全文获取类型
收费全文 | 239篇 |
免费 | 9篇 |
国内免费 | 36篇 |
专业分类
化学 | 264篇 |
晶体学 | 5篇 |
综合类 | 1篇 |
物理学 | 14篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 2篇 |
2014年 | 11篇 |
2013年 | 43篇 |
2012年 | 7篇 |
2011年 | 16篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 13篇 |
2007年 | 12篇 |
2006年 | 19篇 |
2005年 | 21篇 |
2004年 | 10篇 |
2003年 | 9篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 8篇 |
1999年 | 10篇 |
1998年 | 7篇 |
1997年 | 3篇 |
1996年 | 10篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1990年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有284条查询结果,搜索用时 15 毫秒
81.
The consecutive reaction of bis [ 2, 2, 2-trifluoroethyl] phosphite and its application to the one-pot synthesis of 3-cyano-β, γ-unsaturated nitriles with exdusive or predominant E-selectivity (E: Z = 100-85: 0-15) and excellent yields (94%-99%) are described. 相似文献
82.
Toshifumi Tsuda 《Tetrahedron》2005,61(45):10719-10733
A direct and practical method for the construction of β-mannosidic linkages is described. While β-selectivities in the TMSOTf-promoted glycosidation of 2,3,4,6-tetra-O-benzyl-d-mannosyl diethyl phosphite are found to be highly dependent on the reactivity of acceptor alcohols, 2,3-di-O-benzyl-4,6-O-benzylidene-d-mannosyl diethyl phosphite reacts with a wide range of acceptor alcohols in the presence of TMSOTf in CH2Cl2 at −45 °C to give β-mannosides in high yields with good to high β-selectivities. 相似文献
83.
N. N. Kabal'nova V. V. Shereshovets A. S. Vorob'ev I. A. Rusakov I. I. Furlei Yu. I. Murinov 《Russian Chemical Bulletin》1993,42(12):2045-2047
The rate constants for the quenching of singlet oxygen by sterically hindered phenols were determined. It was observed that the rate constant for the quenching increases with a decrease in the ionization potential of phenols.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2132–2134, December, 1993.This work was supported by the Russian Foundation for Basic Research (Grant 93-03-5231). 相似文献
84.
迄今, 在中温水热条件下已合成了大量具有空旷骨架结构的过渡金属磷酸盐微孔材料[1], 这类材料在非线性光学材料、磁性材料、超导材料及催化等诸多方面具有潜在的应用前景[2~5]. 相似文献
85.
The reaction of diethyl α-oxoethylphosphonate and diethyl oxobenzylphosphonate with diethyl phosphite, dimethyl phosphite, and diphenylphosphine oxide affords, depending on the substrates and conditions (nature and quantity of the amine catalyst, temperature, and solvent), the Pudovik adduct and/or the corresponding >P(O)–CH–O–P(O)< product formed by rearrangement. The nature of the substituent on the central carbon atom (a methyl or phenyl group) influences the inclination for the rearrangement. The asymmetric products (either adducts or rearranged species) with different P(O)Y functions (Y = RO or Ph) exhibit interesting NMR features. 相似文献
86.
Der-Jang Liaw Kun-Li Wang 《Journal of polymer science. Part A, Polymer chemistry》1996,34(7):1209-1217
A fluorine-containing diamine, 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane (BAPPH) ( II ), was synthesized in two steps on condensation of 2,2-bis(4-hydroxyphenyl)hexafluoropropane with p-chloronitrobenzene in the presence of potassium carbonate, giving 2,2-bis[4-(4-nitrophenoxy)phenyl]hexafluoropropane ( I ), followed by reduction with hydrazine monohydrate/Pd—C. Fluorine-containing polyamides and copolyamides having inherent viscosities 0.41–0.88 dL g−1 were prepared by direct polycondensation of BAPPH with various aromatic diacids or with mixed diacids, by triphenyl phosphite and pyridine in N-methyl-2-pyrrolidinone (NMP). The polyamides were examined by elemental analysis, IR spectra, inherent viscosity, x-ray diffraction, solubility, DSC, and TGA. The diffractogram showed that the polyamides were crystalline except IVb , IVc , IVf , and Vc . Almost all polyamides were soluble in polar aprotic solvents. The polymers obtained from BAPPH lost no mass below 350°C, with 10% loss of mass being recorded above 467°C in nitrogen. These aromatic polyamides had glass transition temperatures in the 221–253°C range. © 1996 John Wiley & Sons, Inc. 相似文献
87.
在具有开放骨架结构的过渡金属磷酸盐微孔材料的合成中,钒磷酸盐因在催化和磁学方面具有潜在的性质和特殊结构特征而引起人们的广泛兴趣.近年来,人们正在尝试用假四面体结构的[HPO3]^2-替代四面体结构的[PO4]^3-,因为{HPO3}结构基元同钒原子的连接方式与{PO4}结构基元和钒原子的连接方式具有明显的差别, 相似文献
88.
Sheng‐Huei Hsiao Li‐Min Chang 《Journal of polymer science. Part A, Polymer chemistry》2000,38(9):1599-1608
A series of new poly(imide‐hydrazide)s and poly(amide‐imide‐hydrazide)s were obtained by the direct polycondensation of N‐[p‐(or m‐)carboxyphenyl]trimellitimide (p‐ or m‐CPTMI) with terephthalic dihydrazide (TPH), isophthalic dihydrazide (IPH), and p‐aminobenzhydrazide (p‐ABH) by means of diphenyl phosphite and pyridine in the N‐methyl‐2‐pyrrolidone (NMP) solutions containing dissolved CaCl2. The resulting hydrazide‐containing polymers exhibited inherent viscosities in the 0.15–0.96 dL/g range. Except for that derived from p‐CPTMI with TPH or p‐ABH, the other hydrazide copolymers were readily soluble in polar solvents such as NMP and dimethyl sulfoxide (DMSO). As evidenced by X‐ray diffraction patterns, the hydrazide copolymer obtained from TPH showed a moderate level of crystallinity, whereas the others were amorphous in nature. Most of the amorphous hydrazide copolymers formed flexible and tough films by solvent casting. The amorphous hydrazide copolymers had glass‐transition temperatures (Tg) between 187 and 233 °C. All hydrazide copolymers could be thermally converted into the corresponding oxadiazole copolymers approximately in the region of 250–400 °C, as evidenced by the DSC thermograms. The oxadiazole copolymers showed a significantly decreased solubility when compared to their respective hydrazide precursors. They exhibited Tg's of 264–302 °C and did not show dramatic weight loss before 400 °C in air or nitrogen. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1599–1608, 2000 相似文献
89.
采用固相亚磷酸三酯法和化学与酶促相结合的方法合成了9个PstI接头片段,并对它们进行了酶切反应研究.结果表明:PstI识别序列中尿苷的存在只降低其互补链的切割程度,对其本链没有影响;PstI切割底物是按两步单股切割机制进行,作用的最小底物是含有识别序列的8~12聚脱氧核糖核苷酸,且对底物中识别序列两边的碱基对数目有一定要求;PstI识别序列中的二个胞苷在酶反应中起的作用是不一样的 相似文献
90.