Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation

Piezoresponse force microscopy(PFM) has emerged as one of the most powerful techniques to probe ferroelectric materials at the nanoscale, yet it has been increasingly recognized that piezoresponse measured by PFM is often influenced by electrostatic interactions. In this letter, we report a capacitive excitation PFM(ce-PFM) to minimize the electrostatic interactions. The effectiveness of ce-PFM in minimizing electrostatic interactions is demonstrated by comparing the piezoresponse and the effective piezoelectric coefficient measured by ce-PFM and conventional PFM. The effectiveness is further confirmed through the ferroelectric domain pattern imaged via ce-PFM and conventional PFM in vertical modes, with the corresponding domain contrast obtained by ce-PFM is sharper than conventional PFM. These results demonstrate ce-PFM as an effective tool to minimize the interference from electrostatic interactions and to image ferroelectric domain pattern, and it can be easily implemented in conventional atomic force microscope(AFM)setup to probe true piezoelectricity at the nanoscale.     

参外联合激励下的簇发振荡及其机理

当周期激励频率远小于系统固有频率时,会存在快慢耦合效应,与单项激励不同,参外联合激励不仅会导致快子系统平衡曲线和分岔行为的复杂化,也会产生一些特殊的非线性现象,为此,本文以两耦合Hodgkin-Huxley细胞模型为例,引入周期参外联合激励,探讨在频域不同尺度耦合时该系统的簇发振荡的特点及其分岔机制．通过建立相应的快慢子系统,得到慢变参数变化下的快子系统的各种分岔模式以及相应的分岔行为,结合转换相图,揭示耦合系统随激励幅值变化时的动力学行为及其机理．研究表明,在激励幅值较小时,系统表现为概周期振荡,两频率分别近似于快子系统平衡曲线由Hopf分岔引起的两稳定极限环的振荡频率．概周期解随激励幅值的增加进入簇发振荡,导致这些簇发振荡的主要原因是在慢变参数变化的部分区间内,存在唯一稳定的平衡曲线,使得系统的轨迹逐渐趋向该平衡曲线,产生沉寂态,并随着慢变参数的变化,由分岔进入激发态．同时,快子系统中参与簇发振荡的稳定吸引子随激励幅值的变化也会不同,导致不同形式的簇发振荡．另外,与单项激励下的情形不同,联合激励时快子系统的部分稳定吸引子掩埋在其它稳定吸引子内,从而失去对簇发振荡的影响．     

双光子聚合引发剂BVPDA的合成、结构及非线性光学性质

合成了双光子聚合引发剂{4-[2-(4-溴苯基)-乙烯基]苯基}-二苯基胺(BVPDA),并测定了其晶体结构.结果表明,BVPDA为三斜晶系,P1空间群,a=1.0834(3)_nm,b=1.5625(2)_nm,c=1.9640(2)_nm,α=92.807(8)°,β=103.647(10)°,γ=106.676(13)°,V=3.0705(10)_nm³,Z=6,T=293(2)K,Dc=1.383g/cm³,R₁=0.0735,wR=0.1063.用¹HNMR谱、¹³CNMR谱及元素分析进行了表征.测试了紫外吸收光谱、单光子荧光光谱、单光子荧光寿命和双光子荧光光谱.在760nm的飞秒脉冲激光激发下,BVP-DA发出较强的上转换荧光,荧光峰位于462nm.以BVPDA作引发剂,加入丙烯酸酯型齐聚物(CN120C80),用Ti:sapphire飞秒激光器作光源,制作了一个三维周期性微结构.     

利用电子自旋共振技术捕捉烯类单体双光子聚合反应的自由基信号

<正>自1999年烯类单体的双光子聚合方法被发现以来[1],其产物在光开关制备[2]、光子晶体[3]、微机械[4]及三维微加工[5]等领域得到了广泛的应用.由此,烯类双光子聚合机理也成为人们研究的焦点[6].到目前为止,研究者们普遍认为烯类单体的双光子聚合反应属于自由基历程,各种利用双光子     

纳米钙钛矿型LaFe1-xNixO3(x=0~1.0)的制备及其在紫外光激发下的电化学性能

本文采用溶胶-凝胶法制备了LaFe1-xNixO3(x=0,0.2,0.4,0.6,0.8,1.0)纳米晶粉末,利用XRD、TEM和电化学测试方法对LaFe1-xNixO3材料的相结构、形貌、成分组成和其在碱液中的充放电性能以及电化学动力学性能等方面进行了表征和分析,同时对电极受紫外光激发前后的电化学行为进行了对比研究。XRD和TEM分析表明,用硝酸盐作为原材料和溶胶-凝胶方法可制备出单一相结构的纳米晶钙钛矿型LaFe1-xNixO3复合氧化物,随Ni替代量x的增大,LaFe1-xNixO3的相结构由正交结构向菱面体结构转变,其分子体积和晶粒尺寸呈现减小的趋势。电化学研究结果表明,紫外光激发前,LaFe1-xNixO3电极的放电容量随x的增加而逐渐增大;光激发后,电极的放电容量和交换电流Io与未激发前相比显著提高,当x=0.4时其放电容量具有最大值483.1mAh·g-1,Io值由光激发前的3.54～11.58 mA·g-1大幅增加至激发后的8.37～40.11 mA·g-1。     

Theoretical computation of low‐lying electronic states of HCNS: A CASPT2 study

Complete active space self‐consistent field (CASSCF) and complete active space second‐order perturbation theory (CASPT2) calculations in conjunction with the aug‐cc‐pVTZ basis set have been used to investigate the low‐lying electronic states of thiofulminic acid (HCNS), HCNS⁺, and HCNS^?. The result of geometry optimization using CASPT2/aug‐cc‐pVTZ shows that theoretically determined geometric parameters and harmonic vibrational frequencies for the HCNS ground state X¹Σ⁺(X¹A′) are in agreement with previous studies. The ionization energies, the electron affinity energies, the adiabatic excitation energies, and vertical excitation energies have been calculated and the corresponding cation and anion states are identified. By calculating adiabatic electron affinity, the states of HCNS^? have been identified to contain both π orbital states (X²A′ and 1²A″) and dipole‐bond states (1⁴A′ and 1⁴A″). © 2012 Wiley Periodicals, Inc.     

Approximate Atomic Green Functions

In atomic and many-particle physics, Green functions often occur as propagators to formally represent the (integration over the) complete spectrum of the underlying Hamiltonian. However, while these functions are very crucial to describing many second- and higher-order perturbation processes, they have hardly been considered and classified for complex atoms. Here, we show how relativistic (many-electron) Green functions can be approximated and systematically improved for few- and many-electron atoms and ions. The representation of these functions is based on classes of virtual excitations, or so-called excitation schemes, with regard to given bound-state reference configurations, and by applying a multi-configuration Dirac-Hartree-Fock expansion of all atomic states involved. A first implementation of these approximate Green functions has been realized in the framework of Jac, the Jena Atomic Calculator, and will facilitate the study of various multi-photon and/or multiple electron (emission) processes.     

Parametric excitation of beams moving over supports

Studied in this work are the formulation of equations of motion and the response to parametric excitation of a uniform cantilever beam moving longitudinally over a single bilateral support. The equations of motion are generated by using assumed modes to discretize the beam, by regarding the support as a kinematic constraint, and by employing an alternate form of Kane's method that is particularly well suited to systems subject to constraints. Instability information is developed using the results of perturbation analysis for harmonic longitudinal motions of small amplitude and with Floquet theory for general periodic motions of any amplitude. Results demonstrate that definitive instability information can be obtained for a beam moving longitudinally over supports based on the frequencies of free transverse vibration of a beam that is longitudinally fixed.     

An Optimal Nonlinear Feedback Control Strategy for Randomly Excited Structural Systems

A strategy for optimal nonlinear feedback control of randomlyexcited structural systems is proposed based on the stochastic averagingmethod for quasi-Hamiltonian systems and the stochastic dynamicprogramming principle. A randomly excited structural system isformulated as a quasi-Hamiltonian system and the control forces aredivided into conservative and dissipative parts. The conservative partsare designed to change the integrability and resonance of the associatedHamiltonian system and the energy distribution among the controlledsystem. After the conservative parts are determined, the system responseis reduced to a controlled diffusion process by using the stochasticaveraging method. The dissipative parts of control forces are thenobtained from solving the stochastic dynamic programming equation. Boththe responses of uncontrolled and controlled structural systems can bepredicted analytically. Numerical results for a controlled andstochastically excited Duffing oscillator and a two-degree-of-freedomsystem with linear springs and linear and nonlinear dampings, show thatthe proposed control strategy is very effective and efficient.     

端部激励相位差下斜拉索的非线性振动

斜拉桥中拉索承受着多种端部激励,可激发大幅空间振动．以斜拉索为对象,探究不同端部激励间相位差对其非线性振动的影响．首先,推导斜拉索无量纲离散控制方程,引入考虑相位的三向端部激励得到一般化模型;然后,针对拉索下端存在的纵桥向、竖向和横桥向激励的两两组合,受大幅或小幅激励,及其在主共振区或主参数共振区几组因素,共计12种工况,采用数值分析法分别研究了各工况下不同激励相位差时的斜拉索稳态响应．研究发现：激励相位差能加剧与激励频率相近的面内、外模态振动;在任意端部激励组合下,激励相位差不仅可使斜拉索非线性振动出现定量变化,还可改变内共振的表现形式．面内、外激励组合下,相位差对拉索响应幅值的影响以π为周期变化,且当相位差趋于π/2 + kπ (k = 0, 1, 2…)时影响最为突出;而面内激励组合下,以2π为变化周期,当相位差为π + 2kπ (k = 0, 1, 2, …)时其对稳态幅值的影响最显著．其原因是：面外激励关于拉索所在的竖直面对称,故其本质上以π为周期;而面内激励无此对称性,仍以2π为周期．因此,有无面外激励参与决定了激励间相位差对斜拉索响应的影响规律．