全文获取类型
收费全文 | 6102篇 |
免费 | 188篇 |
国内免费 | 711篇 |
专业分类
化学 | 4130篇 |
晶体学 | 51篇 |
力学 | 398篇 |
综合类 | 12篇 |
数学 | 166篇 |
物理学 | 2244篇 |
出版年
2024年 | 6篇 |
2023年 | 71篇 |
2022年 | 101篇 |
2021年 | 103篇 |
2020年 | 150篇 |
2019年 | 108篇 |
2018年 | 113篇 |
2017年 | 170篇 |
2016年 | 199篇 |
2015年 | 159篇 |
2014年 | 270篇 |
2013年 | 437篇 |
2012年 | 425篇 |
2011年 | 503篇 |
2010年 | 396篇 |
2009年 | 480篇 |
2008年 | 476篇 |
2007年 | 501篇 |
2006年 | 474篇 |
2005年 | 287篇 |
2004年 | 259篇 |
2003年 | 204篇 |
2002年 | 156篇 |
2001年 | 125篇 |
2000年 | 104篇 |
1999年 | 88篇 |
1998年 | 77篇 |
1997年 | 73篇 |
1996年 | 60篇 |
1995年 | 53篇 |
1994年 | 71篇 |
1993年 | 42篇 |
1992年 | 46篇 |
1991年 | 40篇 |
1990年 | 34篇 |
1989年 | 26篇 |
1988年 | 16篇 |
1987年 | 20篇 |
1986年 | 12篇 |
1985年 | 13篇 |
1984年 | 14篇 |
1983年 | 2篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1973年 | 3篇 |
1970年 | 1篇 |
排序方式: 共有7001条查询结果,搜索用时 15 毫秒
31.
32.
Summary The role of chemical reactions in the selection of patterns in phase-separating mixtures is presented. Linearized theory and
computer simulation show that the initial long-wavelength instability characteristic of spinodal decomposition is suppressed
by chemical reactions, which restrict domain growth to intermediate length scales even in the late stages of phase separation.
Our findings suggest that chemical reactions may provide a novel way to stabilize and tune the steady-state morphology of
phase-separating materials.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
33.
架起传统与现代的桥梁--建筑历史与理论课程体系教学改革的思考 总被引:2,自引:0,他引:2
邱枫 《宁波大学学报(理工版)》2004,17(4):485-488
重新审视建筑历史理论教学的目标、内容、教学方式和手段,通过对国内几座有影响的建筑院校的调研,比较各个院校在这些问题及途径上的异同,分析其利弊,以期促进建筑历史与理论课程体系教学的建设和改革. 相似文献
34.
Willem Potze 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(4):575-586
A mathematical model is proposed to describe the heat transfer in quartz glass axisymmetric tubes. Heat is transferred inside the glass by radiation and conduction. Scattering of thermal radiation inside the glass is ignored. At the boundaries of the tube the radiative intensity is specularly reflected. The spectral dependent radiative intensity and the temperature distribution inside the tube are determined. The model is applied to simulate the cooling process of a quartz glass tube. The calculated temperature is in agreement with that obtained from an experiment. Furthermore, steady-state temperature distributions in quartz glass tubes of different lengths have been determined. 相似文献
35.
Synthesis and Structure of K3N Two phases in the binary system K/N have been obtained via co‐deposition of potassium and nitrogen onto polished sapphire at 77 K and subsequent heating to room temperature. The powder diffraction pattern of one of these phases can be satisfactorily interpreted by assuming the composition K3N, and the anti‐TiI3 structure‐type, which is also adopted by Cs3O. The resulting hexagonal lattice constants are: a = 779.8(2), c = 759.2(9) pm, Z = 2, P63/mcm. Comparison with possible structures of K3N generated by computational methods and refined at Hartree‐Fock‐ and DFT level, reveals that the energetically most favoured structure has not formed (presumable Li3P‐type), but instead one of those with very low density. In this respect, the findings for K3N are analogous to the results on Na3N. The thermal evolution of the deposited starting mixture has been investigated. Hexagonal K3N transforms to another K/N phase at 233 K. Its XRD can be fully indexed resulting in an orthorhombic cell a = 1163, b = 596, c = 718 pm. Decomposition leaving elemental potassium as the only residue occurs at 263 K. 相似文献
36.
Marek Pękała Jan Mucha Benedicte Vertruyen Rudi Cloots Marcel Ausloos 《Journal of magnetism and magnetic materials》2006
Samples of La0.7Ca0.3Mn1−xGaxO3 with x=0, 0.025, 0.05 and 0.10 were prepared by standard solid-state reaction. They were first characterized chemically, including the microstructure. The magnetic properties and various transport properties, i.e. the electrical resistivity, magnetoresistivity (for a field below 8 T), thermoelectric power and thermal conductivity measured each time on the same sample, are reported. The markedly different behaviour of the x=0.1 sample from those with a smaller Ga content, is discussed. The dilution of the Mn3+/Mn4+ interactions with Ga doping considerably reduces the ferromagnetic double exchange interaction within the manganese lattice leading to a decrease of the Curie temperature. The polaron binding energy varies from 224 to 243 meV with increased Ga doping. 相似文献
37.
F. Namouchi H. Guermazi C. Zerrouki S. Agnel J.J. Bonnet 《European Polymer Journal》2007,43(11):4821-4829
Charges evolution in poly(methyl methacrylate) (PMMA) samples under thermal aging effect has been studied by means of two complementary techniques, thermal step method (TSM) and thermally stimulated depolarization current (TSDC). For the first method, measurements reveal that injected charges, whose quantity is found depending on the number of applied temperature cycles, remain close to the surface sample. TSDC measurements have been carried out for different temperatures ranging from 25 °C to 140 °C. Three distinguishable dipolar relaxations (β1, β2 and α) have been highlighted. In the same way, the presence of polarization and injected charges has been confirmed. In support of electric characterization, X-ray reflectometry has been used. The obtained results equally emphasized the thermal aging effect on the material. 相似文献
38.
The behavior of the specific heat cp, effective mass M*, and the thermal expansion coefficient of a Fermi system located near the fermion condensation quantum phase transition (FCQPT) is considered. We observe the first type behavior if the system is close to FCQPT: the specific heat
,
, while the thermal expansion coefficient
. Thus, the Grüneisen ratio Γ(T)=/cp does not diverges. At the transition region, where the system passes over from the non-Fermi liquid to the Landau Fermi liquid, the ratio diverges as
. When the system becomes the Landau Fermi liquid, Γ(T,r)∝1/r, with r being a distance from the quantum critical point. Provided the system has undergone FCQPT, the second type takes place: the specific heat behaves as
, M*∝1/T, and =a+bT with a,b being constants. Again, the Grüneisen ratio diverges as
. 相似文献
39.
Micro-hotplates operated at elevated temperature form the basic element in several sensor devices, such as integrated calorimetric or Taguchi-type gas sensors and flow-rate sensors. In all of these applications thermal properties of the sensing elements play a determining role in functional operation, therefore, their accurate characterisation is essential. The micro-hotplates investigated were developed by one side porous silicon micro-machining technology, forming Pt micro-filaments embedded in non-stoichiometric silicon nitride, and suspended across a cavity. This work is dealing with the accurate temperature detection in the micro-scale by different measurement methods for the deduction of steady state and transient thermal properties from the results. Transient properties of the structure were investigated by application of a simplified thermal equivalent circuit model. 相似文献
40.
The purpose of this work was to investigate the effect of several factors (anion type in the copper salt, pH and concentration of the salt solution) on the structure and thermo-oxidative degradation of the polyacrylamidoxime-copper chelates, by using elemental analysis, IR spectroscopy and dynamic thermogravimetry. The chelates containing copper ions as sulphate exhibit a better initial thermal stability than the polyacrylamidoxime fibre presumably due to the crosslinking generated by the intermolecular complexation of the ions; the removal of the sulphate anions takes place concomitantly with the second step of polymeric chain decomposition. The initial thermal decomposition of the chelates formed by copper ions as nitrate begins at lower temperatures as compared to the polyacrylamidoxime fibre, probably by the nitrate anion release, which partly overlaps the initial decomposition of the copper ion-crosslinked polymeric chains. Copper ions as either sulphate or nitrate catalyse the reactions involved in the main step of polyacrylamidoxime fibre decomposition; the higher the copper amount, the stronger the catalytic effect. 相似文献