X-ray attenuation coefficients of Fe compounds in the K-edge region at different energies and the validity of the mixture rule

The total mass attenuation coefficients for element Fe and compounds FeF₃, Fe₂O₃, FeCl₂·4H₂O, FeCl₃2NH₄Cl·H₂O were measured at different energies between 4.508-17.443 keV range by using secondary excitation method. Ti, V, Cr, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Nb, Mo were chosen as secondary exciter. 59.5 keV gamma rays emitted from an ²⁴¹Am annular source were used to excite secondary exciter and K_α(K-L₃, L₂) lines emitted of secondary exciter were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. It was observed that mixture rule method is not a suitable method for determination of the mass attenuation coefficients of compounds, especially at energy that is near the absorption edge. Obtained values were compared with theoretical values.     

Electronic structure of layered uranium compounds from photoemission spectroscopy

We present the photoemission results of two layered tetragonal compounds, the anti-ferromagnet UAsSe and ferromagnet USb₂. We observed intriguing electronic structure for both UAsSe and USb₂, in which relatively dispersive and narrow 5f bands are present. In the vicinity of the Fermi edge we found a very sharp photoemission peak with dispersion of several meV along the Γ to Z direction of the Brillouin zone. We also found a broader, hybridized f-character band with dispersion of several hundred meV along the Γ to X direction. Narrow and dispersive bands in these U-based magnetic materials are reminiscent of band magnetism as previously found in some transition metals.     

On the steady motions of a flat domain wall in a ferromagnet

A new derivation is presented of Walker's exact solution to Gilbert equation, a solution which mimicks the travelling-wave motion of a flat domain wall at 180^°. It is shown that a process during which the working of the applied magnetic field exactly compensates dissipation (the Walker condition) exists both under the constitutive circumstances considered in the standard Gilbert equation and when either the internal free-energy or the dissipation, or both, are generalized by the introduction of higher-gradient terms; but that such a process cannot solve the generalized Gilbert equation. It is also shown that, when dry-friction dissipation is considered and a suitable magnetic field is applied, the associated Gilbert equation has a Walker-type solution mimicking a flat wall, at 90^° this time, which however does not satisfy the Walker condition. Received 16 November 2001     

Gastrennung mit Hilfe des Zirkulations-Diffusions-Verfahrens Teil I : Hochanreicherung von Gasen in Trennrohren mit natürlicher Zirkulation

Auf der Grundlage des Zirkulations-Diffusions-Prinzips wurden zwei Trennrohre für die Hochanreicherung von Gasen enytwickelt. Als Modellgasmischungen dienten H₂-N₂ Kr-CH₄ und Luft. Neben Wasserdampf wurden Methanol- und Äthaanoldämpfe als Treibmittel benutzt. Gute Trennungen wurden in einem nur 20 cm langen Rohr erzielt, dessen Trennspalt horizontal durch Lamellen in kleine Sektionen und durch ein Drahtdiaphragma vertikal in zwei Ringkammern geteilt wird. Drei Rohre dieses Typs wurden in einer rechteckigen Kaskadenanordnung getestet. Die Theorie des Transportes im Trennrohr sowie die Behandlung des hydrodynamischen Problems werden angegeben. Eine Anwendung des beschriebenen Trennrohres zur Isotopentrennung und zur Gashochanreicherung erscheint aussichtsreich.     

Diffusion tensor parameters and principal eigenvector coherence: Relation to b-value intervals and field strength

Diffusion-weighted MRI images acquired at b-value greater than 1000 s mm^− 2 measure the diffusion of a restricted pool of water molecules. High b-value images are accompanied by a reduction in signal-to-noise ratio (SNR) due to the application of large diffusion gradients. By fitting the diffusion tensor model to data acquired at incremental b-value intervals, we determined the effect of SNR on tensor parameters in normal human brains, in vivo. In addition, we also investigated the impact of field strength on the diffusion tensor model. Data were acquired at 1.5 and 3 T, at b-values 0, 1000, 2000 and 3000 s mm^− 2 in twenty diffusion-sensitised directions. Fractional anisotropy (FA), mean diffusivity (MD) and principal eigenvector coherence (κ) were calculated from diffusion tensors fitted between datasets with b-values 0–1000, 0–2000, 0–3000, 1000–2000 and 2000–3000 s mm^− 2. Field strength and b-value effects on diffusion parameters were analysed in white and grey matter regions of interest. Decreases in FA, κ and MD were found with increasing b-value in white matter. Univariate analysis showed a significant increase in FA with increasing field strength in highly organised white matter. These results suggest there are significant differences in diffusion parameters at 1.5 and 3 T and that the optimal results, in terms of the highest values of FA in white matter, are obtained at 3 T with a maximum b = 1000 s mm^− 2.     

Diffusion on the torus for Hamiltonian maps

For a mapping of the torusT ² we propose a definition of the diffusion coefficientD suggested by the solution of the diffusion equation ofT ². The definition ofD, based on the limit of moments of the invariant measure, depends on the set where an initial uniform distribution is assigned. For the algebraic automorphism of the torus the limit is proved to exist and to have the same value for almost all initial sets in the subfamily of parallelograms. Numerical results show that it has the same value for arbitrary polygons and for arbitrary moments.     

Transport coefficients of quasicrystals

The transport coefficients for the nine point groups —which represent the symmetry groups of the quasicrystals in two and three dimensions—have been evaluated and tabulated in this work, employing group-theoretical methods.     

Calculation of geometrical coupling coefficients for the hyperspherical harmonics approach

An elegant and fast method for the calculation of geometrical structure coefficients needed for an expansion of a few-body wavefunction and interaction in hyperspherical harmonics has been proposed. A sum rule for the GSC has also been derived, which is useful for an independent check of the coefficients. The proposed method of computation is many orders of magnitude faster than conventional methods.     

Experimental investigation of reflection coefficients for lossy liquid-solid-liquid systems

The reflection coefficient for a bounded ultrasonic beam incident on a liquid-solid-liquid system (LSL) is studied. Systematic measurements were carried out to investigate the variations of the amplitude of the reflection modulus ∣R_LSL∣ with incident angle and parameter Fd (frequency-thickness of the plate). The experimental plots confirm the theoretical works of Claeys et al¹ and Bogy and Gracewski². It is shown that the attenuation of the media has a great influence on the variations of this coefficient as has been already mentioned in the literature, for liquid-solid configurations.     

Electrocatalysis of oxygen reduction reaction on Nafion/platinum/gas diffusion layer electrode for PEM fuel cell

In this work a new membrane electrode based on Pt-coated Nafion membrane was fabricated. Chemical deposition process was used to coat platinum on Nafion 117 membrane and then Pt-coated Nafion membrane was hot pressed on gas diffusion layer (GDL) to make new membrane electrode. The electrochemical and chemical studies of the Pt-coated Nafions were investigated by electrochemical techniques, X-ray diffraction and scanning electron microscopy. The electrochemical results indicated that as the concentration of H₂PtCl₆ increased, the oxygen reduction reaction rate increased until the concentration was reached where the reduction reaction was limited by the problem of mass transport. The electrochemical results for oxygen reduction reaction showed that the new electrode which prepared by plating Nafion membrane with 0.06 M H₂PtCl₆ in electroless plating solution, has a higher performance than other electrodes. The XRD results showed that the average platinum particle size of the best sample was about 3 nm. The loading of platinum for this electrode was 0.153 mg cm⁻².