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排序方式: 共有2736条查询结果,搜索用时 828 毫秒
31.
高硅ZSM—5沸石填充硅橡胶膜的醇—水渗透蒸发分离性质 总被引:5,自引:3,他引:5
高硅ZSM-5沸石填充疏水性硅橡胶蓦地低浓度醇-水体度醇-水体的渗透蒸发性质的研究有明,提高沸石硅铝比,增加填充量以及进行酸处理皆有利于改善膜对醇-水的分离系数和通量。料液的成,浓度以及温度对膜的分离性质也有显著影响。 相似文献
32.
肝素化壳聚糖季铵盐/壳聚糖复合膜抗凝血性能的研究 总被引:13,自引:1,他引:13
以壳聚糖季铵盐,壳聚糖为基本原材料,选用戊二醛为交剂剂及固定剂,制备一种物理机械性能较优的抗凝血材料。探讨了戊二醛及肝素钠两者用量对肝素化程度及血液生的影响。 相似文献
33.
To obtain new materials with synergetic or complementary behaviors, polyaniline composite filled with ZnO rods in ramification-like
structure was prepared by a hydrothermal approach. Comparative experiments of ZnO preparation in the presence of some metal
ions were also carried out. The results indicated that the morphology of ZnO was strongly affected by the preparation condition.
The method to grow ZnO rods in the presence of polyaniline offers a simple approach to obtain polyaniline composite filled
with linear ZnO structure. The results of X-ray photoelectron spectroscopy show that the strong interaction between ZnO and
polyaniline possibly exists to cause the charge transfer. 相似文献
34.
杂原子Y分子筛的二次合成及其吸附脱硫性能 总被引:13,自引:0,他引:13
采用液-固相同晶取代反应制备了骨架含Ga的Y型分子筛, 并对其吸附脱硫性能进行了研究. 在室温, 空速为7 h−1的条件下, 镓化Y型分子筛([Ga]AlY)处理噻吩、四氢噻吩、4,6-二甲基二苯并噻吩(4,6-DMDBT)正壬烷溶液(硫含量500 μg•g−1), 每克吸附剂吸附硫的量分别为7.7、17.4、14.5 mg. 采用密度泛函理论(DFT)中的广义梯度近似方法(GGA)计算各分子中硫原子上的电荷数, 噻吩中硫原子的电荷数为−0.159, 而4,6-DMDBT和四氢噻吩分别为−0.214、0.298. 四氢噻吩和4, 6-DMDBT中硫原子上的电子密度大于噻吩中硫原子上的电子密度, 这就使得四氢噻吩和4,6-DMDBT中的硫原子与吸附位间的作用会远大于噻吩中的硫原子与吸附位间的作用, 吸附容量必然会大很多. 采用[Ga]AlY处理抚顺石油二厂的催化裂化汽油(硫含量:299 μg•g−1), 每克吸附剂处理2.1 mL汽油时, 处理后汽油的硫含量为54.8 μg•g−1, 说明[Ga]AlY对汽油脱硫有一定的效果. 相似文献
35.
36.
Effect of multi-walled carbon nanotubes on non-isothermal crystallization kinetics of polyamide 6 总被引:2,自引:0,他引:2
The non-isothermal crystallization behaviors of multi-walled carbon nanotubes (MWNTs)/polyamide 6 (PA6) composites were investigated by differential scanning calorimetry (DSC). Three methods, namely, Avrami, Ozawa and Mo, were carried out to analyze the non-isothermal crystallization data. The results showed that the MWNTs in PA6 acted as effective nucleation agents. However the crystallization rate of composites obtained was lower than that of the neat PA6. It is indicated that the presence of MWNTs influenced the mechanism of nucleation and the growth of PA6 crystallites. 相似文献
37.
A. Fendler M. P. Villanueva E. Gimenez J. M. Lagarón 《Cellulose (London, England)》2007,14(5):427-438
The present work presents and discusses the interrelation between composition, morphology, thermal history, mechanical and
barrier properties to oxygen and limonene of composites of HDPE/MA-PE/cellulose fibers of significant interest in, among others,
food packaging applications. From the overall results, it was observed that increasing the loading of purified alpha-cellulose
fibers in the polyethylene matrix beyond 10 wt.% led to a decrease in the permeability coefficient of d-limonene, effect which was found to be primarily related to a decrease in the overall solubility of this strongly plasticizing
aroma component. On the other hand, the oxygen permeability was found to decrease to a significant extend with increasing
fiber content beyond 5 wt.%, but this effect was more strongly ascribed to a significant decrease in the diffusion coefficient.
Therefore, the fibers are thought to generate a more tortuous path for the non-interacting gas molecules to travel across
the composites thickness, even when tested at high relative humidity conditions. Optimum fiber loading levels in terms of
overall property balance were found to be around 20 wt.%. 相似文献
38.
探针反应和FTIR法研究Pt与L型沸石的相互作用董家禄,朱建华,须沁华,张婕,刘大壮(南京大学化学系,南京,210008)(郑州工学院化工系,郑州,450002)关键词Pt/L沸石,沸石催化剂,异丙醇分解反应,Pt-载体相互作用Pt的分散度和电子状态... 相似文献
39.
Zouhair Asfari Rym Abidi Françoise Arnaud Jacques Vicens 《Journal of inclusion phenomena and macrocyclic chemistry》1992,14(2):163-169
The template synthesis of copper(II) phthalocyanine by the condensation of dicyanobenzene within the supercages of Cu(II) exchanged X and Y type zeolites was studied using differential scanning calorimetry. The exotherms for intrazeolite and surface complexation have been resolved. These thermal events exhibit a dependence on the copper loading and hydration level which has been interpreted as a pressure effect. 相似文献
40.