Correction of optical distortions in dry depth profiling with confocal Raman microspectroscopy

We present a generalized approach to obtain improved Raman intensity profiles from in‐depth studies performed by confocal Raman microspectroscopy (CRM) with dry objectives. The approach is based on regularized deconvolution of the as‐measured confocal profile, through a kernel that simulates optical distortions due to diffraction, refraction and collection efficiency on the depth response. No specific shape or restrictions for the recovered profile are imposed. The strategy was tested by probing, under different instrumental conditions, a series of model planar interfaces, generated by the contact of polymeric films of well‐defined thickness with a substrate. Because of the aforementioned optical distortions, the as‐measured confocal response of the films appeared highly distorted and featureless. The signal computed after deconvolution recovers all the films features, matching very closely with the response expected. Copyright © 2011 John Wiley & Sons, Ltd.     

Application of multi-frame approach in single-frame blind deconvolution

A new single-frame blind deconvolution algorithm for the linear shift-invariant imaging system is presented. The algorithm processes the partial images segmented from one single degraded image by multi-frame approach to recover the point spread function (PSF). Then a deconvolution method is employed to restore the whole image with the recovered PSF. In addition, in order to improve the fidelity and resolution of the recovered PSF, the coprimeness of the partial images is utilized. Results of simulated and real atmospheric turbulence degraded images using the algorithm are reported.     

程序升温大体积进样和解卷积气相色谱-质谱法测定蔬菜水果中32种农药残留量

建立了蔬菜、水果中有机磷、有机氯、拟除虫菊酯和氨基甲酸酯等32种农药的气相色谱-质谱(GC-MS)检测方法。样品经乙腈提取,石墨碳黑串联丙氨基固相萃取柱净化,采用程序升温大体积进样,GC-MS全扫描模式采集,结合解卷积技术定性分析,内标法定量。分别对程序升温和大体积进样等条件进行了研究,并考察了方法选择性和耐用性。在最优条件下,32种农药的响应值与浓度呈良好的线性关系(r>0.995),各农药的方法检出限为2.0~5.0 μg/kg,以菠菜、四季豆和黄瓜为代表基质,进行3个水平(0.010~0.50 mg/kg)的加标回收试验(n=6),回收率为65.2%~120.3%,相对标准偏差(RSD)为4.1%~22.3%。该方法快速、灵敏、可靠、耐用,能满足蔬菜、水果中多类多残留痕量分析的要求。     

Metamictization in zircon. Part I: Raman investigation following a Rietveld approach: Profile line deconvolution technique.

The line profile form of Raman spectra can be analyzed using the very same approach and software used for diffractogram deconvolution via the Rietveld approach. In both cases the ‘true’ profile containing information about the sample must be separated from the instrument's profile function (and potentially from the emission profile) which can be achieved by deconvolution. In this first part of a two‐part study we demonstrate how the instrument's function can be described via a Gaussian function profile (yielding the very same result as several convoluted hat functions) using several examples (diamond, calcite, silicon and silicon carbide) for which true Raman bandwidth values are presented (assuming the true band profile to be Lorentzian). Also, asymmetrical bands can be described and analyzed via the presented deconvolution approach. The second part of this study will discuss and apply this method for studying the radiation‐induced damage in zircon grains (metamictization). Copyright © 2008 John Wiley & Sons, Ltd.     

Chemometric deconvolution of gas chromatographic unresolved conjugated linoleic acid isomers triplet in milk samples

A generally known problem of GC separation of trans-7;cis-9; cis-9,trans-11; and trans-8,cis-10 CLA (conjugated linoleic acid) isomers was studied by GC–MS on 100 m capillary column coated with cyanopropyl silicone phase at isothermal column temperatures in a range of 140–170 °C. The resolution of these CLA isomers obtained at given conditions was not high enough for direct quantitative analysis, but it was, however, sufficient for the determination of their peak areas by commercial deconvolution software. Resolution factors of overlapped CLA isomers determined by the separation of a model CLA mixture prepared by mixing of a commercial CLA mixture and CLA isomer fraction obtained by the HPLC semi-preparative separation of milk fatty acids methyl esters were used to validate the deconvolution procedure. Developed deconvolution procedure allowed the determination of the content of studied CLA isomers in ewes’ and cows’ milk samples, where dominant isomer cis-9,trans-11 is eluted between two small isomers trans-7,cis-9 and trans-8,cis-10 (in the ratio up to 1:100).     

仿生鳍条姿态测量及其误差分析

在复杂环境下齿轮箱信号往往会淹没在噪声信号中,特征向量难以提取。为了有效的进行故障诊断,提出了基于最大相关反褶积(MCKD)总体平均经验模态分解(EEMD)近似熵和双子支持向量机(TWSVM)的齿轮箱故障诊断方法。首先采用MCKD方法对强噪声信号进行滤波处理,在采用EEMD方法对齿轮箱信号进行分解,分解后得到本征模函数(IMF)分量进行近似熵求解,得到齿轮特征向量,最后将其输入到TWSVM分类器中进行故障识别。仿真实验表明,采用MCKD-EEMD方法能够有效的提取原始信号,与其他分类器相比,TWSVM的计算时间短,分类效果好等优点。     

谱域光学相干层析系统中基于解卷积方法的像质优化

谱域光学相干层析（spectral domain optical coherence tomography, 简记为SD-OCT）系统的轴向点扩散函数（point spread function, 简记为PSF）并不具备空不变特性,无法直接应用于解卷积运算.为实现SD-OCT系统成像质量基于解卷积算法的优化,本文采用数值校正后的轴向扫描信号和轴向有效PSF来实施基于Lucy-Richardson算法的解卷积运算,进而实现了SD-OCT系统中图像质量尤其是轴向分辨率的改善.本文理论分析了SD-OCT系统中导致轴向有效PSF随成像深度增大而下降和图像模糊的因素,阐述了利用解卷积算法实现图像质量优化的过程,基于建立的SD-OCT系统实施了不同成像深度位置处PSF的标定,并利用离散轴向位置处PSF的峰值拟合了轴向有效PSF的调制函数.利用调制函数对所有轴向扫描信号进行数值校正,然后根据轴向有效PSF进行解卷积算法.典型样品的解卷积图像重建结果表明,提出的解卷积方法能有效提高系统的轴向分辨率,同时有效抑制系统灵敏度随成像深度增大而下降的趋势. 关键词： 谱域光学相干层析 Lucy-Richardson解卷积 有效点扩散函数     

高能脉冲X射线能谱测量

给出了高能脉冲X射线能谱测量的基本原理及实验结果.采用Monte-Carlo程序计算了高能光子在能谱仪中每个灵敏单元内的能量沉积,利用能谱仪测量了"强光Ⅰ号"加速器产生的高能脉冲X射线不同衰减程度下的强度,求解得到了具有时间分辨的高能脉冲X射线能谱,时间跨度57ns,时间步长5ns,光子的最高能量3.0MeV,平均能量1.04MeV,能量在0.2—0.9MeV之间的光子数目最多,占46.5%.也利用二极管的电压电流波形理论计算了光子的能谱,并与利用能谱仪测得的能谱进行了比较,两种方法所得结果基本一致.     

Iterative Wiener deconvolution based method for phase retrieval from noisy intensities

To retrieve the phase from the noisy measured intensities in the diffraction planes, an iterative Wiener deconvolution based method is proposed. With the same iterative scheme as the iterative angular spectrum method (IAS), the propagation of the optical wave function between the input plane and the diffraction planes is calculated by Wiener deconvolution in this method. The angular spectrum convolution kernel used in the iterative angular spectrum method is incorporated into the Wiener filter. The simulation experiments show that the proposed method can reduce the impact of the noise on the retrieved phase and performed better than the pre-denoising method. Furthermore, the proposed method exhibits great advantage compared to IAS for retrieving the complicated phase distribution from two measured intensities.     

稀疏孔径光学系统成像的图像恢复算法研究

提出两种稀疏孔径光学系统成像的图像恢复模型.分析维纳滤波、最小二乘方滤波和极大似然法盲去卷积三种图像恢复算法的适用条件.针对存在噪声干扰的稀疏孔径光学系统,通过实验对比,指出维纳滤波和最小二乘方滤波把相机光学传函当作系统传函,其理论推导能够达到最优.盲去卷积把大气传输函数和相机光学传函作为系统传函进行恢复,其恢复结果优于维纳滤波带入常数K和最小二乘方滤波调整参量结果.