Syntheses and characterization of 16‐arm star and star diblock copolymer and AB8 9‐miktoarm star copolymer via NMRP and ROP from dendritic multifunctional macroinitiators

A dendritic macroinitiator having 16 TEMPO‐based alkoxyamines, Star‐16 , was prepared by the reaction of a dendritic macroinitiator having eight TEMPO‐based alkoxyamines, [G‐3]‐OH , with 4,4′‐bis(chlorocarbonyl)biphenyl. The nitroxide‐mediated radical polymerization (NMRP) of styrene (St) from Star‐16 gave 16‐arm star polymers with PDI of 1.19–1.47, and NMPR of 4‐vinylpyridine from the 16‐arm star polymer gave 16‐arm star diblock copolymers with PDI of 1.30–1.43. The ring‐opening polymerization of ε‐caprolactone from [G‐3]‐OH and the subsequent NMRP of St gave AB₈ 9‐miktoarm star copolymers with PDI of 1.30–1.38. The benzyl ether linkages of the 16‐arm star polymers and the AB₈ 9‐miktoarm star copolymers were cleaved by treating with Me₃SiI, and the resultant poly(St) arms were investigated by size exclusion chromatography (SEC). The SEC results showed PDIs of 1.23–1.28 and 1.18–1.22 for the star polymers and miktoarm stars copolymers, respectively, showing that they have well‐controlled poly(St) arms. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1159–1169, 2007.     

Banach-stone theorems and separating maps

LetC(X,E) andC(Y,F) denote the spaces of continuous functions on the Tihonov spacesX andY, taking values in the Banach spacesE andF, respectively. A linear mapH:C(X,E)→C(Y,F) isseparating iff(x)g(x)=0 for allx inX impliesHf(y)Hg(y)=0 for ally inY. Some automatic continuity properties and Banach-Stone type theorems (i.e., asserting that isometries must be of a certain form) for separating mapsH between spaces of real- and complex-valued functions have already been developed. The extension of such results to spaces of vector-valued functions is the general subject of this paper. We prove in Theorem 4.1, for example, for compactX andY, that a linear isometryH betweenC(X,E) andC(Y,F) is a “Banach-Stone” map if and only ifH is “biseparating (i.e,H andH ⁻¹ are separating). The Banach-Stone theorems of Jerison and Lau for vector-valued functions are then deduced in Corollaries 4.3 and 4.4 for the cases whenE andF or their topological duals, respectively, are strictly convex. Research supported by the Fundació Caixa Castelló, MI/25.043/92     

Kreĭn–Saakyan and Trace Formulas for a Pair of Canonical Differential Operators

An analog of the Kreĭn–Saakyan formula is derived for any pair of relatively prime self-adjoint extensions of a minimal symmetric canonical differential operator. This allows us to deduce a trace formula in the matrix case. I am grateful to Sh. Saakyan for his interest in this work and lively discussion. Received: December 8, 2006. Accepted: December 30, 2006.     

Engel Values in Residually Finite Groups

The following theorem is proved. Let n be a positive integer and q a power of a prime p. There exists a number m = m(n, q) depending only on n and q such that if G is any residually finite group satisfying the identity ([x _1,n y ₁] ⋯ [x _m,n y _m ])^q ≡ 1, then the verbal subgroup of G corresponding to the nth Engel word is locally finite.     

Estimation of intrinsic processes affected by additive fractal noise

Fractal Gaussian models have been widely used to represent the singular behavior of phenomena arising in different applied fields; for example, fractional Brownian motion and fractional Gaussian noise are considered as monofractal models in subsurface hydrology and geophysical studies Mandelbrot [The Fractal Geometry of Nature, Freeman Press, San Francisco, 1982 [13]]. In this paper, we address the problem of least-squares linear estimation of an intrinsic fractal input random field from the observation of an output random field affected by fractal noise (see Angulo et al. [Estimation and filtering of fractional generalised random fields, J. Austral. Math. Soc. A 69 (2000) 1-26 [2]], Ruiz-Medina et al. [Fractional generalized random fields on bounded domains, Stochastic Anal. Appl. 21 (2003a) 465-492], Ruiz-Medina et al. [Fractional-order regularization and wavelet approximation to the inverse estimation problem for random fields, J. Multivariate Anal. 85 (2003b) 192-216]. Conditions on the fractality order of the additive noise are studied to obtain a bounded inversion of the associated Wiener-Hopf equation. A stable solution is then obtained in terms of orthogonal bases of the reproducing kernel Hilbert spaces associated with the random fields involved. Such bases are constructed from orthonormal wavelet bases (see Angulo and Ruiz-Medina [Multiresolution approximation to the stochastic inverse problem, Adv. in Appl. Probab. 31 (1999) 1039-1057], Angulo et al. [Wavelet-based orthogonal expansions of fractional generalized random fields on bounded domains, Theoret. Probab. Math. Stat. (2004), in press]). A simulation study is carried out to illustrate the influence of the fractality orders of the output random field and the fractal additive noise on the stability of the solution derived.     

The Riesz decomposition of finely superharmonic functions

This paper answers a question of Fuglede about minimal positive harmonic functions associated with irregular boundary points. As a consequence, an old and central problem of fine potential theory, concerning the Riesz decomposition, is resolved. Namely, it is shown that, on certain fine domains, there exist positive finely superharmonic functions which do not admit any positive finely harmonic minorant and yet are not fine potentials.