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《Quaestiones Mathematicae》2013,36(3):209-218
In this paper, we study the extension of isometries between the unit spheres of L ∞ and a normed space E. We find a condition under which an isometric mapping between the unit spheres can be extended to a linear isometry on the whole space L ∞. 相似文献
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在Ar气氛中, 采用高温固相反应法合成了K5LnLi2F10(Ln=La, Ce, Gd, Y)化合物,X射线衍射图表明: 除K5YLi2F10外, 均具有与K5NdLi2F10(KNLF)相同的结构。计算了K5LnLi2F10(Ln=Ln, Ce, Gd)的晶胞参数和晶胞体积, 它们随着La^3^+, Ce^3^+,Gd^3^+的离子半径减小而有规律地减小, 测定了K5CexLn1-xLi2F10化合物的激发光谱和荧光光谱, 发现Ce^3^+的激发波长和发射波长随着La^3^+, Gd^3^+, Y^3^+离子的改变几乎不变, 并对这种现象进行了讨论。 相似文献
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细胞壁模板诱导介观尺寸生物SiO~2材料合成 总被引:2,自引:0,他引:2
在人工培养年下施用正硅酸乙酯(TEOS)在结缕草叶外表皮细胞间隙,以细胞壁为模板生物矿化合成介观尺寸有序SiO~2材料,植物吸收和矿化构筑单元的硅化学形态显著影响有序SiO~2结构的形成,这反映出TEOS和细胞壁模板分子作用时有较强的结构控制能力和缓慢的凝聚硅化过程。X-ray(EDX)能谱分析显示一根完整的硅柱是含有SiO~2和C元素,表明TEOS部分水解后在植物外表皮细胞间隙合成了不同于自然的地球化学条件下形成SiO~2。 相似文献
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《Composite Interfaces》2013,20(5-7):571-579
The mechanical properties of hydroxyapatite related macroporous biocomposites (MPBs) are influenced by a number of factors, such as the pore size, the filler content and the properties of the matrix and the inclusion. Failure often occurs when the strength of the implant cannot bear the applied mechanical load. In this study, the effects of filler content on the mechanical properties of MPBs have been investigated. A finite element (FE) unit cell model of a macroporous hydroxyapatite–polyetheretherketone (HA–PEEK) biocomposite structure with uniform and interconnected pores has been constructed. In the FE model, the HA particles were assumed to have random distribution, and particle volume fraction would be varied in the PEEK matrix. The material behaviours of both HA and PEEK have been implemented in the ABAQUS finite element code. HA was modelled to exhibit elastic behaviour and undergo plastic softening to a residual strength when a critical stress was reached, while the PEEK matrix would follow elastic–plastic behaviour. The macroscopic compressive stress–strain relations of the macroporous biocomposite structures have been predicted. Increasing particle volume fraction could lead to an increase in the compressive elastic modulus of the structures but a reduction in the compressive strength. The von Mises stress distribution and the effect of stress concentration in the structures with different filler content are also discussed. The proposed model could provide macro-structural and microscopic information of the macroporous biocomposite structure to the designers in order to facilitate the fabrication of this kind of structure with optimum mechanical properties. 相似文献
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《Composite Interfaces》2013,20(8-9):899-909
Conducting glass substrates are modified with platinum by vacuum coating, thermal decomposition and electrochemical sedimentation methods. A dye-sensitized nanocrystalline solar cell (DSC) is assembled by using a substrate modified with platinum as photocathode. The surface status of the photoanode is observed, the surface resistance of the substrate is measured, and the influence of the photoanode on the photoelectrical efficiency of the DSC is investigated. It is found that the platinum film prepared by the electrochemical sedimentation method with a plane, shining and uniform appearance shows lower surface resistance and better photoelectric efficiency than that prepared by the other two methods. The surface resistance is 12.4 Ω · cm?1, using it as photoanode, and the DSC's open circuit voltage, short current and fill factor is 6.2 mA/cm2, 0.662 V and 52.3%, respectively. 相似文献
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本文研究了水溶液中meso-四(4-磺苯基)卟啉(TPPS)二聚体(Dimer)的各种影响因素和它的电化学性质。提出了二聚体的模型, 说明了水溶性金属卟啉(Cu^2+,Zn^2+, Mn^2+-TPPS)循环伏安图上的一对小尖峰是二聚体在汞电极上吸附还原和氧化的结果。 相似文献