全文获取类型
收费全文 | 14981篇 |
免费 | 1087篇 |
国内免费 | 1022篇 |
专业分类
化学 | 13384篇 |
晶体学 | 105篇 |
力学 | 68篇 |
综合类 | 10篇 |
数学 | 120篇 |
物理学 | 3403篇 |
出版年
2024年 | 9篇 |
2023年 | 132篇 |
2022年 | 243篇 |
2021年 | 317篇 |
2020年 | 407篇 |
2019年 | 374篇 |
2018年 | 220篇 |
2017年 | 279篇 |
2016年 | 487篇 |
2015年 | 561篇 |
2014年 | 556篇 |
2013年 | 1238篇 |
2012年 | 706篇 |
2011年 | 759篇 |
2010年 | 677篇 |
2009年 | 833篇 |
2008年 | 937篇 |
2007年 | 988篇 |
2006年 | 920篇 |
2005年 | 767篇 |
2004年 | 797篇 |
2003年 | 719篇 |
2002年 | 533篇 |
2001年 | 361篇 |
2000年 | 427篇 |
1999年 | 341篇 |
1998年 | 330篇 |
1997年 | 291篇 |
1996年 | 293篇 |
1995年 | 290篇 |
1994年 | 223篇 |
1993年 | 186篇 |
1992年 | 197篇 |
1991年 | 121篇 |
1990年 | 97篇 |
1989年 | 96篇 |
1988年 | 85篇 |
1987年 | 70篇 |
1986年 | 47篇 |
1985年 | 35篇 |
1984年 | 37篇 |
1983年 | 16篇 |
1982年 | 24篇 |
1981年 | 7篇 |
1980年 | 12篇 |
1979年 | 12篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1976年 | 5篇 |
1972年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
151.
152.
153.
154.
Katsunori Nishimura Rie Hidaka Fumitoshi Hirayama Hidetoshi Arima Kaneto Uekama 《Journal of inclusion phenomena and macrocyclic chemistry》2006,54(1-2):85-88
Geometries, electronic properties and NMR-shielding of cucurbit[5]uril, decamethylcucurbit[5]uril, cucurbit[6]uril, cucurbit[7]uril,
and cucurbit[8]uril are investigated with DFT calculations. All molecules are highly symmetrical with a distinct geometric
flexibility. In addition with a characteristic partial charge distribution these findings account for their chemical complex
building ability. 相似文献
155.
M. G. Voronkov L. I. Larina Yu. I. Bolgova O. M. Trofimova N. F. Chernov V. A. Pestunovich 《Chemistry of Heterocyclic Compounds》2006,42(12):1585-1591
The 1H, 13C, 15N, and 29Si NMR, IR, and UV spectra of N-(1-silatranylmethyl) and N-(trimethoxysilylmethyl) derivatives of nitrogen heterocycles have
been studied. The dependence and interrelation of the chemical shifts of 29Si and 15N nuclei of the silatranyl group in the spectra of N-(1-silatranylmethyl)-substituted nitrogen heterocycles are determined
by the nature of the heterocyclic system.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1857–1865, December, 2006. 相似文献
156.
Luigi Angiolini Daniele Caretti Elisabetta Salatelli Monique Biesemans 《Journal of organometallic chemistry》2006,691(9):1965-1972
Starting from 4-isopropylbenzoic acid, three new triorganotin carboxylates bearing methyl, butyl and phenyl substituents at tin, respectively, were prepared and fully characterized by spectroscopic and thermal techniques, with particular regard to the coordination number of tin atom, in solution as well as in the solid state. The triorganotin compounds, tested as transesterification catalysts in the reaction between ethyl acetate and primary, secondary or tertiary alcohol, respectively, displayed, as expected, a strong decrease of activity on passing from the primary to the tertiary alcohol reactant. Different activities by the tin carboxylates were also observed in the reaction between primary alcohol and ethyl acetate. The reaction mechanism, as elucidated by Sn NMR, involves coordination of both ester substrate and alcohol reactant to the triorganotin compound, the reaction conversion appearing related not only to the Lewis acidity of the tin atom, but also to the nature of the reactants. Preliminary catalytic tests were also carried out in the reaction between glyceryl tridodecanoate (as a model of natural triglyceride) and ethanol, mimicking the preparation of biodiesel fuel. Although in this case lower conversions were obtained with respect to the reactions on ethyl acetate, the catalytic activity of organotin derivatives appears considerable. 相似文献
157.
~(19)F-NMR法测定聚醚多元醇中伯羟基的相对含量 总被引:2,自引:0,他引:2
<正> 聚醚多元醇是聚氨酯材料的主要原料之一.多元醇中伯羟基含量的多少对反应活性有着直接的影响,因此,准确地测定伯羟基含量已成为许多研究者关心的课题,并已报道了不少测定方法,其中主要包括化学动力学方法、~1H-核磁共振(NMR)法和~(19)F-NMR法,~1H-NMR法系利用不同的酰化剂,将聚醚多元醇酰化后测其酰化物的~1H-NMR谱,从伯、仲羟基相应的酯基氢的积分比例来计算伯羟基的相对含量,但由于体系中存在其它含氢基因,且是大量的,使测量困难或应用受到限制.~(19)F-NMR法测伯羟 相似文献
158.
Gáti T Simon A Tóth G Magiera D Moeller S Duddeck H 《Magnetic resonance in chemistry : MRC》2004,42(7):600-604
Adducts of four phosphine chalcogenides with the chiral dirhodium complex ([Rh-Rh]) were investigated by variable-temperature 1H and 31P NMR spectroscopy in order to compare their properties as axial ligands. Whereas the selenide (1) and the sulfide (2) are strong ligands with electrostatic attraction and, in addition, a significant orbital (HOMO-LUMO) interaction, the phosphine oxide compounds (P=O) bind primarily via electrostatic attraction and are relatively weak donors. Moreover, the overall bond strength in these adducts depends on steric congestion around the P=O group. 相似文献
159.
Teleshev A. T. Vasil"eva L. N. Nifant"ev E. E. Tsodikov M. V. Bukhtenko O. V. Zhdanova T. N. 《Russian Chemical Bulletin》2003,52(9):2083-2085
The reactivities of cyclophosphite precursors in alkoxo syntheses involving titanium(iv) tetra(n-butoxide) were studied by 31P NMR and IR spectroscopy. 2-Diethylamido-4-methyl-1,3,2-dioxaphosphinane and 4-ethyl-2,6,7-trioxaphosphabicyclo[2.2.2]octane in benzene are inert toward Ti(OBu)4. Gelation is accompanied by hydrolysis 2-diethylamido-4-methyl-1,3,2-dioxaphosphinane to give the corresponding hydrophosphoryl compound, while 4-ethyl-2,6,7-trioxaphosphabicyclo[2.2.2]octane remains intact during gelation. 相似文献
160.
V. P. Borovik I. Yu. Bagryanskaya Yu. V. Gatilov O. P. Shkurko 《Journal of Structural Chemistry》2003,44(4):650-654
The crystal structures of 2-amino-4-phenyl-9H-pyrimido[4,5-b]indole and its nitrate were determined by XRD analysis. 13C NMR, XRD, and quantum-chemical data indicate that the acid proton is predominantly localized at the N(3) atom of the pyrimidine ring in both isolated nitrate molecules and in molecules in crystal and solution. 相似文献