Adsorption of two anions (F− and Cl−) and two cations (Li+ and Na+) on the surface of aluminum nitride nanotubes (AlNNTs) is investigated by density functional theory. The reactions are site-selective, so that the cations and anions prefer to be adsorbed atop the N and Al atoms of the tube surface, respectively. The adsorption energies of anions (−4.46 eV for F− and −1.12 eV for Cl−) are much higher than those of cations (about −0.17 eV for Li+ and −0.12 eV for Na+) which can be explained using frontier molecular orbital theory. It was found that the adsorption of anions may facilitate the electron emission from the AlNNT surface by reducing the work function due to the charge transfer occurs from the anions to the tube. It has been predicted that in contrast to the cations the adsorption of anions also obviously increases the electrical conductivity of AlNNT. 相似文献
Facile and direct synthesis of porous nanorod‐type graphitic carbon nitride/CuO composite ( CuO‐g‐C3N4 ) has been achieved by using a Cu–melamine supramolecular framework as a precursor. The CuO‐g‐C3N4 nanocomposite demonstrated improved visible‐light‐driven photocatalytic activities. The results indicate that metal–melamine supramolecular frameworks can be promising precursors for the preparation of efficient g ‐C3N4 nanocomposite photocatalysts. 相似文献
Optical frequency combs enable precision measurements in fundamental physics and have been applied to a growing number of applications, such as molecular spectroscopy, LIDAR and atmospheric trace‐gas sensing. In recent years, the generation of frequency combs has been demonstrated in integrated microresonators. Extending their spectral range to the visible is generally hindered by strong normal material dispersion and scattering losses. In this paper, we report the first realization of a green‐light frequency comb in integrated high‐Q silicon nitride (SiN) ring microresonators. Third‐order optical non‐linearities are utilized to convert a near‐infrared Kerr frequency comb to a broadband green light comb. The 1‐THz frequency spacing infrared comb covers up to 2/3 of an octave, from 144 to 226 THz (or 1327‐2082 nm), and the simultaneously generated green‐light comb is centered around 570‐580 THz (or 517‐526 nm), with comb lines emitted down to 517 THz (or 580 nm) and up to 597 THz (or 502 nm). The green comb power is estimated to be as high as −9.1 dBm in the bus waveguide, with an on‐chip conversion efficiency of −34 dB. The proposed approach substantiates the feasibility of on‐chip optical frequency comb generation expanding to the green spectral region or even shorter wavelengths.
Defects present in (0 0 0 1) textured polycrystalline AlN grown by the sublimation–recombination method were analyzed using transmission electron microscopy (TEM) methods. Grains in the polycrystalline boule had either a smooth or a rough surface. The rough surface grains had mainly edge dislocations, whereas the smooth surface grains had some sub-grain boundaries and were mostly free of dislocations. Dislocations at the grain boundaries were pinned and could not be annihilated. 相似文献
For the first time silicon nitride (Si3N4) nanoparticles was used for preparation electrochemical biosensor. GOx immobilized on the Si3N4 nanoparticles exhibits facile and direct electrochemistry. The surface coverage and heterogeneous electron transfer rate constant (ks) of immobilized GOx were 6.3×10?13 mol cm?2 and 47.4±0.3 s?1. The sensitivity, linear concentration range and detection limit of the biosensor for glucose detection were 38.57 µA mM?1 cm?2, 25 µM to 8 mM and 6.5 µM, respectively. This biosensor also exhibits good stability, reproducibility and long life time. These indicate Si3N4 nanoparticles is good candidate material for construction of third generation biosensor and bioelectronics devices. 相似文献
Geometrical optimization of tetra-3d metal nitrides (Mn4N, Fe4N, Co4N, and Ni4N) has been performed and the relations of their energies (E) and their total magnetic moments (M) are obtained by plane-wave-basis density-functional calculations without any assumption of specific spin arrangement. The E vs. M relations obtained for Fe4N and Mn4N have a bimodal character. The ground state of Fe4N is a high-spin state, which would correspond to the ferromagnetic character, while that of Mn4N is a low-spin state, which would correspond to the observed ferrimagnetic character. Lattice constants and total magnetic moments of these tetra-3d metal nitrides are almost accurately predicted. From the spin-polarized densities of states curves, Co4N would have the largest spin polarization ratio of 0.88, which suggests Co4N can be a candidate material for ferromagnetic electrodes for spin-injection. 相似文献