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41.
A variety of 2-arylthio-4-methoxybenzoates are regioselectively prepared by TiCl4-mediated [3+3] cyclocondensations of 3-arylthio-1-trimethylsilyloxy-1,3-butadienes with 3-oxo-orthoesters. Unsubstituted 2-(arylthio)benzoates were prepared by Me3SiOTf-catalyzed cyclization of 3-arylthio-1-trimethylsilyloxy-1,3-butadienes with 1,1,3,3-tetramethoxypropane. The TiCl4-mediated cyclization of 3-arylthio-1-trimethylsilyloxy-1,3-butadienes with 1,1-bis(methylthio)-1-en-3-ones results in regioselective formation of 2-arylthio-6-(methylthio)benzoates. 相似文献
42.
2-Acetyl- and 2-alkoxycarbonyl-3-(trifluoromethyl)phenols were prepared by [3+3] cyclization of 1,3-bis-silyl enol ethers with 4-ethoxy- and 4-silyloxy-1,1,1-trifluoroalk-3-en-2-ones. 相似文献
43.
Hengchang MaQiangsheng Sun Wenfeng LiJinxia Wang Zhe ZhangYaoxia Yang Ziqiang Lei 《Tetrahedron letters》2011,52(14):1569-1573
Pd(acac)2 catalyzed dimerization of vinylarenes to form dimers under mild condition with excellent yields and stereoselectivities. In particular, the use of TFA highly promoted the activity and selectivity of the dimerization. The studies on mechanism for the reaction displayed clearly that the dimerization of styrenes is 100% atom economic reaction. 相似文献
44.
Ihsan Ullah Rasheed Ahmad Khera Muhammad Nawaz Inam Iqbal Alexander Villinger Peter Langer 《Tetrahedron》2010,66(21):3824-3835
Sterically encumbered biaryls are prepared in two steps by combination of the CuI-proline-catalyzed arylation of acetylacetone with formal [3+3] cyclizations of 1,3-bis(trimethylsilyloxy)-1,3-dienes. In addition, the synthesis of 4,6- and 5,6-diarylsalicylates based on [3+3] cyclizations is reported. 相似文献
45.
46.
Friedel-Crafts reaction of 1-(N-acylamino)alkyltriarylphosphonium salts with arenes or heteroarenes without the need for any catalyst provided access to a wide range of biologically interesting N-(1-arylalkyl)amides or 1-arylalkylphosphonium salts which can be of great interest in the chemistry of ylides and phosphonium ionic liquids. Depending on reaction conditions and substrate structure, the reaction can be conducted selectively with high yields toward each of the above-mentioned products. Mechanistic aspects of the above transformations were also considered. 相似文献
47.
Thomas Baker 《合成通讯》2013,43(18):2747-2752
We report the preparation of two bifunctional silyl triflates, 1,1,4,4-tetramethyl-1,4-disila-1,4-butanediyl-bis(trifluoromethanesulfonate) and 1,1,5,5-tetramethyl-1,5-disila-1,5-pentanediyl-bis(trifluoromethanesulfonate). Detailed synthetic procedures and characterization data are described. 相似文献
48.
Inam Iqbal Nasir Rasool Muhammad A. Rashid Alexander Villinger Peter Langer 《Tetrahedron》2009,65(36):7562-8801
Functionalized 2-(arylthio)benzoates are prepared by formal [3+3] cyclizations of 3-arylthio-1-trimethylsilyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones and 1,1-diacylcyclopropanes. 相似文献
49.
The first fluoroalkylated 1,3-bis(silyloxy)-1,3-butadienes have been prepared. Their reaction with oxalyl chloride provides a convenient approach to fluoroalkylated γ-alkylidenebutenolides. 相似文献
50.
The reaction of palladium(II) bromide or palladium(II) iodide with the respective gallium(III) halogenide in the presence of aromatic solvents leads to the formation of palladium(II) tetrabromo— and tetraiodogallate. The compounds are isostructural {monoclinic, C2/m, Pd[GaBr4]2: a = 1267(2), b = 808(1), c = 722(1) pm, β = 94.5(1)°; Pd[GaI4]2: a = 1363(1), b = 849.9(4), c = 756.6(7) pm, β = 95.38(3)°}. The structures contain mononuclear complexes Pd[GaX4]2, where X— = Br— ( 1 ), I— ( 2 ). The crystal structures of 1 and 2 were determined by single‐crystal X‐ray diffraction. Crystals of both compounds turned out to be similarly twinned. 相似文献