弱吸收基底上弱吸收薄膜的光学常数计算方法

采用一种相对简单而又精确的光度法来计算弱吸收基底上弱吸收薄膜的光学常数,为低损耗紫外薄膜的设计与实现提供了理论基础。采用JGS1型熔融石英基底,制备了MgF2与LaF3材料的单层膜,获得了JGS1型熔融石英基底及MgF2与LaF3薄膜的光学常数色散曲线。结果显示:在200 nm左右处,JGS1型熔融石英基底的吸收已经比较明显,消光系数在10-8量级,因此,应考虑基底的弱吸收,以提高薄膜光学常数的计算精度。     

硼酸对亚微米级Ca3Sc2Si3O12:Ce绿色荧光粉的制备及发光性能的影响

采用凝胶-燃烧法合成了Ca₃Sc₂Si₃O₁₂ ∶Ce绿色LED用荧光粉,用X射线粉末衍射(XRD)、扫描电镜(SEM)、荧光光谱仪等对合成产物进行了分析和表征.结果表明:通过添加H₃BO₃做助熔剂,制得的荧光粉晶相纯正,颗粒形貌均呈现为较规则的类球形,而且所得荧光粉的粒径均小于1 μm.发射光谱呈现为一宽带,发射主峰位于505 nm,该宽峰对应于Ce³⁺关键词： 白光LED 荧光粉 3Sc₂Si₃O₁₂ ∶Ce')" href="#">Ca₃Sc₂Si₃O₁₂ ∶Ce 发光     

利用积分方程法的各向异性地层频率测深三维模拟

应用一种新的积分方程算法对各向异性地层频率域电磁测深三维问题进行正演模拟.利用范数小于或等于1的修正Green算子得到各向异性地层中的新积分方程,由于满足压缩映射条件,该积分方程在任意参数条件下总是迭代收敛的.提出一种应用迭代法求解新积分方程的迭代初值优化选择方法,并通过具体算例对比说明该方法可使频率域电磁测深三维模拟的计算效率得到有效提高.最后应用所述算法对层状各向异性大地轴向频率测深视电阻率响应进行三维数值模拟,考察分析地层的各向异性对视电阻率响应特征的影响,得到一些重要结论.     

Alq3和CdSeS量子点掺杂体系的载流子输运性质的研究

利用飞行时间法(time-of-flight)测定了有机小分子发光材料8-羟基喹啉铝(Alq3)与CdseS量子点掺杂体系的载流子迁移率.研究了Alq3和CdSeS混合薄膜的载流子迁移率与外加电场强度和量子点浓度的变化关系.研究结果表明,CdSeS量子点的掺杂浓度的增加会引起薄膜样品位置无序的增加.除此之外,Alq3和CdSeS量子点界面之间的电荷转移作用,以及在量子点之间进行跳跃传输的电子数量都会改变样品的载流子迁移率.     

Infrared and visible emission of Er in combustion-synthesized CaAl2O4 phosphors

New near-infrared luminescent, monoclinic CaAl₂O₄:Er³⁺ phosphor was prepared by using the combustion route at furnace temperatures as low as 500 °C in a few minutes. Combustion synthesized phosphor has been well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive analysis of X-ray (EDAX) mapping studies. The luminescence spectra of Er³⁺-doped calcium aluminate were studied at UV (380 nm), vis (488 nm) and IR (980 nm) excitation. Upon UV and vis excitation, the CaAl₂O₄:Er³⁺ phosphor exhibits emission bands at ~523 nm and at ~547 nm, corresponding to transitions from the ²H_11/2 and ⁴S_3/2 erbium levels to the ⁴I_15/2 ground state. A strong luminescence at 1.55 μm in the infrared (IR) region due to ⁴I_13/2→⁴I_15/2 transition has been observed in CaAl₂O₄:Er³⁺ phosphor upon 980 nm CW pumping. In the spectrum of IR-excited up-conversion luminescence, green (~523 and ~547 nm) and red (662 nm) luminescence bands were present, the latter associated with the ⁴F_9/2→⁴I_15/2 transitions of Er³⁺ ions. Both excited state absorption and energy transfer may be proposed as processes responsible for the population of the ⁴S_3/2 and ⁴F_9/2 erbium levels upon IR excitation. The mechanisms responsible for the up-conversion luminescence are discussed.     

Hydrothermal preparation and photoluminescence of bundle-like structure of ZnWO4 nanorods

ZnWO₄ nanorods with a bundle-like structure were synthesized at 180°C for 12 h by a hydrothermal technology from Na₂WO₄⋅2H₂O and ZnSO₄⋅7H₂O in the presence of sodium dodecyl sulfate (SDS). The as-synthesized bundle-like structure of ZnWO₄ nanorods was characterized by various techniques: TEM, XRD and EDS. The luminescence properties of the bundle-like structure of the ZnWO₄ nanorods were investigated by photoluminescence (PL) spectroscopy.     

Local time and Tanaka formula for a multitype Dawson–Watanabe superprocess

In [3] Dynkin defined the local time of a continuous superprocess as a stochastic integral and gave a criterion for existence of local time. Here we prove that the conditions in Dynkin's existence criterion are satisfied by the multitype Dawson–Watanabe superprocess, and give a Tanaka formula‐like representation of the local time which is used to show that the occupation measure of the multitype superprocess is absolutely continuous with respect to an appropriate reference measure, and that the corresponding density coincides a.s. with the local time. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Rotational spectrum of the Ar–dimethyl sulfide complex

The rotational spectra of three isotopomers of the Ar–dimethyl sulfide (DMS) complex – normal, ³⁴S, and ¹³C species – were measured in the frequency region from 3.7 up to 24.1 GHz by Fourier transform microwave spectroscopy. The normal species yielded 43 a-type and 79 c-type transitions. No Ar tunneling splitting was observed, while many transitions were split by the internal rotation of the two methyl tops of the DMS unit. In cases where the K-type splitting was close to that due to methyl internal-rotation, several forbidden transitions were observed that followed b-type selection rules. All of the observed transition frequencies were analyzed simultaneously using a phenomenological Hamiltonian also used in previously published work describing the Ar–dimethyl ether (DME) and Ne–DME complexes. The rotational and centrifugal distortion constants and the potential barrier height to methyl-top internal rotation, V₃, were determined. The rotational constants were consistent with an Ar–DMS center of mass (cm) distance of 3.796 (3) Å and a S–cm–Ar angle of 104.8 (2)°. The V₃ potential barrier obtained, 736.17 (32) cm⁻¹, was 97.8% of the DMS monomer barrier. By assuming a Lennard–Jones-type potential, the dissociation energy was estimated to be 2.4 kJ mol⁻¹, which was close to the value for Ar–DME, 2.5 kJ mol⁻¹.     

Simulating physiological conditions to evaluate nanoparticles for magnetic fluid hyperthermia (MFH) therapy applications

Magnetite nanoparticles with high self-heating capacity and low toxicity characteristics are a promising candidate for cancer hyperthermia treatment. In order to achieve minimum dosage to a patient, magnetic nanoparticles with high heating capacity are needed. In addition, the influence of physiological factors on the heat capacity of a material should be investigated in order to determine the feasibility. In this study, magnetite nanoparticles coated with lauric acid were prepared by co-precipitation of Fe³⁺:Fe²⁺ in a ratio of 2:1, 5:3, 3:2, and 4:3, and the pH was controlled using NaOH. Structural and magnetization characterization by means of X-ray diffractometry (XRD) and a superconducting quantum interference device (SQUID) revealed that the main species was Fe₃O₄ and further showed that most of the nanoparticles exhibited superparamagnetic properties. All of the magnetic nanoparticles showed a specific absorption rate (SAR) increase that was linear with the magnetic field strength and frequency of the alternating magnetic field. Among all, the magnetic nanoparticles prepared in a 3:2 ratio showed the highest SAR. To further test the influence of physiological factors on the 3:2 ratio magnetic nanoparticles, we simulated the environment with protein (bovine serum albumin, BSA), blood sugar (dextrose), electrolytes (commercial norm-saline) and viscosity (glycerol) to examine the heating capacity under these conditions. Our results showed that the SAR value was unaffected by the protein and blood sugar environments. On the other hand, the SAR value was significantly reduced in the electrolyte environment, due to precipitation and aggregation with sodium ions. For the simulated viscous environment with glycerol, the result showed that the SAR values reduced with increasing glycerol concentration. We have further tested the heating capacity contribution from the Néel mechanism by trapping the magnetic nanoparticles in a solid form of polydimethylsiloxane (PDMS) to eliminate the heating pathway due to a Brownian motion. We measured the heating capability and determined that 47% of the total heat generated by the magnetic nanoparticles was from the Néel mechanism contribution. For evaluating magnetic nanoparticles, this method provides a fast and low cost method for determining qualitative and quantitative information measurement for the effect of physiological interference and could greatly reduce the cost and time by in vitro or animal test.     

Effects of acid and alkaline based surface preparations on spray deposited cerium based conversion coatings on Al 2024-T3

Cerium based conversion coatings were spray deposited on Al 2024-T3 and characterized to determine the effect of surface preparation on the deposition rate and surface morphology. It was found that activation of the panel using a 1-wt.% sulfuric acid solution increased the coating deposition rate compared to alkaline cleaning alone. Analysis of the surface morphology of the coatings showed that the coatings deposited on the acid treated panels exhibited fewer visible cracks compared to coatings on alkaline cleaned panels. Auger electron spectroscopy depth profiling showed that the acid activation decreased the thickness of the aluminum oxide layer and the concentration of magnesium on the surface of the panels compared to the alkaline treatment. Additionally, acid activation increased the copper concentration at the surface of the aluminum substrate. Based on the results, the acid based surface treatment appeared to expose copper rich intermetallics, thus increasing the number of cathodic sites on the surface, which led to an overall increase in the deposition rate.