Hierarchical Modeling of Entangled Polymers

Summary : We demonstrate that it is possible to link multi-chain molecular dynamics simulations with the tube model using a single chain slip-links model as a bridge. This hierarchical approach allows significant speed up of simulations, permitting us to span the time scales relevant for a comparison with the tube theory. Fitting the mean-square displacement of individual monomers in molecular dynamics simulations with the slip-spring model, we show that it is possible to predict the stress relaxation. Then, we analyze the stress relaxation from slip-spring simulations in the framework of the tube theory. In the absence of constraint release, we establish that the relaxation modulus can be decomposed as the sum of contributions from fast and longitudinal Rouse modes, and tube survival. Finally, we discuss some open questions regarding possible future directions that could be profitable in rendering the tube model quantitative, even for mildly entangled polymers.     

衬钽管石墨炉原子吸收法测定痕量镓时基体改进剂的研究及应用

提出用钒和铜混合基体改进剂衬钽管石墨炉原子吸收测定镓的方法。衬钽管使镓的灵敏度提高6倍左右,钒和铜混合基体改进剂不仅能进一步提高灵敏度,而且能提高灰化温度,降低原子化温度,增强抗干扰能力。测定 GSD 标准样品中的镓时,不需对样品进行预分离即可直接进行测定,结果与参考值相符。     

Ultramicro determination of organic halogens using sealed tube dry combustion method

A sealed tube dry combustion method that is simple, accurate, and precise for ultramicro determination of halogens in organic compounds has been developed. Samples below 1 mg are heated at 580 °C for 1 h in an electric furnace. After the combustion and absorption of the gaseous halogen, the interior of the tube is rinsed. Subsequent titration is carried out potentiometrically with silver nitrate and yielded standard deviations of 0.21% for chlorine, 0.17% for bromine, and 0.25% for iodine.     

A facile and green synthetic approach toward fabrication of starch-stabilized magnetite nanoparticles

A facile and green synthetic approach for fabrication of starch-stabilized magnetite nanoparticles was implemented at moderate temperature. This synthesis involved the use of iron salts, potato starch,sodium hydroxide and deionized water as iron precursors, stabilizer, reducing agent and solvent respectively. The nanoparticles(NPs) were characterized by UV-vis, PXRD, HR-TEM, FESEM, EDX, VSM and FT-IR spectroscopy. The ultrasonic assisted co-precipitation technique provides well formation of highly distributed starch/Fe_3O_4-NPs. Based on UV–vis analysis, the sample showed the characteristic of surface plasmon resonance in the presence of Fe_3O_4-NPs. The PXRD pattern depicted the characteristic of the cubic lattice structure of Fe_3O_4-NPs. HR-TEM analysis showed the good dispersion of NPs with a mean diameter and standard deviation of 10.68 4.207 nm. The d spacing measured from the lattice images were found to be around 0.30 nm and 0.52 nm attributed to the Fe3O4 and starch, respectively. FESEM analysis confirmed the formation of spherical starch/Fe_3O_4-NPs with the emission of elements of C, O and Fe by EDX analysis. The magnetic properties illustrated by VSM analysis indicated that the as synthesized sample has a saturation magnetization and coercivity of 5.30 emu/g and 22.898 G respectively.Additionally, the FTIR analysis confirmed the binding of starch with Fe_3O_4-NPs. This method was cost effective, facile and eco-friendly alternative for preparation of NPs.     

大气声传播通道的声源当量估计方法

提出了一种基于大气声传播通道的爆炸声源能量估计方法,通过将计算大气声学的传播能量分布结果与大气中传播的声压幅度衰减模型相结合,使用平流层通道与热层通道传播损失能量比例作为修正量,提高了对爆炸声源能量的估计精度。在多次地面爆炸实验得到的数据中,使用观测距离800 km以上且同时存在平流层通道与热层通道的次声接收信号,对比了平流层顶风速修正的能量估计方法与该文提出的基于大气声传播通道的能量估计方法。实验结果验证了相对于传统风速修正的能量估计方法,该方法可显著降低估计误差。     

硅的原子吸收光谱分析进展

对近十年来用原子吸收光谱法测定硅的情况进行评述．重点介绍用石墨炉测定硅时，为了避免硅与石墨炉中碳形成难熔碳化硅影响测定硅的灵敏度而使用的各种化学改进剂，涂层石墨管和一些新的实验技术．引用参考文献４２篇．     

对可压缩流体若干问题的讨论

根据气体幼力学中一维定常等熵等流的基本方程组,得出的一维定常等熵管流的速度变化与管截面变化关系式,定性一讨论了一维定常等熵管流的截面变化对气流速度的影响。     

Functional Analysis of Tube Chain Conveyors

This paper describes some of the aspects necessary for the design and use of tube chain conveyors. It is based on the reports of experienced experts and recent tube chain conveyor experimental results. The aim of the research work is the formulation of general technical regulations for tube chain conveyors. Theoretical models were developed, which allow the calculation of the motion resistances in all parts of the conveyor by the use of empirical extracted correction factors. Specially designed measurement equipment enabled the measurement of the important chain tractive force from the closed tube system. The measurements show the influence of the major operational parameters and the bulk solid properties.     

Walker Bleakney and the development of the shock tube at Princeton

Recollections of activities in the Physics Department of Princeton University leading to the construction and use of the SHOCK TUBE are recorded. Walker Bleakney was the leader of these activities from 1940 to 1979, and his methods and attitude are described. Original interferograms made at Princeton show some results obtained.