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31.
Li2Br(NH2): The First Ternary Alkali Metal Amide Halide The pseudobinary system LiNH2/LiBr was investigated by X-ray methods. The crystal structure of the compound Li2Br(NH2) was solved by single crystal data: Li2Br(NH2): Pnma, Z = 8, a = 12.484(2) Å, b = 7.959(1) Å, c = 6.385(1) Å, Z(Fo) with (Fo)2 ≧ 3σ(Fo)2 = 348, Z (parameter) = 51, R/Rw = 0.019/0.021 Li2Br(NH2) crystallizes in a new type of structure. To one another isolated chains of [Li2Li4/2(NH2)22+] show the motif of closest rod packing. They are connected via bromide ions in a distorted cubic primitive arrangement. 相似文献
32.
Vesselin Dimitrov Yanko Dimitriev Vili Mihailova 《Monatshefte für Chemie / Chemical Monthly》1983,114(6-7):669-674
The structure of glasses in the Fe2O3-V2O5 system in the 0–50 mol% Fe2O3 range is studied by IR-spectroscopy. It is found that the introduction of Fe2O3 favours the transformation of the VO5-groups into VO4 ones. This effect may be shown with the aid of IR-spectra, owing to the fact that these glasses are characterized by two high-frequency bands at 1020 and 930 cm–1. The first is determined by the vibrations of the short V=O nonbridging bonds in the VO5-groups, while the second is assigned to the vibrations of the V—O-bonds in deformed VO4-tetrahedra.
IR-spektroskopische Strukturuntersuchung von Gläsern des Systems Fe2O3-V2O5
Zusammenfassung Die Struktur von Gläsern des Systems Fe2O3-V2O5 in dem Bereich von 0–50 Molprozent Fe2O3 wurde mit Hilfe der IR-Spektroskopie untersucht. Zusatz von Fe2O3 begünstigt die Umwandlung der VO5- in VO4-Gruppen. Das kann in den IR-Spektren durch zwei Banden bei 1020 und 930 cm–1 festgestellt werden. Die erste wird durch Schwingungen der kurzen V=O-Nichtbrücken-bindungen in den VO5-Gruppen verursacht, die zweite wird auf Schwingungen der V—O-Bindungen in dem deformierten VO4-Tetraeder zurückgeführt.相似文献
33.
Matthias Otto Müller Stefan N. Groesser Silvia Ulli-Beer 《European Journal of Operational Research》2012,216(2):495-502
Collaborative research, defined as research involving actors participating in the problem situation under study, has an important role in operational research, strategic management and systems thinking. In a recent study, we found that a strong organizational focus incorporated into many soft operational research (OR) approaches is inadequate for studying societal problem situations, which are fragmented and have no clear boundary. Specifically, we failed to find a process of identifying individuals that is capable of representing the perspectives of actors and sufficient for research into societal problem situations. We found no clear terminology accounting for ontological differences between actors, individuals representing them and conceptual representations of acting entities. In response to this gap in the literature, we propose terminology that differentiates among actors (individuals or collective entities in the real world), experts (individuals capable of representing the perspective of an actor) and agents (ideal-typical representations of actors). Based on this terminology, we propose an iterative method to guide the assembly of an expert group to undertake collaborative research into societal problem situations. To demonstrate the application of our method, we present selected insights from our study in an electronic supplement. 相似文献
34.
Mahmood Tajbakhsh Majid M. Heravi Abolfazl Hosseini Ahmad Shahrezaiee 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):773-776
Hantzsch 1,4-dihydropyriines were rapidly and efficiently oxidized using bismuth nitrate supported onto silica gel under microwave irradiation. 相似文献
35.
36.
Abbas Shockravi Hashem Shargi Hassan Valizadeh Majid M. Heravi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2555-2559
An efficient synthesis of 3-substituted coumarins under solventless system is described. 相似文献
37.
Majid M. Heravi Hossein A. Oskooie Ladan Sangsefidi Mitra Ghassemzadeh Koroush Tabar-Hydar 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2843-2846
Oxidative deprotection of tetrahydropyranyl ethers (THP ethers) using chromium trioxide supported onto zeolite under microwave irradiation in solvent free condition is described. 相似文献
38.
Kira Rubina Edgars Ābele Juris Popelis Solveiga Grinberga Pavel Arsenyan Edmunds Lukevics 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):521-529
A novel two-step method for the preparation of ( E )-2-chlorovinylthioarenes (or hetarenes) from thiols and 1,1,2-trichloroethane in the phase transfer catalytic systems solid K 2 CO 3 /solid KI/18-crown-6/xylene and solid KOH/18-crown-6/toluene has been developed. ( E )-2-chlorovinylthioarenes were isolated in yields up to 98%. Utilization of ( E )-2-chlorovinylthioarenes in the Heck and Stille reactions has been shown. 相似文献
39.
William F. Trench 《Journal of Difference Equations and Applications》2013,19(9):811-821
We consider the functional difference system ( A ) j x i ( n )= f i ( n ; X ), 1 h i h k , where X =( x 1 ,…, x k ) and f 1 (·; X ),…, f k (·; X ) are real-valued functionals of X , which may depend quite arbitrarily on values of X ( l ) for multiple values of l ] Z . We give sufficient conditions for ( A ) to have solutions that approach specified constant vectors as n M X . Some of the results guarantee only that the solutions are defined for n sufficiently large, while others are global. The proof of the main theorem is based on the Schauder-Tychonoff theorem. Applications to specific quasi-linear systems are included. 相似文献
40.
F. Balibrea Gallego J.L. García Guirao J.I. Muñoz Casado 《Journal of Difference Equations and Applications》2013,19(3-4):289-304
We consider Sturm–Liouville eigenvalue problems of second order with arbitary seperated boundary conditions and perform a suitabl discretization of them. The obtained discrete Sturm–Liouville eigenvalue problems are examined and the asymptotic behavior of their eigenvalue as the norm of the partition tends to zero is investigated. 相似文献