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71.
Adriana Tudose 《Tetrahedron letters》2006,47(48):8529-8533
Simple catalysts formed in situ from palladium acetate and a variety of imidazolium and imidazolinium carboxylates and dithiocarboxylates have been screened in the coupling of aryl halides with trans-2-phenylvinylboronic acid. Imidazol(in)ium carboxylates show an excellent activity, which compares to that displayed by the parent imidazol(in)ium chlorides, whereas imidazol(in)ium dithiocarboxylates are poorly efficient. Interestingly, the base employed exerts a profound influence on the trans/cis stereochemistry of the coupling product. 相似文献
72.
Ana M. Piloto 《Tetrahedron》2006,62(39):9258-9267
Four carboxylic fused furans are presented as new fluorescent labels for the amino and hydroxyl functions of organic molecules. Various representative l-amino acids were chosen as models, labelled at their N-terminus and also at their side-chain. Fluorescent derivatives were obtained in high yields, and their absorption and emission properties were studied. 相似文献
73.
两种蓝色有机电致发光材料 总被引:4,自引:1,他引:3
重点研究以两种蓝色OEL材料蒽类衍生物JBEM和联苯乙烯衍生物DPVBi分别作基质,以perylene作掺杂剂的器件的电致发光性能,特别研究了它稳定性,在这度和效率方面,两种器件并没有很大差别,然而在稳定性方面却有很大差别,蒽类衍生物JBEM的器件在100cd/m^2初始亮度下,半亮度寿命可达1035h,而DPVBi的器件在同样条件下,半亮度寿命为255h。通过分析两种器件的能级图,认为稳定性的差别可能源于两种蓝光材料本身的热稳定性不同,JBEM优于DPVBi,是一种很有前途的蓝色发光材料。 相似文献
74.
The effect of ITO films thickness on the properties of flexible organic light emitting diode 总被引:1,自引:0,他引:1
Indium tin oxide (ITO) thin films were deposited on cyclic olefin copolymer substrate at room temperature by an inverse target sputtering system. The crystal structure and the surface morphology of the deposited ITO films were examined by X-ray diffraction and atomic force microscopy, separately. The electrical properties of the conductive films were explored by four-point probing. Visible spectrometer was used to measure the optical properties of ITO-coated films. The performance of the flexible organic light emitting diode device with different thickness anode was investigated in this study. 相似文献
75.
偶氮苯衍生物三阶非线性的四波混频研究 总被引:7,自引:0,他引:7
用皮秒Nd:YAG激光器的倍频光(532nm)对具有离域π-共轭电子云结构的偶氮苯类样品材料作简并四波混频补给,测得三阶非线性电极化率x^(3)和它们的时间响应分别为10^-9esu和20ps,并对影响x^(3)的瞬时光栅作用和x^(3)的响应时间人了讨论。 相似文献
76.
L. T. Eremenko L. B. Romanova M. E. Ivanova I. L. Eremenko S. E. Nefedov Yu. T. Struchkov 《Russian Chemical Bulletin》1994,43(4):619-623
An effective method of esterification of 1,4-cubanedicarboxylic acid with alkylsulfuric acids is proposed. The derivatives of alkanols with substantially different pKa Valus are obtained in high yields. Molecular structures of the esters obtained are confirmed by various methods. The X-ray study showed a remarkable effect of the nature of an alkyl radical on the geometry of the cubane core.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.668–672, April, 1994.The authors thank Dr. G. V. Lagodzinskaya for analyzing the NMR spectra and for useful discussions. 相似文献
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80.
Koichi Itoh Takeji Takui 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(2):29
This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism. 相似文献