3-Mo次级发射材料,测试了各种材料的次级发射系数。结果表明在钼中加入稀土氧化物可以具有很好的次级发射性能。经过激活处理后,材料的最大次级发射系数均高于2.0,达到了材料使用要求的发射水平。应用扫描电镜(SEM)和光电能谱仪(XPS)研究了稀土元素在烧结体断口和发射前后在试样表面的分布情况。分析结果表明稀土元素易于在晶界处偏聚,且发射后试样表面稀土元素的相对浓度明显高于发射前的浓度。 相似文献
107.
Microcolumns containing 8-hydroxyquinoline azo-immobilized on controlled pore glass were incorporated in a field sampler for on-site collection, isolation and preconcentration of trace metal ions in waters of the Okavango Delta, Botswana. Sequestered trace metal ions were recovered by elution with 0.5 ml of 1.5 M nitric acid, and determined by graphite furnace atomic absorption spectrometry (GFAAS). This sampling and enrichment method minimizes sample contamination, and collection of large volumes of water samples for transporting, over long distances, to analytical laboratories is avoided.Data reported comprise one of the initial surveys on trace metal ion concentrations in waters of the Okavango Delta, Botswana. In waters with more efficient mixing, dissolved metal ion concentrations found were generally low with slightly elevated levels of manganese (7-19 μg l−1), zinc (2.7-4.8 μg l−1), nickel (0.2-2.5 μg l−1) and copper (0.3-2.1 μg l−1). For each trace metal ion, concentration levels seem to reflect zones of varying water conveyance, and show no obvious temporal and spatial variations apart from a slight increment from the inlet in the upper Delta to the outlets in the lower Delta. 相似文献
108.
Homo-dinuclear alkynyl complexes with a distinct metal–metal bond constitute a rapidly growing field, where the focus is placed on compounds based on ruthenium, molybdenum, tungsten or rhodium. Interesting characteristics of these complexes include paramagnetism, intense charge-transfer absorptions, tunable bridging ligands, which may not be easily accessible in mononuclear acetylide systems. These complexes have significant potential for use in both molecular electronics and supramolecular chemistry. In this short account, previous work in this area is assessed, and each of the major groups of complexes is discussed in terms of both the synthetic strategies and structural motifs. 相似文献
109.
首次合成了喹喔啉-2,3-二甲酰胺(Qxda)与3d过渡金属的三种固体配合物:M(Qxda)2cl2(M=Co(I),Ni(I),Cu(Ⅱ)。通过元素分析,摩尔电导,红外光谱,电子光谱,磁化率,热分析等手段对配合物的组成和性质进行了研究。 相似文献
110.
The formation of negative hydrogen ions in a conventional hollow cathode discharge has been investigated. A mixture of Ne and H2 proved to be more advantageous compared to pure hydrogen. The study has been performed by solving the electron Boltzmann equation, coupled with a system of balance equations for neon and hydrogen neutral and charged particles. The vibrational distribution function of hydrogen has been calculated. Our calculations show unusually high population of vibrationally excited hydrogen molecules in a Ne–H2 mixture, which explains the high density of negative hydrogen ions under optimal conditions (total gas pressure of few Torr, hydrogen number mole fraction of 1–10% and discharge current of 10–100 mA). Line intensities originating from highly excited neon states vs. hydrogen pressure have been calculated and a comparison with existing experimental results has been made. 相似文献