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101.
The Effect of the Modification of Carbon Spheres with ZnCl2 on the Adsorption Properties towards CO2
Iwona Peech Piotr Staciwa Daniel Sibera Ewelina Kusiak-Nejman Antoni W. Morawski Joanna Kapica-Kozar Urszula Narkiewicz 《Molecules (Basel, Switzerland)》2022,27(4)
Zinc chloride and potassium oxalate are often applied as activating agents for carbon materials. In this work, we present the preparation of ZnO/carbon spheres composites using resorcinol-formaldehyde resin as a carbon source in a solvothermal reactor heated with microwaves. Zinc chloride as a zinc oxide source and potassium oxalate as an activating agent were applied. The effect of their addition and preparation conditions on the adsorption properties towards carbon dioxide at 0 °C and 25 °C were investigated. Additionally, for all tested sorbents, the CO2 sorption tests at 40 °C, carried out utilizing a thermobalance, confirmed the trend of sorption capacity measured at 0 and 25 °C. Furthermore, the sample activated using potassium oxalate and modified using zinc chloride (a carbon-to-zinc ratio equal to 10:1) displayed not only a high CO2 adsorption capacity (2.69 mmol CO2/g at 40 °C) but also exhibited a stable performance during the consecutive multicycle adsorption–desorption process. 相似文献
102.
研究核爆聚变电站中的一类中子学问题——如何利用核爆炸产生的大量中子生产核燃料.首先,根据核爆中子场的特点,确定可以利用的中子能量范围.用慢化理论对慢化材料的厚度进行估计,并用MCNP程序进行数值计算.研究如何利用中子反照效应减少造材料层的厚度,最后提出一个较合理的造材料技术路线. 相似文献
103.
利用中温太阳能为甲醇分解的吸热反应供热,可以将中温太阳能转化为合成气燃料的化学能,同时提高燃料热值和太阳能的可用性,还可以实现太阳能与化石燃料的互补.本研究提出了太阳能热化学系统的一体化设计原则,建立了综合考虑太阳能集热、反应动力学和反应器结构参数的太阳能甲醇分解反应器的理论分析模型,并首次研制了5 kW热功率的抛物槽式太阳能甲醇分解一体化实验装置.太阳能甲醇分解的实验结果表明太阳能集热器可以为甲醇分解提供200~300 ℃的反应温度,在辐照300~800 W/m2,甲醇进料量为0.5~4l/h条件下,甲醇转化率可以达到50%~95%,投射到吸收-反应器上的太阳能转换为燃料化学能的效率可以达到30%~60%,具有良好的甲醇分解和太阳能转换性能.研制的实验装置体现了一体化设计特征,同时理论分析结果与实验结果也具有很好的一致性.本文研究成果将为开拓太阳能与化石能源互补的能量系统提供理论支撑和实验数据. 相似文献
104.
《Analytical letters》2012,45(12):1107-1111
Abstract An exploratory study was made of the esterification of octanoic acid using reaction-gas chromatography and diazo-methane prepared by distillation as reagent. The technique does not require esterification external to the chromatographic system. 相似文献
105.
l-Glutamine amidohydrolase (l-glutaminase, EC 3.5.1.2) is a therapeutically and industrially important enzyme. Because it is a potent antileukemic agent
and a flavor-enhancing agent used in the food industry, many researchers have focused their attention on l-glutaminase. In this article, we report the continuous production of extracellular l-glutaminase by the marine fungus Beauveria bassiana BTMF S-10 in a packed-bed reactor. Parameters influencing bead production and performance under batch mode were optimized
in the order-support (Na-alginate) concentration, concentration of CaCl2 for bead preparation, curing time of beads, spore inoculum concentration, activation time, initial pH of enzyme production
medium, temperature of incubation, and retention time. Parameters optimized under batch mode for l-glutaminase production were incorporated into the continuous production studies. Beads with 12×108 spores/g of beads were activated in a solution of 1% glutamine in seawater for 15 h, and the activated beads were packed
into a packed-bed reactor. Enzyme production medium (pH 9.0) was pumped through the bed, and the effluent was collected from
the top of the column. The effect of flow rate of the medium, substrate concentration, aeration, and bed height on continuous
production of l-glutaminase was studied. Production was monitored for 5 h in each case, and the volumetric productivity was calculated. Under
the optimized conditions for continuous production, the reactor gave a volumetric productivity of 4.048 U/(mL·h), which indicates
that continuous production of the enzyme by Ca-alginate-immobilized spores is well suited for B. bassiana and results in a higher yield of enzyme within a shorter time. The results indicate the scope of utilizing immobilized B. bassiana for continuous commercial production of l-glutaminase. 相似文献
106.
分析了磁阀式可控电抗器的结构和工作原理,通过直流控制电流控制铁芯的饱和度来调节电抗器的投入容量,采用可控硅和复杂的可编程逻辑器件(CPLD)为其设计了控制装置,实现了电抗器容量的自动连续调节,具有响应速度快、可靠性高的特点,并在电网无功补偿中得到了较好的应用. 相似文献
107.
B.?Giesen H.?Wiggers A.?Kowalik P.?RothEmail author 《Journal of nanoparticle research》2005,7(1):29-41
The formation and growth of silicon-nanoparticles from silane in a microwave reactor was investigated. Experiments were performed for the following conditions: precursor concentration 380–2530 ppm, pressures of 20–30 mbar, microwave powers 120–300 W. The formed particles were examined in-situ with a particle mass spectrometer. Additionally, particles were collected on grids and analyzed by transmission electron microscopy, X-ray diffraction, and by determining the specific surface area by BET. The particle size was found to be in the range of 5–8 nm in diameter. A simple model was used to simulate the particle formation processes taking place inside the reactor. The microwave energy coupled into the reactor flow was treated as a spatially distributed energy source resulting in a local temperature increase. The particles were assumed to have a monodisperse size distribution. To allow an approximation of their shape they were characterized by their volume and surface area. The model takes nucleation, convection, coagulation, and coalescence into account. The fluid flow inside the microwave reactor was simulated with the commercial CFD-code Fluent. 相似文献
108.
The kinetics of the reactions of the macroradicals Rf′OCF2 (I) and Rf′OCF2CF2 (II) with HCl, Cl2 and F2 have been studied in the liquid phase, being Rf′ a poly(oxydifluoromethylene-oxytetrafluoroethylene) chain with average molecular weight of about 104 Da. Radical (I) showed a higher reactivity compared to radical (II) with all the three radical transfer agents.In case of HCl the activation energy for the reaction:
109.
A numerical analysis is presented for buoyancy driven flow of a Newtonian fluid contained in a two dimensional (R, ) hemispherical enclosure for high Rayleigh (Ra) numbers. It is assumed that the flow is driven by the uniformly distributed internal heat sources within the enclosure. All walls of the cavity are maintained at a constant temperature. Finite volume based SIMPLER algorithm has been used for the present analysis. Discretised governing equations, in primitive variables, are solved by a combination of Three Diagonal Matrix Algorithm (TDMA) and Point Successive Overrelaxation (PSOR) method. A benchmark solution prepared for a Ra number range of 107 to 1012 and Prandtl (Pr) number 7.0, shows an excellent agreement with the experimental results obtained from the open literature. 相似文献
110.
A 100 MWt reactor design has been conceived to support flux level of the order of 1015 n/cm2/s in selected flux trap zones. The physics design considers high enriched metallic alloy fuel in the form of annular plates
placed in a D2O moderator tank in a hexagonal lattice arrangement. By choosing a tight lattice pitch in the central region and double the
lattice pitch in the outer region, it is possible to have both high fast flux and thermal flux trap zones. By design the flux
level in the seed fuel has been kept lower than in the high flux trap zones so that the burning rate of the seed is reduced.
Another important objective of the design is to maximize the time interval of refueling. As against a typical refueling interval
of a few weeks in such high flux reactor cores, it is desired to maximize this period to as much as six months or even one
year. This is possible to achieve by eliminating the conventional control absorbers and replacing them with a suitable amount
of fertile material loading in the reactor. Requisite number of seedless thorium-aluminum alloy plates are placed at regular
lattice locations vacated by seed fuel in alternate fuel layers. It is seen that these thorium plates are capable of acquiring
asymptotic fissile content of 14 g/kg in about 100 days of irradiation at a flux level of 8 × 1014 n/cm2/s. In summary, the core has a relatively higher fast flux in the central region and high thermal flux in the outer region.
The present physics design envisages a flat core excess reactivity for the longest possible cycle length of 6 months to one
year. It is also possible to modify the design for constant subcriticality for about the same period or longer duration by
considering neutron spallation source at the centre and curtailing the power density in the inner core region by shielding
it with a layer of thoria fuel loading.
相似文献