全文获取类型
收费全文 | 6008篇 |
免费 | 242篇 |
国内免费 | 230篇 |
专业分类
化学 | 3332篇 |
晶体学 | 6篇 |
力学 | 681篇 |
综合类 | 46篇 |
数学 | 1136篇 |
物理学 | 1279篇 |
出版年
2024年 | 16篇 |
2023年 | 60篇 |
2022年 | 114篇 |
2021年 | 90篇 |
2020年 | 105篇 |
2019年 | 114篇 |
2018年 | 90篇 |
2017年 | 118篇 |
2016年 | 144篇 |
2015年 | 134篇 |
2014年 | 195篇 |
2013年 | 363篇 |
2012年 | 258篇 |
2011年 | 303篇 |
2010年 | 296篇 |
2009年 | 326篇 |
2008年 | 312篇 |
2007年 | 384篇 |
2006年 | 290篇 |
2005年 | 289篇 |
2004年 | 275篇 |
2003年 | 221篇 |
2002年 | 223篇 |
2001年 | 166篇 |
2000年 | 177篇 |
1999年 | 182篇 |
1998年 | 155篇 |
1997年 | 191篇 |
1996年 | 151篇 |
1995年 | 182篇 |
1994年 | 119篇 |
1993年 | 56篇 |
1992年 | 65篇 |
1991年 | 69篇 |
1990年 | 57篇 |
1989年 | 41篇 |
1988年 | 31篇 |
1987年 | 14篇 |
1986年 | 11篇 |
1985年 | 15篇 |
1984年 | 16篇 |
1983年 | 11篇 |
1982年 | 12篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1973年 | 3篇 |
排序方式: 共有6480条查询结果,搜索用时 15 毫秒
191.
Summary Rare earth elements 1,3,5-benzenetricarboxylates were prepared as solids of the general formula Ln(C9H3O6)·nH2O, where n=6 for La-Dy and n=4 for Ho-Lu,Y. Their solubilities in water at 293 K are of the order 10-4-10-6 mol dm-3. The IR spectra of the complexes indicate that the carboxylate groups are bridging and bidentate chelates. Hydrated 1,3,5-benzenetricarboxylates
lose water molecules during heating in one step (La-Tb), two steps (Y, Ho-Tm) or three steps (Dy, Yb, Lu). The anhydrous complexes
are stable up to 573-742 K and decompose to oxides (Ce-Lu) at higher temperatures. 相似文献
192.
天然药物及制剂中微量元素硒的测定方法概况 总被引:1,自引:0,他引:1
硒是人体必需的微量元素,具有抗肿瘤、防衰老、防辐射和增强机体免疫力等多种功能。本文就国内近年来对天然药物及其制剂中微量元素硒的分析方法概况作一综述,包括:原子吸收分光光度法、荧光分光光度法、电感耦合等离了光谱法、催化分光光度法、分光光度法、化学发光淬灭法、极谱法、中子活化分析法和色谱法等。 相似文献
193.
本工作通过比较端视与侧视ICP的分析性能,研究了端视ICP系统对稀土元素的分析特性。高频发生器输出功率与载气流量对端视与侧视ICP激发特性的影响没有明显差异,取光方式的不同是二者分析性能差异的根本原因。端视ICP由于取光时避开了产生连续背景的环形热区和截取了整个中心通道的光谱,其背景减小,谱线强度增强,获得较好的测定下限。对14种稀土元素测定下限的比较表明:端视ICP比铡视ICP下降10-30倍。 相似文献
194.
A method has been developed enabling direct analysis (i.e. after dilution only) of beer, instant coffee, milk, and milk powder by ICP–AES. Analysis of the beverages after dilution with a low concentration of HNO3 was used for accurate determination of essential minor and trace elements (Ca, Mg, K, P, S, and Zn). Selenium, introduced as the hydride, was determined simultaneously with the other non-hydride-forming elements using the commercial multi-mode sample-introduction system (MSIS). To obtain accurate results, however, some simple pre-treatment was needed. Analysis was also performed after microwave-assisted decomposition of the samples. Three different modes of sample-preparation, i.e. dilution only, partial decomposition (aqua regia treatment), and complete decomposition were compared. The results obtained by use of the three different sample-preparation methods were in very good agreement. Results from analysis of certified reference material (SRM 1459 non-fat milk powder) also verified the accuracy of the methods. The limit of detection obtained for Se using dual-mode sample introduction was 0.5 ng mL–1, which corresponds to approximately 2 ng g–1 in beer and approximately 4 ng g–1 in coffee and milk when using the recommended procedure. 相似文献
195.
用原子捕获技术提高火焰原子吸收光谱法的灵敏度 总被引:1,自引:0,他引:1
采用简易的石英原子捕获器,使Cu,Ag,Au,Zn,Cd,Pb,Sb,Bi等易挥发元素在空气-乙炔火焰原子吸收光谱法中的灵敏度提高了3~5倍,并有较好的精密度,相对标准偏差在1%左右,方法中用此技术测定了标准物质中Pb、Cd的含量,获得了满意的结果,它较之石墨炉原子吸收光地具有快速,简便的特点,具有较大的实用价值。 相似文献
196.
An analytical procedure for dissolving wolframite in order to determine trace elements by atomic absorption is reported. After decomposition of the mineral by alkaline fusion, the cooled flux is dissolved by heating with aqua regia. The finely crystalline precipitate of tungstite, which forms on standing, is filtered and dissolved by heating with aqua regia. Tungstite forms again in the latter solution and the filtration and solubilization are repeated until the solution contains negligible amounts of trace elements. Following this procedure, trace elements in 35 samples of natural wolframite have been dissolved and the solutions obtained have been analyzed by atomic absorption spectrometry for Fe, Mn, Cu, Zn, Pb, Co, Ni and Cd. 相似文献
197.
30名受试者平均年龄59.5±6.9岁.其中女性11名。每名受试者连续饮用微量元素活性剂口服液1个月。结果表明.血清总胆固醇由6.037mmol/L减少到4.867mmol/L,P<0.01。低密度脂蛋白由4.470mmol/L减少到3.667mmol/L.P<0.O1.甘油三脂和极低密度脂蛋白也分别降低了9.8%和10.6%;而高密度脂蛋白由0.720mmol/L增至1.003mmol/L,P<O.O5;血浆丙二醛浓度由4.435mmol/L降至4.081mmol/L,P<0.05:红细胞谷胱甘肽过氧化物酶和超氧化物歧化酶浓度均升高。血脂和血脂蛋白的变化表明.微量元素活性剂口服液对中老年人防治脑动脉硬化和冠心病具有良好作用。 相似文献
198.
佳木斯地区中草药微量元素的测定 总被引:1,自引:0,他引:1
采用原子吸收分光光度法测定了佳木斯地区产12种中草药的元素含量,为本地区中草药资源的开发和利用提供了有意义的数据。 相似文献
199.
吕明松 《广东微量元素科学》1997,4(7):52-54
以临床典型病案为例,探讨了中医中药传统理论和现代微量元素研究的关系,重点讨论了向量元素锌、宏量元素钙与高血压、风湿症的病因病机和治疗关系。 相似文献
200.
Atsushi Mizuike 《中国化学会会志》1990,37(2):117-124
Trace element speciation has recently become one of the most important problems in water analysis. Proper combination of preconcentration techniques with instrumental determination methods is essential to speciation analysis, because sensitivity and selectivity of direct determination methods are generally lacking. The present paper describes such preconcentration techniques as filtration, centrifugation, flotation and sorption, which have been developed in the author's laboratory for the speciation of heavy metals in river and pond waters by electron microscopy, X-ray microanalysis and chemical analysis. The application of freeze concentration to the speciation of silica in high-purity waters is also discussed. 相似文献