全文获取类型
收费全文 | 13958篇 |
免费 | 1134篇 |
国内免费 | 2550篇 |
专业分类
化学 | 13693篇 |
晶体学 | 153篇 |
力学 | 474篇 |
综合类 | 68篇 |
数学 | 1201篇 |
物理学 | 2053篇 |
出版年
2024年 | 34篇 |
2023年 | 128篇 |
2022年 | 290篇 |
2021年 | 356篇 |
2020年 | 496篇 |
2019年 | 492篇 |
2018年 | 450篇 |
2017年 | 631篇 |
2016年 | 665篇 |
2015年 | 565篇 |
2014年 | 650篇 |
2013年 | 1405篇 |
2012年 | 958篇 |
2011年 | 818篇 |
2010年 | 688篇 |
2009年 | 749篇 |
2008年 | 790篇 |
2007年 | 799篇 |
2006年 | 747篇 |
2005年 | 717篇 |
2004年 | 674篇 |
2003年 | 518篇 |
2002年 | 463篇 |
2001年 | 418篇 |
2000年 | 427篇 |
1999年 | 402篇 |
1998年 | 353篇 |
1997年 | 315篇 |
1996年 | 292篇 |
1995年 | 251篇 |
1994年 | 255篇 |
1993年 | 215篇 |
1992年 | 148篇 |
1991年 | 88篇 |
1990年 | 74篇 |
1989年 | 52篇 |
1988年 | 48篇 |
1987年 | 25篇 |
1986年 | 30篇 |
1985年 | 33篇 |
1984年 | 34篇 |
1983年 | 16篇 |
1982年 | 33篇 |
1981年 | 17篇 |
1980年 | 5篇 |
1979年 | 11篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 5篇 |
1974年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
62.
In this paper, we report the conducting and electrochemical properties of a homogeneous V2O5-SiO2 xerogel composite obtained from the simultaneous polymerization in both inorganic components (Si-O and V-O based polymers) forming an interpenetrating polymer network, where a mutual “solubility” due to cross-links and entanglements was observed. The presence of V2O5 inside the silica matrix has a strong effect on electrical conductivity; measurements showed room temperature conductivity almost 1000 times higher than what is found in the literature. In addition, the electrochemical behavior is quite similar to that found in V2O5 xerogel. Moreover, the effects of thermal treatment on the conducting and electrochemical properties were investigated. It was found that both properties were improved with no significant effect on V2O5 xerogel layered structure. 相似文献
63.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献
64.
技术联盟的共生演化分析 总被引:1,自引:0,他引:1
企业组建技术联盟的根本目的,就是基于自己能力缺陷,分散风险,降低研发成本,共享技术收益,是一个典型的利益共生体.Logistic生物种群共生进化模型给技术联盟共生体提供了一个分析框架.分析结果表明:对于主体不均等的技术联盟,主导企业从合作伙伴中获得的收益是非常有限的,远远低于自己对伙伴企业的贡献,并且这种联盟方式要求企业之间的分工程度要高;而对于主体均等的技术联盟而言,双方的贡献相差不大,都相对比较小.技术联盟企业通过分工形式形成各种关系,以激烈的竞争维持着共生模式的稳定性. 相似文献
65.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
66.
A. V. Pastukhov V. A. Davankov E. V. Sidorova E. I. Shkol’nikov V. V. Volkov 《Russian Chemical Bulletin》2007,56(3):484-493
An automated procedure was developed for monitoring fast changes in the size of spherical samples of polymers during their
contact with a solvent or drying. The kinetics of bulk deformation in these processes was studied for a series of cross-linked
polymers, viz., gel-type and porous styrene—divinylbenzene copolymers and poly(divinylbenzenes), and hypercrosslinked polystyrenes. Gel,
macroporous, and hypercrosslinked polystyrenes are substantially different in the rate, mechanism, and degree of swelling,
which is associated with the principal differences in their physical structures. An unusual effect of a sharp decrease followed
by a temporary increase in the volume of porous polystyrene and poly(divinylbenzene) materials were observed during desorption
(evaporation) of organic solvents. Water desorption is accompanied by an excessive bulk compression of porous granules giving
rise to negative deformations, which gradually relax to the state equilibrium for the dry polymer. The results of dynamic
desorption porometry (for water desorption) are indicative of a bimodal size distribution of micropores in hypercrosslinked
polystyrene.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 467–476, March, 2007. 相似文献
67.
68.
A transient molecular network model is built to describe the nonlinear viscoelasticity of polymers by considering the effect
of entanglement loss and regeneration on the relaxation of molecular strands. It is an extension of previous network theories.
The experimental data on three thermoplastic polymers (ABS, PVC and PA6) obtained under various loading conditions are used
to test the model. Agreement between the theoretical and experimental curves shows that the suggested model can describe successfully
the relaxation behavior of the thermoplastic polymers under different loading rates by using relatively few relaxation modes.
Thus the micromechanism responsible for strain-rate dependence of relaxation process and the origin of nonlinear viscoelasticity
may be disclosed.
The project supported by the National Natural Science Foundation of China and Doctorial Fund 相似文献
69.
The current status of the R & D activities is presented on electron beam processing of polymers being carried out at TRCRE. Topics included are sterilization of medical products, graft polymers for selective separation or absorbents and curing of liquid prepolymer-monomer systems. 相似文献
70.
Stefan Wörner Boryana Racheva-Iotova Stoyan Stoyanov 《Mathematical Methods of Operations Research》2002,55(2):247-263
Applying real options thinking to company valuation seems theoretically and intuitively appealing. However, the real option
analogy of a single European option as well as the compound option proxy perform poorly when applied to company valuation.
We therefore suggest to rework the building blocks of real option applications to corporate valuation.
We introduce a framework to delineate the distribution of the underlying asset in the risk neutral world, which is important
in order to value any derivative. This is achieved by an algorithm to calibrate a basket option model using real world data
of observed share prices. The fitting takes account of the class of stable distributions. The index of stability of asymmetric
α stable distribution serves as an over-all parameter to characterise the specific distribution. 相似文献