Crystallochemistry of the novel two-layer RECuMg4 (RE=La, Tb) ternary compounds

The crystal structures of the new ternary compounds LaCuMg₄ and TbCuMg₄ were studied by X-ray powder diffraction and single-crystal methods, respectively. Scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDXS) was used for examining microstructure and phase composition. LaCuMg₄ crystallizes in the UCoAl₄ structure type (space group P6¯2m, Pearson code hP18, a=1.03911(1), c=0.45126(1) nm, Z=3, R_F=0.0654), while TbCuMg₄ exhibits a new structure (space group Cmmm, Pearson code oS48, a=1.35797(6), b=2.03333(9), c=0.39149(2) nm, Z=8, wR₂=0.0426). Both structures represent a family of two-layer compounds. All interatomic distances indicate metallic type bonding. The structural peculiarities of these compounds and their relations are discussed.     

水平变化双层波导声传播问题的耦合简正波解

为了验证现有模型的精度,导出了全反射下边界双层波导中简正波耦合矩阵的解析表达式,并将其应用到全局矩阵耦合简正波模型(Direct Global Matrix Coupled-Mode)中,使得该模型可以提供水平变化双层波导问题的标准解。文中首先利用COUPLE的简正波及耦合矩阵数值解验证了该简正波及耦合矩阵解析表达式的正确性;其次,采用改进的DGMCM模型求解了双层波导海山声传播损失,结果表明,改进后的DGMCM模型可以非常精确地求解水平变化双层波导问题,可作为求解此类问题的标准模型使用。     

Wave interaction with a new type perforated breakwater

In this study examined is the wave interaction with a new modified perforated breakwater, consisting of a perforated front wall, a solid back wall and a wave absorbing chamber between them with a two-layer rock-filled core. The fluid domain is divided into three sub-domains according to the components of the breakwater. Then by means of the matched eigenfunction expansion method, an analytical solution is obtained to assess the hydrodynamic performance of the new structure. An approach based on a step approach method is introduced to solve the complex dispersion equations for water wave motions within two-layer porous media. Numerical results of the present model are compared with previous limiting cases. The effects of rock fill on the reflection coefficient and the horizontal wave force are discussed. The project supported by the Program for Changjiang Scholars and Innovative Research Teams in Universities (IRT0420). The English text was polished by Keren Wang.     

Sound scattering by a resistive and axially symmetric object in a two-layer ocean

An acoustically resistive and axially symmetric object is placed in a two-layer ocean very far from a point source of acoustic waves. The object is either floating in the water layer or buried in the sediment layer. Both layers are homogenous. The size of the object is small when compared to the depth of the water channel. The free surface of the sea is assumed to be soft and the bottom is assumed to be hard. Between the two layers the classical diffraction boundary conditions are taken. An extension of the Deep Water Approximation method [Ergatis P. Radiation, propagation and scattering of acoustic waves in an underwater environment. PhD thesis, University of Patras; 1997 (in Greek)] is being provided to cover the case of resistive scatterers [Colton, D., Kress, R. Integral equation methods in scattering theory. New York: Wiley; 1983].     

The temperature-dependent phase diagrams of the spin-3/2 Ising model on a FM/AFM two-layer lattice with a crystal field

The temperature-dependent phase diagrams of the spin-3/2 Ising model on a two-layer Bethe lattice with ferromagnetic (FM)/antiferromagnetic (AFM) intra-layer and either FM or AFM type inter-layer interactions are investigated under a constant magnetic field (H) and in the presence of a crystal field (D) by using exact recursion equations in a pairwise approach for coordination numbers q=3,4 and 6, in detail. In the light of the ground-state (GS) phase diagrams, the temperature-dependent phase diagrams of the model are obtained by studying the thermal variations of the order parameters, response functions and free energy. Then, they are illustrated on the (kT/J₁,J₃/J₁) and (kT/J₁,J₂/J₁) planes for the given system parameters. It is observed that the system exhibits first- and second-order phase transitions for all q values, and hence, in some cases, tricritical points. The existence of critical-end points and that of isolated points are also observed. The re-entrant behavior owes its presence to the two Néel temperatures, T_N, that are present for all q.     

SUSPENSION-SWELLING GRAFT COPOLYMERIZATION——SYNTHESIS OF ACS RESINS*

Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were studied. Highly effective comples dispersing system was chosen and determined, and two-layer protection model was put forward to clarify the stable effect mechanism Varying the swelling time of CPE in AN and St monomer mixture, some results such as grafting effect, particle characteristics, rubber particle morphology and its size distribution, and properties of ACS resins were investigated , thus the optimum swelling time was proposed.     

An efficient direct approach for computing shortest rectilinear paths among obstacles in a two-layer interconnection model

In this paper, we present a direct approach for routing a shortest rectilinear path between two points among a set of rectilinear obstacles in a two-layer interconnection model that is used for VLSI routing applications. The previously best known direct approach for this problem takes O(nlog²n) time and O(nlogn) space, where n is the total number of obstacle edges. By using integer data structures and an implicit graph representation scheme (i.e., a generalization of the distance table method), we improve the time bound to O(nlog^3/2n) while still maintaining the O(nlogn) space bound. Comparing with the indirect approach for this problem, our algorithm is simpler to implement and is probably faster for a quite large range of input sizes.     

Influence of leading-edge lateral injection angles on the film cooling effectiveness of a gas turbine blade

Typical film-cooling configuration of a symmetrical turbine blade leading edge is investigated using a three-dimensional finite volume method and a multi-block technique. The computational domain includes the curved blade surface as well as the coolant regions and the plenum. The turbulence is approximated by a two layer k– model. The computations have been performed using the TLV two-layer and the TLVA models. However, the utilization of the TLV and TLVA models has not improved the prediction of the lateral averaged film cooling effectiveness of gas turbine blades when compared with those obtained using wall function strategy.The general features of film cooling such as jet blow-off, high turbulence intensity in the shear layer, and secondary rotating vortices are captured in the present study. Comparison between predicted and experimental results indicates that the trends of the thermal field are well predicted in most cases. In the second part of this study, the influence of lateral injection angle on lateral averaged adiabatic film cooling effectiveness is investigated by varying the lateral injection angle around the experimental value ( = 25°, 30°, 35° and 60° spanwise to the blade surface). It was found that the best coverage and consequently, the maximum film cooling effectiveness are provided by the most extremely inclined injection angle, which is 25° in this investigation.     

双层夹心膜电极电位法测定溶剂聚合物膜中杯芳烃-金属离子配合物的生成常数

以双层夹心膜电极为指示电极,采用电位法测定了聚合物膜中活性离子载体杯[6]芳烃乙酯与金属离子形成的配合物的生成常数.提出了一种新的测定夹心膜膜电位的方法,由测得的膜电位可计算出配合物的生成常数.以杯[6]芳烃乙酯为离子载体,测得其与Li⁺,Na⁺,K⁺,Cs⁺和NH⁺₄等离子的配合物生成常数的对数值分别为6.14,6.48.6.74,7.43和6.21.制备了以Cs⁺为主离子的选择性电极,采用固定干扰法,测得对Li⁺,Na⁺,K⁺和NH⁺₄等离子的选择性系数的对数值分别为-3.33,-2.54,-1.6和-2.9.实验结果表明,配合物的生成常数与选择性系数之间有较好的相关性.生成常数越大,电极对相应离子的选择性越高.