全文获取类型
收费全文 | 32547篇 |
免费 | 1337篇 |
国内免费 | 1105篇 |
专业分类
化学 | 26692篇 |
晶体学 | 255篇 |
力学 | 288篇 |
综合类 | 166篇 |
数学 | 6040篇 |
物理学 | 1548篇 |
出版年
2023年 | 265篇 |
2022年 | 434篇 |
2021年 | 392篇 |
2020年 | 510篇 |
2019年 | 690篇 |
2018年 | 682篇 |
2017年 | 829篇 |
2016年 | 909篇 |
2015年 | 877篇 |
2014年 | 912篇 |
2013年 | 1531篇 |
2012年 | 1680篇 |
2011年 | 1835篇 |
2010年 | 1616篇 |
2009年 | 1948篇 |
2008年 | 1522篇 |
2007年 | 1773篇 |
2006年 | 1516篇 |
2005年 | 1411篇 |
2004年 | 1249篇 |
2003年 | 988篇 |
2002年 | 1055篇 |
2001年 | 701篇 |
2000年 | 783篇 |
1999年 | 712篇 |
1998年 | 653篇 |
1997年 | 642篇 |
1996年 | 632篇 |
1995年 | 657篇 |
1994年 | 567篇 |
1993年 | 455篇 |
1992年 | 360篇 |
1991年 | 386篇 |
1990年 | 358篇 |
1989年 | 304篇 |
1988年 | 395篇 |
1987年 | 391篇 |
1986年 | 302篇 |
1985年 | 321篇 |
1984年 | 326篇 |
1983年 | 180篇 |
1982年 | 290篇 |
1981年 | 261篇 |
1980年 | 210篇 |
1979年 | 179篇 |
1978年 | 67篇 |
1977年 | 46篇 |
1976年 | 46篇 |
1975年 | 26篇 |
1974年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
F. Balibrea 《Topology and its Applications》2006,153(12):2092-2095
Recently, Forti, Paganoni and Smítal constructed an example of a triangular map of the unite square, F(x,y)=(f(x),g(x,y)), possessing periodic orbits of all periods and such that no infinite ω-limit set of F contains a periodic point. In this note we show that the above quoted map F has a homoclinic orbit. As a consequence, we answer in the negative the problem presented by A.N. Sharkovsky in the eighties whether, for a triangular map of the square, existence of a homoclinic orbit implies the existence of an infinite ω-limit set containing a periodic point. It is well known that, for a continuous map of the interval, the answer is positive. 相似文献
32.
We show that there are close relations between extremal problems in dual Brunn-Minkowski theory and isotropic-type properties for some Borel measures on the sphere. The methods we use allow us to obtain similar results in the context of Firey-Brunn-Minkowski theory. We also study reverse inequalities for dual mixed volumes which are related with classical positions, such as ?-position or isotropic position. 相似文献
33.
Summary Excessive breakdown of elastin, a structural protein, may be related to aortic disease and emphysema. Since L-valyl-L-proline occurs in high concentrations in elastin, a rapid and sensitive method using HPLC with post-column on-line derivatization was used to measure the dipeptide from swine aortic tissue, and the amount of elastin present was determined. Elastin was extracted by alkaline hydrolysis. After neutralization and filtration, the sample was injected onto a ODS-2 gel column, and the dipeptide was eluted by a linear gradient of 0 to 10% of 1-propanol in 50 mM heptafluorobutyrate, pH 3, at a flow rate of 1 ml/min. The eluent was reacted with fluorescamine at pH 8.6, and fluorescence was detected at an excitation wavelength of 395 nm and a 455 nm cutoff emission filter.Presented at the 17th International Symposium on Chromatography, September 25–30, 1988, Vienna, Austria. 相似文献
34.
35.
E. L. Kristallovich A. G. Eshimbetov N. D. Chuvylkin L. I. Belen'kii Kh. M. Shakhidoyatov 《Chemistry of Natural Compounds》2003,39(5):495-500
The principal types of electronic transitions in absorption spectra of deoxyvasicinone and its 6-amino- and 6-nitro-derivatives were determined by analyzing the electron-density distributions in excited states calculated using ZINDO/S. 相似文献
36.
Donghyun Cho Taihyun Chang Apostolos Avgeropoulos Nikos Hadjichristidis 《European Polymer Journal》2003,39(11):2155-2160
Temperature gradient interaction chromatography (TGIC) was applied for the separation of a complex miktoarm star copolymer which has one polystyrene (PS) arm and three polystyrene-b-polyisoprene (PS-b-PI) diblock copolymer arms. Such miktoarm star polymers are much more difficult to characterize than branched homopolymers since the byproduct, typically polymers with missing arm(s) or coupled products, have not only different molecular weights but also different compositions. TGIC was able to fully separate the byproducts, and the composition of the molecular species corresponding to the different separated elution peaks was determined by two methods, fractionation/NMR and multiple detection (UV and RI). A reasonable agreement between the results of the two methods was obtained. By using the composition found, the corresponding molecular weights were determined by multi-angle light scattering detection. Based on the composition and the molecular weight we were able to identify the structure of the different molecular species. 相似文献
37.
毛细管气相色谱法测定中药中有机氯农药残留量 总被引:4,自引:0,他引:4
建立了江西省两种中药中有机氯农药残留量的气相色谱分析方法。样品以丙酮提取,在NaCl存在下,以正已烷进行液—液分配,提取液用H2SO4净化,采用DB—1701毛细管柱,GC—ECD检测有机氯农药残留量。最低检测限为1.0×10-3-5.0×10-3mg/kg,添加回收率为85.7%-115.2%,应用于实际样品中有机氯农药残留量的检测,获得了较为满意结果。 相似文献
38.
The existence of an attractor for a 2D-Navier-Stokes system with delay is proved. The theory of pullback attractors is successfully applied to obtain the results since the abstract functional framework considered turns out to be nonautonomous. However, on some occasions, the attractors may attract not only in the pullback sense but in the forward one as well. Also, this formulation allows to treat, in a unified way, terms containing various classes of delay features (constant, variable, distributed delays, etc.). As a consequence, some results for the autonomous model are deduced as particular cases of our general formulation. 相似文献
39.
In this paper, the detailed asymptotic behaviour of the solutions of a kinetic equation for quantum particles is studied. It is shown that this behaviour is sensitive not only to the total mass of the initial data but also to its precise behaviour near the origin. In some cases, solutions develop a Dirac mass at the origin for long times in a self-similar manner that is analysed in detail. 相似文献
40.
The dynamic structure factors (DSFs) of several strong glasses (SF6, SF10, BK7, SUPRASIL) measured by Brillouin light scattering spectroscopy are reported. Spectra have been collected, at and above room temperature, at two scattering angles, θ=90° and θ=180° corresponding to exchanged wavevector q values ranging from 0.0256 to 0.0448 nm−1. In particular we find that the isotropic spectral lineshapes are in all cases well described by the simple hydrodynamic theory of an amorphous solid. The width of the Brillouin peaks are found to be consistent with the predicted q2 dependence at both investigated temperatures. This damping is however found to account only partially for the strong asymmetry of the Brillouin line clearly visible on a logarithmic intensity scale. As a matter of fact there is an excess intensity in the very low frequency plateau underlying the central component. The height of this plateau and hence the entire lineshape is well reproduced if a relaxation process is taken into account in the hydrodynamic equations. Owing to the intense elastic scattering we are able to determine unambiguously only the ratio between amplitude and characteristic time of this process which quantifies the sound dispersion to be of the order of a few percent in all samples. The temperature dependence of the parameters indicates that this relaxation cannot be attributed to thermally activated relaxation phenomena. These general findings favorably compare with molecular dynamics simulation results on similar systems. 相似文献