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51.
Zhijie Fang Zhe Su Wenjing Qin Hao Li Bing Fang Wei Du Qiong Wu Bo Peng Peng Li Haidong Yu Lin Li Wei Huang 《中国化学快报》2021,31(11):2903-2908
H2S is an essential gas signal molecule in cells, and viscosity is a key internal environmental parameter. Recent studies have shown that H2S acts as a cytoarchitecture agent and gas transmitter in many tissues, e.g., as a regulator of neuroendocrine in the brain for mediating vascular tone in blood vessels. Mitochondrial viscosity is an important parameter for judging whether mitochondrial function is normal. It has been reported that oxidative stress and mitochondrial dysfunction are connected with Parkinson’s disease (PD), and the protective role of H2S in PD models has been extensively demonstrated. Herein, Mito-HS, a new two-photon fluorescent probe was demonstrated to detect cross-talk between the two channels of mitochondrial viscosity and H2S content. Moreover, this probe could detect the relative amount of and changes in mitochondrial H2S in situ due to the reduced mitochondrial targeting ability after reaction with H2S. The results show that H2S in mitochondria is inversely related to viscosity. The PD model has a lower H2S in mitochondria and a higher mitochondrial viscosity than did the normal. This result is important for our deep understanding of PD and its causes. 相似文献
52.
Zhong‐Fu An Chao Zheng Dr. Run‐Feng Chen Jun Yin Jian‐Jian Xiao Hui‐Fang Shi Ye Tao Dr. Yan Qian Prof. Wei Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(49):15655-15661
A novel conjugated asymmetric donor–acceptor (CADA) strategy for preventing the redshift in photoluminescence, as well as preserving the merits of donor–acceptor architectures, was proposed and demonstrated for two triazine derivatives, which showed highly efficient, narrow, and blueshifted ultraviolet light emission in solid films along with special aggregation‐induced emission behavior. A mechanism of aggregation‐induced locally excited‐state emission by suppressing the twisted intramolecular charge‐transfer emission for the spectacular optoelectronic phenomena of these CADA molecules was suggested on the basis of both experimental measurements and theoretical calculations. By taking advantage of this special CADA architecture, fluorescent probes based on aggregates of conjugated asymmetric triazines in THF/water for the detection of explosives show superamplified detection of picric acid with high quenching constants (>1.0×107 M ?1) and a low detection limit of 15 ppb. 相似文献
53.
J. Swiatkiewicz 《Phase Transitions》2013,86(9-10):891-896
Transient behaviour of the excited states originated from the neutral and the charged species is discussed using data from time-resolved experiments. Complex transient characteristics obtained for the slightly charged poly-(bithiophene) film during electrochemical doping were explained in terms of sequential molar fraction changes of the neutral species, the radical cation and the π-dimerized radical cations. Femtosecond transient absorption measurement carried out in time range of 0-4 ns for a two-photon excited dye reveals a multi-exponent decay with well separated relaxation times and the distinct relaxation mechanisms. At high irradiance and a sufficient fluence, the multi-photon excitation processes affect the subpicosecond response and lead to formation of the photo-products. 相似文献
54.
A facile route to improve photoluminescent performance and service lifetime of a promising blue light emitting material is reported and demonstrated here using a copolymer system of N-(2-ethylhexyl)-2,7-carbazole (Cz) and 1,3,5,7-tetrakis- (4-bromophenyl) adamantane (TBA). The copolymers were successfully synthesized by palladium-catalyzed Suzuki coupling reactions. Structure and molecular weight of the materials were characterized by FT-IR and 1H-NMR spectroscopies, elemental analysis and gel permeation chromatography. The influence of adamantane content on the thermal stability and photoluminescent performance of the synthesized copolymers was investigated in detail. DSC results showed that glass transition temperature increased dramatically, from 68°C for neat carbazole, to 88°C, 120°C and 152°C, after the addition of 10%, 20%, and 30% TBA, respectively. The same trend was found when thermal decomposition temperature at 5% weight loss was evaluated from TGA data. Importantly, this increased stability can be extended to thermo-optical performance, with the Cz-TBA system showing higher color purity and stronger emission intensity within blue light wavelength than carbazole alone. Nevertheless, measurements of emitting spectral stability at a broader temperature range (100–200°C) and photoluminescence quantum yield suggested that there is a delicate trade-off between the performance and adamantane content. 相似文献
55.
Dr. Robert Ludmerczki Prof. Luca Malfatti Dr. Luigi Stagi Dr. Manuela Meloni Prof. Carlo Maria Carbonaro Prof. Maria Francesca Casula Dr. Dóra Bogdán Dr. Stefania Mura Prof. István M. Mándity Prof. Plinio Innocenzi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(7):2543-2550
Carbonized polymer dots (CPDs), a peculiar type of carbon dots, show extremely high quantum yields, making them very attractive nanostructures for application in optics and biophotonics. The origin of the strong photoluminescence of CPDs resides in a complicated interplay of several radiative mechanisms. To understand the correlation between CPD processing and properties, the early stage formation of carbonized polymer dots has been studied. In the synthesis, citric acid monohydrate and 2-amino-2-(hydroxymethyl)propane-1,3-diol have been thermally degraded at 180 °C. The use of an oil bath instead of a more traditional hydrothermal reactor has allowed the CPD properties to be monitored at different reactions times. Transmission electron microscopy, time-resolved photoluminescence, nuclear magnetic resonance, infrared, and Raman spectroscopy have revealed the formation of polymeric species with amide and ester bonds. Quantum chemistry calculations have been employed to investigate the origin of CPD electronic transitions. At short reaction times, amorphous C-dots with 80 % quantum yield, have been obtained. 相似文献
56.
Fei Dou Cephas Small Francoise Provencher Jason Ferreira Xuhua Wang Elham Rezasoltani Hongmei Liu Xinping Zhang 《Journal of Polymer Science.Polymer Physics》2017,55(12):940-947
We investigate the influence of particle plasmons on exciton and charge generation and recombination processes in the blend of poly (9‐(1‐octylnonyl)‐9H‐carbazole‐benzothiadiazole‐4,7‐diyl‐2,5‐thiophenediyl) (PCDTBT) and [6,6]‐phenyl‐C70butyric acid methyl ester (PC70BM). The particle plasmons are generated from gold nanoparticles, which are embedded into PCDTBT:PC70BM blend. For the blend with gold nanoparticles, we observe enhance light harvesting. Despite the enhanced light collection, we find that the quasi‐steady‐state charge generation has not been influenced by the particle plasmons. However, the generation and recombination of long‐lived (sub‐millisecond) polaron paris have been significantly enhanced: from untrapped state in the pristine blend to the trapped state in the gold nanoparticle‐embedded blend. This result implies that the plasmon‐influenced polarons are trapped at the broadband geminate polaron pair (GPP) state. This state acts as an intermediate state, which either leads to the formation of charge transfer excitons (CTXs) or free charge carriers. In our case, the particle plasmon‐influenced polarons are trapped in the GPP state, which leads to the formation of CTXs. For this reason, we do not observe the enhanced charge generation in PCDTBT:PC70BM blend with particle plasmon resonance. Finally, we revealed that the long‐lived polarons mainly resulted from the localization by particle plasmons. The macroscopic modification in the blend film made negligible contributions to this influence. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 940–947 相似文献
57.
A copper metal–organic framework nanoparticles (Cu‐MOF‐NPs) synthesized via simple technique. The prepared Cu‐MOF‐NPs nanoparticles were further characterized using 1H‐NMR, FE‐SEM/EDX and thermal study (DSC/TGA). The FE‐SEM/EDX, thermal analysis, and NMR spectrum data with the other analysis support the nano‐Cu‐MOF structure and the monomeric unit (n[Cu (AIP)2(APY)(H2O)2].4H2O) of Cu‐MOF‐NPs. The photoluminescence (PL) studies of triiodothyronine hormone (T3) based on the prepared Cu‐MOF‐NPs investigated. The results revealed that the Cu‐MOF‐NPs might be used as a biosensor in the determination of triiodothyronine hormone (T3) in biological fluids through a significant quenching of the photoluminescence intensity of Cu‐MOF‐NPs at excitation wavelength 492 nm. The calibration plot achieved over the concentration range 0.0–200.0 ng/dL T3 hormone with a correlation coefficient 0.996 and limit of detection (LOD) and quantification (LOQ) 0.198 and 0.60 ng/dL, respectively. The PL spectra are indicating that Cu‐MOF‐NPs has highly selective sensing properties for T3 hormone without interfering with other human many hormones types. This approach considered a promising analytical tool for early diagnosis of the cases of thyroid disease. The mechanism of quenching between the Cu‐MOF‐NPs, and T3 hormone studied. The mechanism was a dynamic type and obtained due to the energy transfer mechanism. 相似文献
58.
Our group has developed a series of molecular electrocatalysts for hydrogen generation based on triazenido–metal complexes (cobalt, copper, etc.). In this paper, we first present the electrocatalytic performance of a new dinuclear silver complex, [Ag2(L)2], formed by the reaction of the triazenido ligand 1‐[(2‐carboxymethyl)benzene]‐3‐[(2‐methoxy)benzene]triazene (HL) with AgNO3. At room temperature, the silver complex shows photoluminescence at 653 nm. The electrocatalytic systems based on this silver complex can afford 106.57 and 1536.36 moles of hydrogen per mole of catalyst per hour from acetic acid at an overpotential (OP) of 991.6 mV and from a neutral aqueous buffer (pH = 7.0) at an OP of 837.6 mV, respectively. Electrochemical investigations show that both silver ion and triazenido ligand play a role in determining the catalytic activities of the electrocatalytic system. 相似文献
59.
Dr. Ning Chen Dr. Yanglin Shen Dr. Ting Xu Dr. Wangqiang Shen Prof. Xing Lu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(65):16212-16218
Surface cracks could improve the optical and photoelectronic properties of crystalline materials as they increase specific surface area, but the controlled self-assembly of fullerene (C60) molecules into micro-/nanostructures with surface cracks is still challenging. Herein, we report the morphology engineering of novel C60 microstructures bearing surface cracks for the first time, selecting phenetole and propan-1-ol (NPA) as good and poor solvents, respectively. Our systematic investigations reveal that phenetole molecules initially participate in the formation of the ends of the C60 microstructures, and then NPA molecules are involved in the gradual growth of the sidewalls of the microstructures. Therefore, the surface cracks of C60 microstructures can be finely regulated by adjusting the addition of NPA and the crystallization time. Interestingly, the cracked C60 microstructures show superior photoluminescence properties relative to the smooth microstructures due to the increased specific surface area. In addition, C60 microstructures with wide cracks show preferential recognition of silica particles over C60 particles owing to electrostatic interactions between the negatively charged C60 microstructures and the positively charged silica microparticles. These C60 crystals with surface cracks have potential applications from optoelectronics to biology. 相似文献
60.