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31.
32.
稀土离子(Gd3+,Eu3+)加载于纳米介孔ZrO2中的发光 总被引:2,自引:0,他引:2
水热合成法制备的高度有序多孔ZrO2具有规则六角排列,均匀纳米孔洞(约1.8nm),丰富的表面,界面态及比表面积和强的蓝-(近)紫外光发射,使其较常规体材料有更优异的性质,以稀土离子为探针,研究了Gd^3 ,Eu^3 在这些纳米微孔中的发光行为,结果表明,500摄氏度下,介孔ZrO2与稀土离子相作用并有效地将能量传递给稀土离子,增进稀土离子发光,而在ZrO2:Gd-Eu体系中,Gd^3 在ZrO2与Eu3 间起桥梁作用,使基质ZrO2→Eu^3 的能量传递更为有效。 相似文献
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LaAl3(BO3)4的合成及其晶体结构的研究 总被引:1,自引:3,他引:1
在研究LnAl3(BO3)(Ln=稀土元素,Y)的合成及发光特性过程中,发现镧铝硼酸盐LaAl3(BO3)4具有一种新的晶体结构。本文用助熔剂法合成了LnAl3(BO3)4(Ln=Gd,La)单晶样品,LaAl3(BO3)4为薄板状,而GdAl3(BO3)4为六方的棒状,用TREOR90程序对LaAl3(BO3)4粉末样品的X射线衍射数据进行了指标化,结果为:LaAl3(BO3)4属正交晶系,晶胞参数为a=0.93586(4)nm,b=0.79904(3)nm,c=0.40626(6)nm,V=0.34595nm^3,在1000℃空气环境下,用硝酸盐热分解法合成了单相LnAl3(BO3)4:E3 (Ln=Gd,La)荧光粉并研究了其发光特性,结果表明:LnAl3(BO3)4:Eu^3 (Ln=Gd,La)是非常有前途的等离子显示器用荧光粉。 相似文献
35.
YuYingFENG XiaoTianGU JiaHongZHOU JianChunBAO GangLI TianHongLU 《中国化学快报》2004,15(12):1505-1508
New Ge/SiO2 glasses have been synthesized by heating the GeO2/SiO2 dry gels under H2 gas at 700℃. The resulting fluorescence spectra show that this kind of Ge/SiO2 glasses emit strong photoluminescence at 392 nm (3.12 eV), medium strong photoluminescence at 600 nm (2.05 eV) and weak photoluminescence at 770 nm (1.60 eV) respectively. Possible photoluminescence mechanisms are also discussed based on the results of X-ray diffraction (XRD) and X-ray photoelectron spectra (XPS). 相似文献
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M. Jayakannan Paul A. Van Hal Ren A. J. Janssen 《Journal of polymer science. Part A, Polymer chemistry》2002,40(14):2360-2372
Novel alternating conjugated copolymers ( P1–P6 ) consisting of an electron‐deficient benzothiadiazole and a variety of electron‐rich thiophene‐arene‐thiophene units were synthesized by palladium‐catalyzed polycondensations (Stille and Suzuki reactions), aiming at processable materials with a reduced optical band gap. The structures of P1–P6 were confirmed by 1H NMR and 13C NMR, and their molecular weights were determined by size exclusion chromatography. In the Suzuki polycondensation, the role of the catalyst [Pd(PPh3)4 and Pd(OAc)2] on the resulting molecular weight was investigated. Pd(OAc)2 enhances the molecular weight of the polymers for both thiophene and phenylene bis‐boronic esters as compared with Pd(PPh3)4. The optical properties of the polymers were examined in solution and the solid state. The polymers with n‐octyl substituents ( P1 , P4 , P5 , and P6 ) on the thiophene rings possessed less‐planar structures as a result of torsional steric hindrance, and their absorption spectra appeared blueshifted as compared with their unsubstituted analogues ( P2 and P3 ). The electrochemical properties of the polymers were studied using cyclic voltammetry. Although the alkyl substitution affects the oxidation potential, only marginal differences in the reduction potentials were observed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 2360–2372, 2002 相似文献
38.
The synthesis and crystal structure of Li3AlB2O6 with different cell parameters are reported and these cells are transformed each other from the confirmation of crystallographic structural analyses. The absorption spectrum, luminescence and lifetimes of the Li3AlB2O6 and LiSrBO3 solid compounds are measured and the comparisons are made between them. It is shown that the absorption edges are at about 400 nm (or band gap 3.1 eV) and there is one of absorption peaks at about 350 nm for the Li3AlB2O6 and LiSrBO3. The emission band (530 nm) makes a red shift and fluorescence decay time (24.39 ns) of the Li3AlB2O6 becomes smaller compared with the emission band (480 nm) and lifetime (93.16 ns) of the LiSrBO3 at the visible region. The transition energies and oscillator strengths of the clusters (Li3AlB2O6)2 and (LiSrBO3)2 lying at low excited states are calculated by the time-dependent Hartree-Fock method. The obtained results are used to model the photophysical properties and discuss the origin of spectral bands of the Li3AlB2O6 and LiSrBO3. 相似文献
39.
A novel coordination ploymer [{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n was synthesized by the hydrothermal reaction of 3-Na2SBA, ZnSO4·7H2O and 2,2′-bipy. The structure was characterized by elemental analysis, IR and single crystal X-ray diffraction. The title coordination ploymer crystallized in monoclinic with space group P21, a=0.803 42(18) nm, b=1.501 8(3) nm, c=0.821 13(19) nm, β=109.350(4)°. The coordination polymer has an infinite chain structure and its luminescent property has also been studied. CCDC: 282746. 相似文献
40.
纳米材料,包括尺寸为纳米量级的超细微粒?线?薄膜?量子阱和超晶格等引起了人们广泛的重视 [1,2] ?其中 , 半导体纳米微粒和由其构成的纳米固体结构开辟了材料科学研究的新领域?硫化镉 (CdS) 作为一种重要的Ⅱ - Ⅵ族无机半导体材料 , 具有独特的光电性质 , 在光电化学电池和多相光催化反应中都有广泛应用?近年来 , 已有大量关于合成 CdS 纳米结构的文献报导 [3~12] , 所采用的方法如反胶束法?单分子膜法?自组装法以及电化学沉积法等 , 其中非水电解与模板技术相结合的制备方法引起了人们高度的重视并且被广泛的采用?自从 Baranski 等在上… 相似文献