彩色光谱三维属性加密技术的研究

在大量的彩色图像处理工作中,已研究和发展了许多方法和技术对光谱颜色进行定量的控制、变换。无论失真彩色复现,还是假彩色合成,均能做到颜色的定量描述。本论文阐述用彩色光谱的三维属性进行编码演算,在浩瀚的颜色空间中进行线性和非线性的颜色参量映射变换,形成难以辨认和难以破解的密码图,对文本、图像的传递实现加密,是一个创新的技术。     

MoSi2 laser cladding—a comparison between two experimental procedures: Mo–Si online combination and direct use of MoSi2

There are very strong interests in developing low density advanced material systems for service at temperatures up to 1300°C. These materials should mainly have moderate fracture toughness at low and intermediate temperatures and should exhibit oxidation resistant behaviour. The intermetallic compound, MoSi₂ has been considered to be an attractive candidate due to its melting point (2030°C) and excellent oxidation resistance at high temperatures. In this paper, we compare the results obtained with two different techniques for laser cladding, one using an online combination between Mo and Si powders, the second using direct injection of the MoSi₂ powder.     

MESURA 2000: a strategy to integrate a true communication network of metrology experts with process technology experts

 The Centro Nacional de Metrología (CENAM) has developed the MESURA Interinstitutional Network in collaboration with other research and development institutes in Mexico. This network has the aim of providing integral metrological services to industry throughout the country, with uniform standards of quality and consistency. The fulfillment of this aim has been possible because of a number of factors that have made the MESURA Program an attractor for the integration of metrological services. Among these factors are: an unswerving focus on the customer needs, an integral and logical problem solving approach to consultancy, adequate modular classification of the consultants functions, clear-cut definition of the functions of each member of interdisciplinary groups, and a uniform code of communication among the members of the network. The next stage of the strategy is to strengthen the link between metrology and its industrial applications forming a new type of consultant with the technical experts from R&D Centers. These will be consultants with general knowledge and experience in metrology, specialized in certain type of industrial processes and products. The strategy will be initiated in the year 2000 and with it the MESURA Network is expected to make a strong contribution to fostering the optimum use of metrology in industry and to act as a channel for the integration of other technologies in which the participating Centers have expertise.     

全合成法光纤预制棒制造研究

介绍了一种全新的全合成法G.655和G.656光纤制造工艺,详细分析了该工艺中芯层折射率差Δ0、芯层厚度a、第二包层的折射率差Δ2、第二包层的厚度c2等结构参量与光纤光学性能的关系.结果表明,制造该两种光纤时,Δ0应在0.012 0～0.015 5之间,Δ2应在0.014 0～0.023 0之间,a应在2.8～3.2 μm之间,c2应在满足截止波长的要求下尽可能小.     

Green synthesis and application of nanoscale zero-valent iron/rectorite composite material for P-chlorophenol degradation via heterogeneous Fenton reaction

A zero-valent iron/rectorite nanocomposite (NZVI/rectorite) was developed as a heterogeneous H₂O₂ catalyst for P-chlorophenol degradation. The physicochemical properties of NZVI/rectorite were characterized by various techniques including X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive spectrometry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller analysis. Results showed that NZVI sphere nanoparticles were successfully loaded on the rectorite surface with less aggregation and good dispersion. Moreover, compared with acid-leached rectorite (30.91 m²/g), the NZVI/rectorite appeared to have larger surface area (50.75 m²/g). In addition, the effects of pH, reaction time, initial P-chlorophenol concentration, catalyst amount, and H₂O₂ dosage on the P-chlorophenol degradation were systematically investigated. Results showed that NZVI/rectorite presents better properties for the degradation and mineralization of P-chlorophenol compared with pristine NZVI due to the large surface area, low aggregation, and good dispersion of the former. The degradation mechanisms of P-chlorophenol by NZVI/rectorite were adsorption and reduction coupled with a Fenton-like reaction. Four successive runs of the stability and regeneration study also showed that the NZVI/rectorite were unchanged even after 100% of P-chlorophenol degradation ratio. This study has extended the application of NZVI/rectorite as environment function material for the removal of P-chlorophenol from the environment.     

Coordination numbers for rigid spheres and local compositions

The coordination numbers of rigid spheres were simulated on a computer to obtain an improved empirical equation when surrounding spheres are of uniform size. In the case of two different species of surrounding spheres, the coordination numbers vary as a function of local composition and radius ratios. By fitting simulation results, correlations were proposed, which are expected to be of practical use in thermodynamic of real solutions.     

Synthesis of tubuphenylalanine and epi-tubuphenylalanine via regioselective aziridine ring opening with carbon nucleophiles followed by hydroboration-oxidation of 1,1-substituted amino alkenes

An efficient synthesis of N-Boc-tubuphenylalanine benzyl ester (N-Boc-Tup-OBn, 1a) and N-Boc-epi-tubuphenylalanine benzyl ester (N-Boc-epi-Tup-OBn, 1b) is reported herein. Regioselective aziridine 4 ring opening with carbon nucleophiles followed by hydroboration of 1,1-substituted aminoalkene 3 using 9-BBN and subsequent oxidation in an alkaline medium are used as the key steps to provide N-tosyl 1,4-aminoalcohols. The 1,4-aminoalcohols are successfully transformed into the desired products with an overall yield of 23% for 1a and 11% for 1b over 8 consecutive steps separately.     

High-resolution IR spectrum of fluoroform: a close resonance

A very close triple resonance is observed in the Q-branch region of the C-H stretching fundamental transition in CF₃H. The vibrational perturbations are analysed in terms of the rotational structure and of the vibrational zero-order spectrum of totally symmetric states. The relationship to time-dependent intramolecular processes is discussed.