全文获取类型
收费全文 | 2809篇 |
免费 | 67篇 |
国内免费 | 205篇 |
专业分类
化学 | 1652篇 |
晶体学 | 24篇 |
力学 | 24篇 |
数学 | 9篇 |
物理学 | 1372篇 |
出版年
2024年 | 4篇 |
2023年 | 139篇 |
2022年 | 43篇 |
2021年 | 27篇 |
2020年 | 38篇 |
2019年 | 46篇 |
2018年 | 51篇 |
2017年 | 52篇 |
2016年 | 80篇 |
2015年 | 65篇 |
2014年 | 86篇 |
2013年 | 273篇 |
2012年 | 168篇 |
2011年 | 158篇 |
2010年 | 134篇 |
2009年 | 185篇 |
2008年 | 180篇 |
2007年 | 218篇 |
2006年 | 165篇 |
2005年 | 125篇 |
2004年 | 93篇 |
2003年 | 93篇 |
2002年 | 91篇 |
2001年 | 67篇 |
2000年 | 95篇 |
1999年 | 70篇 |
1998年 | 50篇 |
1997年 | 44篇 |
1996年 | 54篇 |
1995年 | 30篇 |
1994年 | 20篇 |
1993年 | 17篇 |
1992年 | 27篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 14篇 |
1987年 | 8篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1979年 | 2篇 |
1976年 | 3篇 |
1972年 | 2篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有3081条查询结果,搜索用时 15 毫秒
81.
Walrand J Lengelé M Blanquet G 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(14):3299-3303
Using diode-laser spectroscopy, the intensities of 58 lines of the v(1) + v(1/2) - v(1/2) band and 36 lines of the 2v(1) - v(1) band of OCS have been measured. The corresponding band strengths S(0)(v) and the vibrational transition dipoles micro(v) have been derived through least squares fitting of these individual intensities. The band strengths values have been determined with a precision better than 2.5%. 相似文献
82.
Investigation of the Interactions of β‐Peptides with DNA Duplexes by Circular Dichroism Spectroscopy
Kenji Namoto James Gardiner Thierry Kimmerlin Dieter Seebach 《Helvetica chimica acta》2006,89(12):3087-3103
The interaction of β‐peptides with the DNA duplexes of dA20dT20 and a GCN4‐binding CRE sequence was examined. To gauge the factors that govern these interactions, two β‐pentadecapeptides, 1 and 2 , a β‐dodecapeptide, 3 , three β‐decapeptides, 4 – 6 , three β‐heptapeptides, 7 – 9 , and β‐octaarginine 10 were designed and synthesized. The β‐peptides were conceived to adopt a β‐peptide 314 helix, in which the side chains at position i and i + 3 are aligned vertically along one side of the helix. The side chains of Lys, Asn, and Arg were positioned such that potential H‐bonding sites were created for a helical conformation to interact with the base pairs of DNA. CD Analysis showed that β‐peptides 1, 2 , and 10 interacted with dA20dT20. In addition, β‐peptides 1 and 2 showed significant interaction with a DNA‐duplex 20mer containing the ATF/CREB recognition sequence for the regulatory protein GCN4. It is impossible, at this stage of the investigation, to make a safe proposal about the actual nature of the interaction of the structures(s) of the complexes, the formation of which is suggested by the CD spectra reported herein. 相似文献
83.
We have performed large-scaleab initio calculations using second order Møller-Plesset perturbation theory (MP2) on the three van der Waals dimers formed from acetylene and carbon dioxide. Intermolecular geometrical parameters are reliably computed at this level of theory. Calculations of vibrational frequencies of the van der Waals modes, currently unobtainable by experimental means, give important information about the intermolecular potential and predict significant large-amplitude motion. Zero point energy contributions are shown to be vital in assessing the relative stability of conformations which are close in energy. Our studies suggest that the barrier to interconversion tunnelling in (CO2)2 is significantly smaller than previously inferred and is approximately the same as in (C2H2)2. The reason for the rigidity of (CO2)2 is the difference in monomer centre-of-mass separation between ground state and transition state. We also show that, in addition to the previously observedC
2v
form, the collinear form of C2H2-CO2 is a local minimum on its potential energy surface. 相似文献
84.
H. K. Neudeck 《Monatshefte für Chemie / Chemical Monthly》1996,127(4):417-434
Summary Both spirodiketones7 and8 were obtained as a mixture (56:44) by treatment of dicarbonic acid5 with polyphosphoric acid (PPA).5 was accessible from dimethylester3, synthesized byretro-Claisen reaction between1 and2. In the same way,30 was obtainedvia
27. The preparation of the pure spiro compounds7 and8, resp., was achieved by aldol reaction between9 and10 or9 and16, resp. Short treatment of the resulting compounds11 and17 with diazomethane yielded the methylbenzoates12 and18. Prolonged reaction (several hours) gave the pyrazole compounds14 and19, resp., which were also obtained (several days) from phthalides14 and20. The latter were formed from the benzylidene compounds11 and17, resp., by heating.11 and17 (after hydrogenation to15a and21a) were cyclized either withPPA or thermically to the spiro compounds7 and8. The main product20 was cyclized thermically to8 after reduction with zinc to a mixture of21a and8 (20:75). 相似文献
85.
E.E Lawson H.G.M Edwards A.F Johnson 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》1997,53(14):2571-2577
Mercapto-thiadiazoles having potential anti-wear behaviour are reacted with polymers with existing viscosity index-improving properties in order to produce materials which may find a use as multifunctional lubricant additives. 2,5-Dimercapto-1,3,4-thiadiazole, 2-amino-5-mercapto-1,3,4-thiadiazole and 2-methyl-5-mercapto-1,3,4-thiadiadiazole were reacted with low MW polybutadiene containing vinyl-1,2, cis-1,4 and trans-1,4 (C=C) groups. The reactions were monitored using FT-Raman spectroscopy in order to determine quantitatively the consumption of the individual structural units when reacted with thiadiazoles. 2,5-Dimercapto-1,3,4-thiadiazole reacted readily with the polybutadiene, achieving 80% reaction within a few hours. The thiadiazole reacted selectively with the order of addition being cis>vinyl>trans. 2-Amino-5-mercapto-1,3,4-thiadiazole and 2-methyl-5-mercapto-1,3,4-thiadiazole were found to react more slowly and hence to a lesser extent (40 and 25%, respectively) over a similar time scale. 相似文献
86.
The photodissociation of methyl iodide in various matrices at low temperature was studied. The observed Raman spectra excited by 514.5 nm laser radiation showed that there were two different photolytically produced iodine species isolated in the matrices after illumination by a medium pressure mercury lamp. One species which was dominant at lower iodine concentrations and exhibited a progression with an ωe of 201 cm?1, belonged to the matrix isolated iodine monomer (I2). The other species, which was dominant at higher iodine concentrations with an ωe of approximately 180 cm?1, belonged to the iodine aggregate ((I2)n). Five progressions of resonance Raman or resonance fluorescence of these two species were also observed in the other matrices. The iodine aggregate in the methyl iodide matrix at 77 K was formed in a crystalline structure, while the photolytically generated iodine aggregate from CH3I/Ar (2/3) matrix at 10 K, after illumination with a mercury lamp, was in amorphous form. The rearrangement of photolytically produced iodine aggregate in methyl iodide matrix was observed as a function of the duration of illumination. Local heating effects of the laser radiation might induce the iodine monomer to aggregate in matrices. The photodissociation mechanism of methyl iodide in matrices is also proposed. 相似文献
87.
A series of alkaline uranyl carbonates, M[UO2(CO3)3]·nH2O (M=Mg2, Ca2, Sr2, Ba2, Na2Ca, and CaMg) was synthesized and characterized by inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectrometry (AAS) after nitric acid digestion, X-ray powder diffraction (XRD), and thermal analysis (TGA/DTA). The molecular structure of these compounds was characterized by extended X-ray absorption fine-structure (EXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS). Crystalline Ba2[UO2(CO3)3]·6H2O was obtained for the first time. The EXAFS analysis showed that this compound consists of (UO2)(CO3)3 clusters similar to the other alkaline earth uranyl carbonates. The average U-Ba distance is 3.90±0.02 Å.Fluorescence wavelengths and life times were measured using time-resolved laser-induced fluorescence spectroscopy (TRLFS). The U-O bond distances determined by EXAFS, TRLFS, XPS, and Raman spectroscopy agree within the experimental uncertainties. The spectroscopic signatures observed could be useful for identifying uranyl carbonate species adsorbed on mineral surfaces. 相似文献
88.
The normal mode frequencies and corresponding vibrational assignments of tert-butylacetylene (TBA) are examined theoretically using the Gaussian 98 set of quantum chemistry codes. All normal modes were successfully assigned to one of the nine types of motion (C---C stretch, CC stretch, C---H stretch, C---C---C bend, CC---C bend, CC---H bend, H---C---H bend, CH3 rock, and CH3 twist) utilizing the C3v symmetry of the molecule. Calculations were performed at the Hartree–Fock, B3LYP, and MP2 levels of theory using the standard 6-311G** basis. Theoretical results were successfully compared against available experimental data. 相似文献
89.
Gao F Ruan WJ Chen JM Zhang YH Zhu ZA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):886-895
A barium-containing crown ether bridged chiral heterotrinuclear salen Zn(II) complex BaZn2L(ClO4)2, where L is a folded dinuclear chiral (R,R)-salen ligand, has been synthesized and characterized by elemental analysis, 1H NMR, UV-vis, IR, circular dichroism (CD) spectra, and mass spectra. As a folded dinuclear chiral host, its recognition with achiral guests (imidazole derivatives), rigid bidentate guest (1,4-diazobicyclo[2,2,2]octane, DABCO) and chiral guests (amino acid methyl esters) was investigated by means of UV-vis spectrophotometric titration, CD spectra. The association constants of D-amino acid methyl esters are found to be higher than those of their L-enantiomer. The sandwich-type binding of BaZn2L(ClO4)2-DABCO supramolecular assembly was specially studied via 1H NMR titration and 1H ROESY. To understand the recognition on molecular level, density functional theory (DFT) calculations on B3LYP/LanL2DZ were performed on the minimal energy conformations of host, guests, and host-guest complexes. The minimal energy conformations were obtained by molecular mechanics (MM) optimization and molecular dynamics (MD) simulation. The results of single point energy, HOMO energy, and charges transfer were analyzed. The results of theoretical calculations are in good agreement with the experimental data. 相似文献
90.
Efforts to develop a database of quadratic force fields for organic molecules are described. The database is based on systematic ab initio calculations, scaled to reproduce the experimentally observed frequencies. The choice of the theoretical method, the basis sets, geometries, internal coordinates and the scaling procedure are discussed. A key point in the procedure is the automatic generation of the internal valence coordinates. This is also very advantageous for geometry optimization. The database should permit the prediction of vibrational frequencies for most organic molecules to 10–20 cm−1, together with semiquantitative intensities. The accuracy is sufficient to identify unknown compounds from a list of reasonable candidates. 相似文献