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51.
V.N. Strekalov V.I. Konov V.V. Kononenko S.M. Pimenov 《Applied Physics A: Materials Science & Processing》2003,76(4):603-607
A mechanism for photographitization of a free diamond surface is proposed. The quantum-kinetic rate of this process is determined.
The graphitization rate is close to zero if the activation energy of the graphitization process is taken as being equal to
the binding energy of a carbon atom with the surface (i.e. equal to the sublimation energy of a carbon atom). On the contrary,
if the activation energy is close to the energy of C–C bonds, the graphitization process may occur at a noticeable rate and
be observed under ‘relatively smooth’ experimental conditions. The temperature rise leads to a considerable increase in the
graphitization rates. Preliminary experimental data on the low-rate laser ablation of diamond are presented to support the
proposed model of photographitization.
An early stage of laser-induced graphitization in the bulk of diamond is also considered. It is found that the nucleation
of a ‘tiny graphite drop’ is possible in the bulk of the diamond inside the focal area of a laser beam; the ‘graphite drop’
growth causing the appearance of mechanical stresses in the surrounding regions. The maximum size of the graphite drop is
determined, which, when exceeded, leads to mechanical damage of the sample and to a change in the mechanism of laser graphitization.
An evident mechanical criterion for laser-induced damage of diamond is proposed.
Received: 2 October 2002 / Accepted: 5 October 2002 / Published online: 29 January 2003
RID="*"
ID="*"Corresponding author. E-mail: stvn@stankin.ru 相似文献
52.
GONGCHU HUANGQIDE DUJIANGCHUAN LIUHONGJIAN 《高校应用数学学报(英文版)》1995,10(1):89-102
How to increase the speed in drawing and recognizing curves has always been a major concern. From the Breshenham Algorithm and DDA Algorithm in the sixties to the double-step and quadruple-step line generation iu the eighties, curves were all dragon point by point. The algorithm in this paper fully utilizes machine commands to accelerate the generation of lines and curves. We introduce and prove for the first time characterization theorems of the segment code order of digital lines and curyes. These theorems give new methods in the recognition and the measure of smoothness of lines and curves. 相似文献
53.
It was founded using the magneto-optical technique that the domain wall in the iron-based amorphous ferromagnet in its movement experienced enhanced deceleration on the surface compared to the volume. The surface deceleration of the wall intensifies under water molecules adsorption on the sample surface. This effect is explained by the domain wall interaction with magnetic micro-defects observed on the sample surface using a magnetic force microscope. 相似文献
54.
Some spectral properties of the transition matrix of an oriented graph indicate the preconditioning of Euler-Richardson (ER) iterative scheme as a good way to compute efficiently the vertexrank vector associated with such graph. We choose the preconditioner from an algebra U of matrices, thereby obtaining an ERU method, and we observe that ERU can outperform ER in terms of rate of convergence. The proposed preconditioner can be updated at a very low cost whenever the graph changes, as is the case when it represents a generic set of information. The particular U utilized requires a surplus of operations per step and memory allocations, which make ERU superior to ER for not too wide graphs. However, the observed high improvement in convergence rate obtained by preconditioning and the general theory developed, are a reason for investigating different choices of U, more efficient for huge graphs. 相似文献
55.
Mark Grant 《Topology and its Applications》2012,159(1):88-97
We show how locally smooth actions of compact Lie groups on a manifold X can be used to obtain new upper bounds for the topological complexity TC(X), in the sense of Farber. We also obtain new bounds for the topological complexity of finitely generated torsion-free nilpotent groups. 相似文献
56.
磁共振系统中的发射/接收(transmit/receive,T/R)开关用于收发通路的切换,要求在隔离大功率信号的同时具有较小的插入损耗;另外,在宽带磁共振谱仪中,一般的窄带T/R开关也不再适用.本文基于PIN(positive-intrinsic-negative)二极管设计了工作频率为10~100 MHz的宽带磁共振T/R开关.通过减小电平跳变、优化开关过冲和解决二极管被动导通等问题,获得了插入损耗小于1 dB、大功率信号隔离度大于75 dB、开关时间1 μs的整体性能.用本文设计的宽带T/R开关替代一般探头中的窄带T/R开关,在0.5 T核磁共振(NMR)波谱仪上测得了氢核和氟核两个不同频率的磁共振信号,验证了宽带T/R开关的宽带性能. 相似文献
57.
文中证明了有限预序集与有限偏序集的一些性质,并基于有限集上的拓扑和其上预序的一一对应关系,利用这些性质通过对极小元和极大元个数进行分类讨论,以一种有别于计算机算法而又容易理解的计算方法得出6元素集合上的T0拓扑总数为130023. 相似文献
58.
Since a tropical Nullstellensatz fails even for tropical univariate polynomials we study a conjecture on a tropical dual Nullstellensatz for tropical polynomial systems in terms of solvability of a tropical linear system with the Cayley matrix associated to the tropical polynomial system. The conjecture on a tropical effective dual Nullstellensatz is proved for tropical univariate polynomials. 相似文献
59.
B. Dacorogna I. Fonseca J. Malý K. Trivisa 《Calculus of Variations and Partial Differential Equations》1999,9(3):185-206
The integral representation for the relaxation of a class of energy functionals where the admissible fields are constrained
to remain on a
-dimensional manifold is obtained. If is a continuous function satisfying for and for all then where is open, bounded, and is the tangential quasiconvexification of f at
belong to the tangent space to at
Received October 10, 1998 / Accepted December 1, 1998 相似文献
60.
The acetone molecule is investigated in its ground state and valence 1,3n-π*, 1,3π-π*, and 1,3σ-π* excited states and Rydberg 1,3n-3s, 1,3π-3?, 1,3n-3py and 1,3π-3py states using the CASSCF, CASPT2, and CCSD(T) methods. Equilibrium geometries of excited states are obtained and their changes with respect to the ground state are discussed. For most excited states the C2v symmetry of the ground state is lowered to the Cs symmetry. A series of valence vertical and adiabatic excitation energies is presented along with excitation energies for Rydberg states. The main body of the paper contains Finite-Field Perturbation Theory (FFPT) calculations of electric properties of the vertically as well as geometry relaxed excited states. Dipole moments of valence excited states decrease significantly upon excitation, being about one half of the ground state dipole moment. Polarizabilities usually change upon excitation much less (increase by about 30%) but hyperpolarizabilities are enhanced up to one or two orders of magnitude. The orientation of the dipole moment is reversed in some vertically excited Rydberg states. Properties of the ground and excited states are discussed considering alterations of the electronic structure and shifts in the geometry. 相似文献