全文获取类型
收费全文 | 5850篇 |
免费 | 305篇 |
国内免费 | 1043篇 |
专业分类
化学 | 6119篇 |
晶体学 | 150篇 |
力学 | 60篇 |
综合类 | 42篇 |
数学 | 28篇 |
物理学 | 799篇 |
出版年
2023年 | 31篇 |
2022年 | 101篇 |
2021年 | 110篇 |
2020年 | 118篇 |
2019年 | 118篇 |
2018年 | 135篇 |
2017年 | 180篇 |
2016年 | 160篇 |
2015年 | 131篇 |
2014年 | 195篇 |
2013年 | 563篇 |
2012年 | 410篇 |
2011年 | 304篇 |
2010年 | 224篇 |
2009年 | 323篇 |
2008年 | 330篇 |
2007年 | 400篇 |
2006年 | 385篇 |
2005年 | 372篇 |
2004年 | 331篇 |
2003年 | 288篇 |
2002年 | 243篇 |
2001年 | 187篇 |
2000年 | 179篇 |
1999年 | 149篇 |
1998年 | 121篇 |
1997年 | 141篇 |
1996年 | 132篇 |
1995年 | 145篇 |
1994年 | 112篇 |
1993年 | 117篇 |
1992年 | 101篇 |
1991年 | 50篇 |
1990年 | 35篇 |
1989年 | 37篇 |
1988年 | 31篇 |
1987年 | 15篇 |
1986年 | 26篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 11篇 |
1981年 | 19篇 |
1980年 | 20篇 |
1979年 | 16篇 |
1978年 | 8篇 |
1977年 | 13篇 |
1976年 | 10篇 |
1974年 | 8篇 |
1973年 | 10篇 |
排序方式: 共有7198条查询结果,搜索用时 15 毫秒
91.
研究了经尿道等离子体双极电切除术(PKRP)切除和经尿道前列腺电切术(TURP)切除的前列腺增生(BPH)组织对640, 660, 680, 700, 720, 740, 760, 780, 800, 820, 840, 860和880 nm波长的钛宝石激光的光学特性及其差异,实验采用双积分球测量系统以及反向倍增法获取BPH组织的吸收和散射特性参数。结果表明:PKRP和TURP切除的BPH组织对这13个不同波长的激光的吸收系数和约化散射系数都是随着激光波长增大而明显减小的,PKRP切除的BPH组织对这同一波长的激光的吸收系数和约化散射系数都明显较TURP切除的BPH组织对相应的波长的激光的吸收系数和约化散射系数要小,PKRP和TURP切除的BPH组织的吸收系数以及约化散射系数的最大值都在640 nm,其值分别为(0.885±0.022)和(0.955±0.024)mm-1以及(1.564±0.039)和(1.658±0.042)mm-1,其差异分别为7.91%以及6.01%,其最小值都在880 nm,其值分别为(0.443±0.011)和(0.455±0.011)mm-1以及(1.117±0.028)和(1.197±0.030)mm-1,其差异分别为2.71%以及7.16%。PKRP和TURP切除的BPH组织对660 nm的吸收系数的差异最大,其值为8.95%,其差异最小在860 nm,其值为1.75%,PKRP和TURP切除的BPH组织对800 nm的约化散射系数的差异最大,其值为9.13%,其差异最小在640 nm,其值为6.01%。 相似文献
92.
The microstructure, hardness and corrosion resistance of commercially pure Ti treated by low energy high current pulsed electron beam (LEHCPEB) have been investigated. The thin near-surface melted layer rapidly solidified into β and subsequently transformed into ultrafine α′ martensite. This has led to a drastic improvement of the corrosion properties and a significant increase (more than 60%) in hardness of the top surface. 相似文献
93.
E. Vogli W. Tillmann U. Selvadurai-Lassl G. Fischer J. Herper 《Applied Surface Science》2011,257(20):8550-8557
In this research work, Ti/TiAlN multilayers of various designs were deposited onto substrates pretreated by different etching procedures. The influence of multilayer design and substrate pretreatment on multilayers adhesion, hardness, wear and friction coefficients was systematically analyzed and correlated with residual stresses of these multilayers as well as with residual stresses on the coating-near substrate region, which were analyzed by synchrotron X-ray diffraction at HZB-BESSYII. These investigations show that the adhesion can be improved by a specific etching procedure, which cause increased compressive stress in the coating-near the substrate region. Additionally, it was found, that the multilayer with the thickest ceramic layers has the highest hardness and the lowest wear coefficients as well as the lowest compressive residual stress within studied multilayers. 相似文献
94.
Raman and mid-infrared spectroscopic study of geometrically frustrated hydroxyl cobalt halides at room temperature 下载免费PDF全文
Mid-infrared absorption and Raman spectra of the geometrically frustrated material series,hydroxyl cobalt halides β-Co 2 (OH) 3 Cl and β-Co 2 (OH) 3 Br,are first,to the best of our knowledge,measured at room temperature,to study the corresponding relationship between their vibrational spectral properties and crystal microstructures.Through the comparative analysis of the four spectra we have categorically assigned the OH-related vibration modes of hydroxyl groups in the trimeric hydrogen bond environment (Co 3 ≡OH) 3… Cl/Br,and tentatively suggested vibration modes of O-Co-O,Co-O and Cl/Br-Co-Cl/Br units.These results can also become the basis for analysing their low-temperature spectral properties,which can help to understand the underlying physics of their exotic geometric frustration phenomena around phase transition temperatures. 相似文献
95.
Thiosemicarbazide lithium chloride [TSLC] a new semiorganic nonlinear optical crystal has been synthesized. Single crystals by TSLC have been grown by slow evaporation solution growth technique at room temperature. Chemical composition of the synthesized material was confirmed by elemental analysis. Powder X-ray diffraction (XRD) pattern of the grown crystal has been studied. Functional groups present in the materials were identified by FT IR spectral analysis ranging between 4000 and 450 cm−1. The optical transmission was studied through UV-vis spectrophotometer. Thermal analysis is carried out on the crystal and inferred to be stable at 176 °C. The second harmonic generation (SHG) of the TSLC crystal was confirmed using Nd:YAG laser and also fluorescence spectral analysis is carried out for the TSLC crystal. 相似文献
96.
"在Pt/Ti/SiO2/Si基片上用溶胶-凝胶法生长制备了PZT(Pb(Zr1-xTix)O3)复合梯度铁电薄膜. 薄膜最终结构由6层组成,"向上"梯度薄膜在Pt底电极上的第一层从PbZrO3开始,顶层是PZT(50/50),即第一层是PbZrO3,第二层PZT90/10 (10%Ti),第三层是PZT80/20,第四层PZT70/30,第五层PZT60/40,第六层PZT50/50.每一层与此相反的是"向下"梯度PZT薄膜.用X射线衍射、俄歇电子能谱和阻抗分析来研究梯度薄膜的结构与介电特性.600 相似文献
97.
利用混合物理化学气相沉积法(hybrid physical-chemical vapor deposition, HPCVD)可以制备出高性能的MgB2超导薄膜, 再对薄膜进行钛(Ti)离子辐照处理.经过辐照处理后的样品被掺入了Ti元素, 与未处理的干净MgB2样品相比,其超导转变温度没有出现大幅度的下降, 而在外加磁场下的临界电流密度得到了明显的提高,同时样品的上临界磁场也得到了提高. 在温度5 K, 外加垂直磁场为4 T的情况下, Ti离子辐照剂量为1× 1013/cm2的样品的临界电流密度达到了1.72× 105 A/cm2, 比干净的MgB2要高出许多,而其超导转变温度仍能维持在39.9 K的较高水平. 相似文献
98.
用新型的具有恒定温度环境的反应热量计,以一定比例的 HCl(3.0 mol·L-1)与无水乙醇的混合溶液作为量热溶剂,分别测定了反应物[CdCl2·5/2H2O,p-tol]和产物[Cd(p-tol)2Cl,H2O]的溶解焓,设计了一个新的热化学循环,得到了氯化镉与对甲基苯胺配位反应的反应焓△rHm=-7.598kJ·mol1-,并计算出了配合物Cd(p-tol)2Cl2的标准生成焓.推荐其值为:△rHm=(p-tol)2Cl2,s]=-490.773kJ·mol-1 相似文献
99.
Qinghong Zhou 《Optics Communications》2011,284(13):3378-3382
The optimization analysis of the output power of the injection-locked cw Ti:sapphire lasers is presented based on the fact that the injection-locked and free-running lasers almost have the same maximum output power. With the modified Ti:sapphire laser model, the dependences of the threshold and slope efficiency on the ring cavity and crystal parameters are studied through the numerical calculations, which clarify the roles of various parameters in affecting the output power. Our calculated results are in good agreement with the reported experimental data for the laser at 756 nm. Therefore our numerically calculated results could be used as a guideline for designing and optimizing such kind of the lasers. 相似文献
100.
采用溶胶-凝胶法(Sol-gel)制备了不同烧结温度和Tm3+掺杂浓度的Y2Ti2O7:xTm (x=0.005,0.01,0.03,0.05)荧光粉,分别采用X射线衍射分析仪(XRD)、透射电子显微镜(TEM)和荧光光谱仪对样品的晶型结构、形貌以及发光性能进行了表征。XRD结果表明,所得到的样品为单一立方相烧绿石结构。样品在361 nm紫外光激发下发射出 蓝光,其峰值波长为456 nm,对应于Tm3+的1D2→3F4跃迁。1 000 ℃烧结的Y2Ti2O7: 0.01Tm3+样品具有较好的发光性能。样品在456 nm处的相对发光强度随Tm3+掺杂浓度的增大先升高后降低,在Tm3+摩尔分数为1%时达到最大,即出现了浓度猝灭现象。 相似文献