光学非球面凹面零件仿形加工方法的修正

从圆锥体靠模仿形法加工非球面光学零件的基本原理出发,指出加工凸非球面时无原理误差,但加工凹非球面时,只能用圆弧包络法加工。用实心圆锥体靠模时,必然存在误差。解决方法是减小工具的曲率半径,或增加一维数控进行补偿,或使用空心圆锥体仿形。实际应用中前两种方法只能减小误差,不能消除。而采用凹模仿形时,则不存在原理误差。     

矿山尾矿中微量银元素快速检测方法的研究

针对矿山尾矿中微量银元素测定的技术难题,提出了一种基于超短光路原理的能量色散X荧光能谱快速检测的方法。提高元素测量分辨率,提高样品分析效率,降低光管功率,延长仪器使用寿命。能谱系统优化了滤片以及探测器屏蔽物等设计,准直器采用对X射线基本无散射的聚四氟乙烯,达到微量银元素的检测要求。实际尾矿测试中,银的检出限达到0.1 mg·kg-1,RSD在0.1%～2.6%之间,准确度在87%～115%之间。对比尾矿、原矿及精矿的检测实验,证明了在能量色散X荧光能谱中引入超短光路设计方法,能够提升系统峰/本底比,满足微量银元素的检测要求。     

微光像增强器用核心材料的发展现状与展望

微光像增强器是微光夜视技术的核心器件,决定了整机的视距、清晰度、使用寿命等关键性能。详细分析了光纤面板、倒像器、纤维光锥、微通道板等微光像增强器核心材料的原理、特性及发展趋势,展望了微光夜视技术的发展方向。     

大口径光学元件检测中的主要误差及其影响

 使用PSD作为大口径光学元件的质量评价标准,标定了测试系统的传递函数,并讨论了在对ICF驱动器中所使用的光学元件进行检测时产生的几种主要误差,分析了这些误差在进行计算和分析时可能造成的影响以及消除的方法。     

三元配合物光度法测定痕量钴的研究

本文提出了 Co( ) -硫氰酸钾 -结晶紫 -聚乙烯醇三元配合物体系光度法测定 Co( )的新方法。该方法灵敏度 ε=3.18× 10 5L·mol-1· cm-1,选择性好 ,精密度高 ,用于水中痕量钴的测定。结果令人满意     

The Mineral Content of Rhizona cyperi after Microwave-Assisted Digestion and Determination by AAS

ABSTRACT

Rhizoma cyperi (tuberal part of Cyperus rotundus Linn) obtained from 15 different zones of China was studied to determine the contents of 16 trace elements such as 4 minor (Ca, K, Mg, and Na), 9 trace (Co, Cr, Cu, Fe, Mn, Mo, Ni, V, and Zn), and 3 toxic (Ag, Cd, and Pb) elements. The concentration determination of 16 elements was performed by atomic absorption spectrophotometry (AAS) after microwave-assisted digestion. A microwave-assisted digestion procedure based on the mixture nitric acid–hydrogen peroxide was evaluated. The method was successfully validated with the good recoveries (97–105%) against CRM GBW07603 (bush twigs and leaves). The calibration curve furnished good linear correlation coefficients (r = 0.9956–0.9999), excellent recoveries (99.35–103.7%), and limits of detection (LOD = 1–50 ng·mL^?1) suitable to determine in Rhizoma cyperi. The results showed that K, Ca, Mg, and Na were the most abundant of the major elements in Rhizoma cyperi with average concentrations of K, 26,221 µg·g^?1; Ca, 1097 µg·g^?1; Mg, 714 µg·g^?1, and Na, 293 µg·g^?1, respectively. K element was determined for the first time in this plant.     

Infrared Absorption Study of Some Cyclic Ureas,Cyclic Thioureas and Their N,N′-Dialkyl Derivatives

Abstract

In his communication on the detection limits for thermal emission spectroscopy of metallic species in flame media, Fassel (¹) attacks our previous statement that detection limits for Al, Be and Mo were available only for turbulent oxygen-supported hydrogen or acetylene flames. It should be borne in mind that he was referring to a preliminary communication (²) which naturally does not carry an extensive bibliography. It should also be noted that we were concerned, in context, with a comparison of the separated flame with conventional flames, not with highly unconventional flames such as those to which he refers. Whilst the point with which he takes issue was a very minor one, incorporated in our preliminary communication mainly as an “aside”, we firmly disagree with his observation. The flame he refers to (³) (⁴) is, in fact, a diluted oxy-acetylene flame which is supported by venting some air (and therefore nitrogen) to dilute the fuel-oxygen mixture. Fassel's communication (¹) erroneously refers to this as a 'premixed oxy-acetylene flame', whereas elsewhere (⁵) it is described more correctly as an oxygen-nitrogen-acetylene flame. The burner he long-pathlength carbonaceous flames (¹⁰). They also allow more sensitive molecular emission spectroscopy of sulphur in an air-hydrogen flame (¹¹), etc. We hope that this unfortunate correspondence will not distract attention from the main issue of our previous or previous preliminary communication on the separated nitrous oxide-acetylene flime.     

Der Einsatz von Sorbentien räumlich-globulrer Struktur zur Abtrennung radioaktiver Verunreinigungen aus Wasser

Abstract

Possibilities of using a new generation of sorbents have been investigated. Polymers of spatial-globular (spherulitic) structure (RGS polymers) have been tested to separate Cs, Sr and rare earth elements – which can also be radioactive contaminants – from different waters.

RGS polymers are both, solids and highly-disperse systems being extremely permeable to fluids and gases with low pressure decline. They were currently used to clean industrial waste-water.

It is shown that these polymers can be used successfully to separate radionuclides. Polymers RGS-81 and RGS-112 have high distribution coefficients for CS, Sr, Sc, the lanthanide series and Hf in weakly acid solutions. In HF solutions, Sc and Hf can be separated from Cs, Sr and the lanthanides.     

二阶Y环频率选择表面的设计研究

利用分形结构的自相似性将分形理论应用于频率选择表面(FSS)领域即可使在单屏FSS上具有多频段带通滤波的特性,结合Floquet周期边界条件,采用矩量法研究了二阶Y环分形FSS在不同入射角度下迭代比例因子F及单元排布方式对频率响应特性的影响规律,给出谐振频率的经验估算值.计算及实验结果表明,FSS的谐振频率主要由迭代比例因子及起始单元尺寸决定,而透过率及-3 dB带宽则对排布方式的改变较敏感.实验结果与理论分析一致.     

原子光谱法测定野生龙葵果中微量元素的含量

采用火焰原子吸收光谱法直接测定了野生龙葵果中铁、锰、锌、铜、钙、镁的含量,再运用原子荧光光谱法测定野生龙葵果中硒的含量。选用硝酸和高氯酸(5∶1)混合消解液进行消解。结果所测定的龙葵果中含有丰富的人体必需微量元素。本方法简单、准确,回收率在93.5%—101.0%之间,相对标准偏差(RSD)小于1.46%,结果令人满意。