全文获取类型
收费全文 | 1808篇 |
免费 | 219篇 |
国内免费 | 107篇 |
专业分类
化学 | 1488篇 |
晶体学 | 3篇 |
力学 | 54篇 |
综合类 | 14篇 |
数学 | 131篇 |
物理学 | 444篇 |
出版年
2024年 | 8篇 |
2023年 | 33篇 |
2022年 | 106篇 |
2021年 | 131篇 |
2020年 | 107篇 |
2019年 | 89篇 |
2018年 | 53篇 |
2017年 | 84篇 |
2016年 | 100篇 |
2015年 | 94篇 |
2014年 | 99篇 |
2013年 | 131篇 |
2012年 | 87篇 |
2011年 | 94篇 |
2010年 | 87篇 |
2009年 | 115篇 |
2008年 | 93篇 |
2007年 | 82篇 |
2006年 | 103篇 |
2005年 | 80篇 |
2004年 | 81篇 |
2003年 | 53篇 |
2002年 | 37篇 |
2001年 | 25篇 |
2000年 | 22篇 |
1999年 | 27篇 |
1998年 | 22篇 |
1997年 | 15篇 |
1996年 | 15篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有2134条查询结果,搜索用时 31 毫秒
11.
This work presents a formulation based on UPML for truncating conductive media by using a local and non-orthogonal coordinate
system to solve Maxwell’s equations by the FDTD method. The detailed procedure for obtaining the UPML equations for this case
is shown and the complete equation set is provided. 相似文献
12.
Gaiane Panina 《Central European Journal of Mathematics》2006,4(2):270-293
Hyperbolic virtual polytopes arose originally as polytopal versions of counterexamples to the following A.D.Alexandrov’s uniqueness
conjecture: Let K ⊂ ℝ3
be a smooth convex body. If for a constant C, at every point of ∂K, we have R
1 ≤ C ≤ R
2
then K is a ball. (R
1
and R
2
stand for the principal curvature radii of ∂K.)
This paper gives a new (in comparison with the previous construction by Y.Martinez-Maure and by G.Panina) series of counterexamples
to the conjecture. In particular, a hyperbolic virtual polytope (and therefore, a hyperbolic hérisson) with odd an number
of horns is constructed.
Moreover, various properties of hyperbolic virtual polytopes and their fans are discussed. 相似文献
13.
We use a recently published method for the renormalization of the self-energy to calculate the self-energy of 6s and 8d levels
to all orders in Zα. We demonstrate the accuracy of the method and its potential for high-n, low-Z applications. We also show that this method is perfectly suited for the evaluation of the two-electron self-energy (self-energy
screening). For the first time, evaluation of the screening of the 1s electron by a second one in either the 1s,2s, 2p1/2 or 2p3/2 shells has been performed, for 30 ⩽ Z ⩽92.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
14.
We study the equilibrium statistical mechanics of classical two-dimensional Coulomb systems living on a pseudosphere (an infinite surface of constant negative curvature). The Coulomb potential created by one point charge exists and goes to zero at infinity. The pressure can be expanded as a series in integer powers of the density (the virial expansion). The correlation functions have a thermodynamic limit, and remarkably that limit is the same one for the Coulomb interaction and some other interaction law. However, special care is needed for defining a thermodynamic limit of the free energy density. There are sum rules expressing the property of perfect screening. These generic properties can be checked on the Debye–Hückel approximation, and on two exactly solvable models, the one-component plasma and the two-component plasma, at some special temperature. 相似文献
15.
Wei-Shih Yang 《Journal of statistical physics》1987,49(1-2):1-32
The grand canonical ensemble of a two-dimensional Coulomb system with±1 charges is proved to have screening phenomena in its high-temperature region. The Coulomb potential in a finite region is assumed to be (–)–1, where
is the Laplacian with zero boundary conditions on. The hard-core condition is not assumed. The model is set up by separating (–)–1 into a shortrange part and a long-range part depending on a parameter. The self-energies are subtracted only for the short-range part and therefore a choice of is a choice of subtraction of self-energies. The method of proof is in general the same as that of Brydges-Federbush Debye screening, except that here a modification for the short-range part of the potentials is needed. 相似文献
16.
Manuel Urbano Cuadrado Gonzalo Cerruela García Irene Luque Ruiz Miguel Ángel Gómez-Nieto 《Journal of mathematical chemistry》2006,40(1):15-27
A method for the treatment of long-dimensional chemical data arrays is presented in this work with the aim of maximising classification models. The method is based on the construction of fingerprints and the subsequent generation of a similarity matrix. The similarity calculation has been modified through a scaling process to take into account different significance shown by the variables. The method was applied to spectral measurements of wines and several aspects were studied, namely: threshold considered in the construction of fingerprints and patterns, weighting factor used for scaling, normalisation method, etc. The application of both Principal Components Analysis and Soft-Independent Modelling of Class Analogies to the similarity matrices gave better classifications of the information than those obtained using original data. 相似文献
17.
Relative protonation energies in the primary, secondary and tertiary aliphatic series of amines are calculated by a semiempirical
method employing the virtual charge model. The method accounts quite well for the observed differences between the gas-phase
protonation affinities and the protonation enthalpies in solution, but when allowance is made for steric shielding from the
bulk solvent for “non-edge” atoms, some anomalies in the uncorrected model are removed. The calculated solute-solvent interactions
are related to experimental enthalpies of solution and to trends expected from the Born model. 相似文献
18.
19.
淫羊藿根与叶活性成分的分析和比较 总被引:8,自引:0,他引:8
采用细胞膜色谱法(CMC)筛选,并结合离体药理实验确定主要活性成分,利用高效液相色谱法分析比较了淫羊藿根与叶中的活性成分及其差异性.色谱条件为Kromasil ODS 柱(150 mm× 4.6 mm.I.D )流动相甲醇-水(70:30,V:V);检测波长270nm。筛选发现淫羊藿根中的两个有效成分YYH-214和YYH-216对血管有较强的舒张作用,表明活性成分在CMC模型体系中的保留特性与药理作用之间存在良好的相关性。在此色谱条件下淫羊藿叶未检测到这两种活性成分. 相似文献
20.
A rapid microtiter plate assay for the detection of inhibitors of the Na+, K+-ATPase has been developed. The assay is based on the measurement of inorganic phosphate released from the substrate, ATP,
and has been designed to be carried out in the individual wells of a microtiter plate. Since the production of inorganic phosphate
is determined colorimetrically, multiple samples can be tested simultaneously using a microtiter plate reader. This microtiter
plate assay is particularly useful for screening large numbers of samples, such as microbial culture supernatants. 相似文献